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In recent years, the temperature of automobile exhaust gas is on a rising trend due to lowering pollutant emissions and improving fuel economy, and exhaust gas temperature reaches as high as 1173K in the case of diesel engine cars. Against this background, Ni-resist D-5S cast iron has been chosen extensively as a turbine housing material for the diesel engine cars. But, Ni-resist D-5S has become a material of great cost volatility due to high Nickel content of 35 mass%, which price is expensive and unstable. On the contrary Ferritic cast steels, which possesses favorable thermal fatigue properties and good material cost stability, are considered to be promising substitutions for the Ni-resist D-5S. However conventional ferritic cast steels have relatively high melting points, which cause poor castability.

Conventionally, the Ni-based superalloys NCF3015 (30Ni-15Cr) and the high nickel content NCF440 (70Ni-19Cr) (with its outstanding wear resistance and corrosion resistance), have been used as engine exhaust valve materials. In recent years, automobile exhaust gases have become hotter because of exhaust gas regulations and enhanced fuel consumption efficiency. Resource conservation and cost reductions also factor into global environmental challenges. To meet these requirements, NCF5015 (50Ni-15Cr), a new resource-conserving, low-cost Ni-based heat-resistant alloy with similar high-temperature strength and wear resistance as NCF440, has been developed. NCF5015's ability to simultaneously provide wear resistance, corrosion resistance and strength when NCF5015 is used with diesel engines was verified and the material was then used in exhaust valves.

As trends of automobile engine exhaust gas temperature are reducing emissions, the material for the exhaust components have been changed from ductile irons to ferritic cast alloys or stainless steel, further to austenitic cast alloys for higher performance engines. The current austenitic alloys, however, have thermal fatigue failure over 1273K. The authors developed excellent thermal fatigue resistant austenitic cast alloys, by investigating the effects of alloying elements on strength and thermal expansion, which correlate with thermal fatigue property. Developed alloys are expected to apply to exhaust components at gas temperatures over 1273K.

Engine valve development trends are to first, reduce the costly metal content and secondly, increase strength or reduce weight. These developments can be used to reduce valve cost or fuel consumption or increase power. The authors developed a new strain age hardening type alloy, NCF2415C, which has both good cold forgeability and heat resistance. Its chemical composition is Fe-24Ni-15Cr-2.2Ti-1.5Al-0.5Nb-0.02C-.006B-2Cu. This new alloy and the establishment f cold forging technology made it possible to develop cold forged exhaust valves having durability equal or better than the conventional hot forged exhaust valves.