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48V mild hybrid powertrains are promising technologies for cost-effective compliance with future CO2 emissions standards. Current 48V powertrains with integrated belt starter generators (P0) with downsized engines achieve CO2 emissions of 95 g/km in the NEDC. However, to reach 75 g/km, it may be necessary to combine new 48V powertrain architectures with alternative fuels. Therefore, this paper compares CO2 emissions from different 48V powertrain architectures (P0, P1, P2, P3) with different electric power levels under various driving cycles (NEDC, WLTC, and RTS95). A numerical model of a compact class passenger car with a 48V powertrain was created and experimental fuel consumption maps for engines running on different fuels (gasoline, Diesel, E85, CNG) were used to simulate its CO2 emissions. The simulation results were analysed to determine why specific powertrain combinations were more efficient under certain driving conditions.