Search Results

Zirconium dioxide (ZrO2) doped with Yttria exhibits superplastic behaviour, corrosion resistance and excellent ion conducting properties [1] at moderate temperatures and thus it can be used as an electroceramic to measure the pH of high temperature water used in fuel cells. Several fabrication processes are available for preparation of zirconia ceramics. This research focused on the study of using Spark Plasma Sintering (SPS) process to prepare Yttria Stabilized Zirconia (YSZ) ceramic. 8 mol% YSZ was subjected to varying SPS sintering conditions. Samples were sintered by changing the heating cycle, dwell time, sintering pressure and cooling cycle. Subsequently, these parameters were related to the densification characteristics of the as-sintered YSZ. The results of specific gravity measurements and microstructure evaluation suggest that stepped heating followed by a slow cooling results in YSZ with highest relative density (99.9%).

The high-pressure direct injection (HPDI) of natural gas (NG) permits diesel engines to retain their high fuel economy while reducing regulated emissions. In the work presented in this paper, directly injected natural gas is ignited by pilot diesel fuel, and both fuels are injected through a single injector. The injector concept is discussed, along with the description of the instrumented Detroit Diesel two-stroke 6V-92TA DDEC II engine used for the experiments. Measurements of the performance and emissions with the HPDI of NG confirm the retention of the high efficiency of the diesel engine and demonstrate reductions in nitrogen oxide (NOx) emissions near 50% at high load using the same injection timing as for diesel fueling. Methane (CH4) and non-methane hydrocarbon (nmHC) emissions were found to be as low as those measured for diesel fueling at high loads, but were higher at low load operation. The gas injection pressure was found to affect the low-load emissions.

An experimental investigation of the autoignition and emission characteristics of transient turbulent gaseous fuel jets in heated and compressed air was conducted in a shock tube facility. Experiments were performed at an initial pressure of 30 bar with initial oxidizer temperatures ranging from 1200 to 1400 K, injection pressures ranging from 60 to 150 bar, and injection durations ranging from 1.0 to 2.5 ms. Methane and 90.0% methane/10.0% ethane blend were used as fuel. Under the operating conditions studied, increasing temperature resulted in a significant decrease in autoignition delay time. Increasing the injection pressure decreased ignition delay as well. The downstream location of the ignition kernel relative to the jet penetration distance was found to be in the range, 0.4

The scattering properties (influenced by morphology) and refractive index (dependent on microstructure) of engine-emitted soot influences its effect on climate, as well as how we interpret optical measurements of aerosols. The morphology and microstructure of soot from two different engines were studied. The soot samples were collected from a 1.9L Volkswagen TDI engine for two different fuel types (ULSD and B20) and six speed/load combinations., as well as from a Cummins ISX heavy-duty engine using the Westport pilot-ignited high-pressure direct-injection (HPDI) natural-gas fuelling system for three different speed/load combinations. The transmission electron microscopy (TEM) was employed to investigate the soot morphology, emphasizing the fractal properties. Image processing was used to extract the geometrical properties of the thirty-five randomly chosen aggregates from each sample.

Soot emissions from direct-injection engines are sensitive to the fuel-air mixing process, and may vary between combustion cycles due to turbulence and injector variability. Conventional exhaust emissions measurements cannot resolve inter- or intra-cycle variations in particle emissions, which can be important during transient engine operations where a few cycles can disproportionately affect the total exhaust soot. The Fast Exhaust Nephelometer (FEN) is introduced here to use light scattering to measure particulate matter concentration and size near the exhaust port of an engine with a time resolution of better than one millisecond. The FEN operates at atmospheric pressure, sampling near the engine exhaust port and uses a laser diode to illuminate a small measurement volume. The scattered light is focused on two amplified photodiodes.

As global energy demands continue to be met with ever evolving and stricter emissions requirements, natural gas (NG) has become a highly researched alternative to conventional fossil fuels in many industrial sectors. Transportation is one such field that can utilize the benefits of NG as a primary fuel for use in internal combustion engines (ICEs). In the context of heavy-duty on-highway transportation applications, diesel-ignited dual-fuel (DIDF) combustion of NG has been identified as a commercially viable alternative technology. Previous investigations of DIDF have examined the various trends present across the spectrum of DIDF operating space. However, in-cylinder processes are still not well understood and this investigation aims to further understanding in this area. An in-cylinder, local infrared absorption fuel concentration sensor is used to examine in-cylinder processes by comparison with previous optical and thermodynamic studies.

An experimental investigation of the autoignition of transient gaseous fuel jets in heated and compressed air is conducted in a shock tube facility. Experiments are performed at an initial pressure of 30 bar with initial oxidizer temperatures ranging from 1150 K to 1400 K, injection pressures ranging from 60 bar to 150 bar, and with injector tip orifice diameters of 0.275 mm and 1.1 mm. Under the operating conditions studied, increasing temperature results in a significant decrease in autoignition delay time, td. The smaller orifice results in an increase in ignition delay time and variability, as compared with the larger orifice. For initial temperatures below about 1250K, ignition is rarely achieved with the smaller orifice, whereas ignition is always achieved with the larger orifice down to 1150 K. Under the conditions studied, increasing the injection pressure decreases ignition delay, a result dynamically consistent with larger orifice size decreasing ignition delay time.

Operators of natural gas engines, used for both mobile and stationary applications, are increasingly looking at running these engines under very lean air-fuel ratios in order to reduce exhaust emissions and increase thermal efficiency. Lean operation of homogeneous-charge spark-ignited engines reduces peak combustion temperatures, thereby reducing NOx emissions. Lean operation is normally restricted, however, by the “lean-limit” of combustion, as measured by the air-fuel ratio above which ignition is impossible, or combustion is incomplete. Operation under lean conditions also reduces the mixture burning rate, which can lead to increased spark advance and lower thermal efficiency. In order to increase the burning rate under ultra-lean air-fuel ratios a new “Squish-Jet” combustion chamber concept has been developed.

High-pressure direct-injection (HPDI) in heavy duty engines allows a natural gas (NG) engine to maintain diesel-like performance while deriving most of its power from NG. A small diesel pilot injection (5-10% of the fuel energy) is used to ignite the direct injected gas jet. The NG burns in a predominantly non-premixed combustion mode which can produce particulate matter (PM). Here we study the effect of injection strategies on emissions from a HPDI engine in two parts. Part-I will investigates the effect of late post injection (LPI) and Part II will study the effect of slightly premixed combustion (SPC) on emission and engine performance. PM reductions and tradeoffs involved with gas late post-injections (LPI) was investigated in a single-cylinder version of a 6-cylinder,15 liter HPDI engine. The post injection contains 10-25% of total fuel mass, and occurs after the main combustion event.

High-pressure direct-injection (HPDI) in heavy duty engines allows a natural gas (NG) engine to maintain diesel-like performance while deriving most of its power from NG. A small diesel pilot injection (5-10% of the fuel energy) is used to ignite the direct injected gas jet. The NG burns in a predominantly mixing-controlled combustion mode which can produce particulate matter (PM). Here we study the effect of injection strategies on emissions from a HPDI engine in two parts. Part-I investigated the effect of late post injection (LPI); the current paper (Part-II) reports on the effects of slightly premixed combustion (SPC) on emission and engine performance. In SPC operation, the diesel injection is delayed, allowing more premixing of the natural gas prior to ignition. PM reductions and tradeoffs involved with gas slightly premixed combustion was investigated in a single-cylinder version of a 6-cylinder, 15 liter HPDI engine.

Compression ignition engines, including those that use natural gas as the major fuel, produce emissions of NOx and particulate matter (PM). Westport Inc. has developed the pilot-ignited high-pressure direct-injection (HPDI) natural gas engine system. Although HPDI engines produce less soot than comparable conventional diesel engines, further reductions in engine-out soot emissions is desired. In diesel engines, multiple injections can help reduce both NOx and PM. The effect of post injections on HPDI engines was not studied previously. The present research shows that late injection of a second gas pulse can significantly reduce PM and CO from HPDI engines without significantly increasing NOx or fuel consumption. In-cylinder pressure measurements were used to characterize the heat release resulting from the multiple injections. Experiments showed that most close-coupled split injection strategies provided no significant emissions benefit and less stable operation.

A diesel pilot-ignited, high-pressure direct-injection of natural gas heavy-duty single-cylinder engine was fuelled with both natural gas and blends of 10% and 23% by volume hydrogen in methane. A single operating condition (6 bar GIMEP, 0.5 ϕ, 800 RPM, 40%EGR) was selected, and the combustion phasing was varied from advanced (mid-point of combustion at top-dead-center) to late (mid-point of combustion at 15°ATDC). Replacing the natural gas with hydrogen/methane blend fuels was found to have a significant influence on engine emissions and on combustion stability. The use of 10%hydrogen was found to slightly reduce PM, CO, and tHC emissions, while improving combustion stability. 23%hydrogen was found to substantially reduce CO and tHC emissions, while slightly increasing NOx. The greatest reductions in CO and tHC, along with a significant reduction in PM, were observed at the latest combustion timings, where combustion stability was lowest.

High pressure injection of natural gas is being investigated as a mean of fueling diesel engines and meeting increasingly stringent EPA regulations on emissions of nitrogen oxides and particulates. In the work described in this paper, the penetration into air of a sonic jet of methane emerging from a suddenly opened poppet valve has been modelled analytically and measured using flow visualization. The injection pressure ratios were in the range 1.5 to 5 and the conical jet sheet Reynolds numbers were in the range 7000 to 56000. Schlieren photographs revealed that the conical sheet gas jet exhibits an unstable behaviour between the upper and lower plates which simulate the fire deck and the piston. The integral model developed indicates the principal parameters on which the gaseous jet penetration depends and establishes the requirements for scaling. The conical sheet jet penetration is found to be approximately 30% less than that of round holes, given the same flow area.

Impending Environmental Protection Agency (EPA) regulations will place severe limits on exhaust emissions of heavy duty diesel engines for urban bus and highway truck applications. To meet this challenge an intensifier-injector system for natural gas fueling of diesel engines is being developed. The intensifier-injector concept employs electronically-controlled, late-cycle, direct injection of high-pressure natural gas with a pilot quantity of diesel fuel. Preliminary performance and emissions data are presented to indicate the potential for diesel engine efficiencies with reduced emissions with this method of natural-gas fueling.

A new injector has been designed for sequential injection of high-pressure natural gas and a quantity of liquid diesel fuel directly into diesel engine cylinders late in the compression stroke. Injected a few degrees before the natural gas, the pilot liquid fuel auto-ignites and serves, as it burns, to ignite the gaseous fuel which enters the chamber as an underexpanded sonic jet generating high local turbulence. Tests on a single-cylinder two-stroke engine with full electronic control have demonstrated the capability of this fueling method to nearly match conventional diesel engine efficiency over a wide range of load and substantially reduce the emissions of oxides of nitrogen (NOx), particulate mater (PM) and carbon dioxide (CO2).

Measurements of ignition characteristics and emissions were made in a shock tube facility operating at engine-relevant conditions. Methane and methane/ethane fuels were injected down the centerline of the shock tube using an electronically controlled prototype gaseous fuel injector developed by Westport Innovations. Air was preheated and compressed using a reflected shock technique that produced run times of 4-5 ms. Particulate matter (PM) emissions were found to be highly intermittent. In only 6 out of 97 experiments was PM detected above background levels. In all of these 6 sooting experiments ignition kernels were located relatively close to the injector tip and ignition occurred prior to the end of fuel injection. Using the large orifice injector tip with pure methane fuel, PM was detected in 4 out of 28 experiments; using the small orifice with pure methane fuel, no PM was detected in any of 50 experiments.

This paper presents a sensitivity-based input selection algorithm and a layered modeling approach for improving Gaussian Process Regression (GPR) modeling with hyperparameter optimization for engine model development with data sets of 120 training points or less. The models presented here are developed for a Pilot-Ignited Direct-Injected Natural Gas (PIDING) engine. A previously developed GPR modeling method with hyperparameter optimization produced some models with normalized root mean square error (nRMSE) over 0.2. The input selection method reduced the overall error by 0.6% to 18.85% while the layered modeling method improved the error for carbon monoxide (CO) by 52.6%, particulate matter (PM) by 32.5%, and nitrogen oxides (NOX) by 29.8%. These results demonstrate the importance of selecting only the most relevant inputs for machine learning models.

Heavy-duty diesel trucking is responsible for 25%-30% of the road transportation CO2 emissions in North America. Retrofitting class-8 trucks with a complementary hydrogen fuelling system makes it possible to co-combust hydrogen and diesel in the existing internal combustion engine (ICE), thus minimizing the costs associated with switching to non-ICE platforms and reducing the barrier for the implementation of low-carbon gaseous fuels such as hydrogen. This retrofitting approach is evaluated based on the exhaust emissions of a converted truck with several thousand kilometres of road data. The heavy-duty truck used here was retrofitted with an air-intake hydrogen injection system, onboard hydrogen storage tanks, and a proprietary hydrogen controller enabling it to operate in hydrogen-diesel co-combustion (HDC) mode.

The AirCare® vehicle emissions inspection and maintenance program is briefly described, together with the benefits which the program has already achieved. Additional benefits have been projected should the program include some more sophisticated assessment of evaporative emission control systems. The feasibility of including such an assessment has been investigated, and a pilot study has been conducted in the regular inspection lanes. The operational and systems implications are described. The pilot study has resulted in an analysis of the incidence of faulty gas caps in the Lower Fraser Valley light-duty vehicle fleet, and how this relates to other vehicle characteristics such as vehicle make, model, model year, mileage etc.; and inspection data including emission control system components tampering and tailpipe emissions. Approximately 10% of all gas caps tested failed the pressure test, compared to the 1% that were failed by visual inspection.

Measurements of performance and emissions of a Detroit Diesel 1-71 engine fueled with natural gas have been made using high-pressure direct-injection (HPDI). Natural gas is injected late in the compression cycle preceded by pilot injection of conventional liquid diesel fuel. With 6 nozzle holes for both natural gas and diesel pilot there was instability in engine operation at low load and wide scatter in emission measurements. Guided by numerical simulation results it was found experimentally that data reproducibility and engine operating stability could both be much improved by using unequal jet numbers for injection of natural gas and pilot diesel. In the range of 100 to 160 bar, combustion rate and NOx emissions increased with gas injection pressure. Best thermal efficiency results were obtained for a gas pressure of 130 bar. By adjusting beginning of injection, NOx reductions of up to 60 % from the diesel baseline could be obtained, while preserving conventional diesel efficiency.