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In view of the new emission regulations seeking to lower the particle cut-off size down to the current 23 nm, an extensive comprehension on the nature of sub-23 nm particles is crucial. In this regard, a new challenge lies ahead considering an even more massive use of biofuels. The objective of this research study was to characterize the sub-23 nm particles and to evaluate their volatile organic fraction (VOF) from a high performance, 1.8 L gasoline direct injection (GDI) engine under the Worldwide harmonized Light vehicles Test Cycle (WLTC). Particle emissions were measured through an Engine Exhaust Particle Sizer (EEPS) capable of particle sizing and counting in the range 5.6 - 560 nm. The sampling and conditioning were performed by both a single diluter and the Dekati Engine Exhaust Diluter (DEED) a Particle Measurement Programme (PMP) compliant sample conditioning system.

The use of lean or ultra-lean ratios is an efficient and proven strategy to reduce fuel consumption and pollutant emissions. However, the lower fuel concentration in the cylinder hinders the mixture ignition, requiring greater energy to start the combustion. The prechamber is an efficient method to provide high energy favoring the ignition process. It presents the potential to reduce the emission levels and the fuel consumption, operating with lean burn mixtures and expressive combustion stability. In this paper the analysis of the combustion process of SI engines equipped with an innovative architecture and operating in different injection modes was described. In particular, the effect of the prechamber ignition on the engine stability and the efficiency was investigated in stoichiometric and lean-burn operation conditions. The activity was carried out in two parts.

The new real driving emission cycles and the growing adoption of turbocharged GDI engines are directing the automotive technology towards the use of innovative solutions aimed at reducing environmental impact and increasing engine efficiency. Water injection is a solution that has received particular attention in recent years, because it allows to achieve fuel savings while meeting the most stringent emissions regulations. Water is able to reduce the temperature of the gases inside the cylinder, coupled with the beneficial effect of preventing knock occurrences. Moreover, water dilutes combustion, and varies the specific heat ratio of the working fluid; this allows the use of higher compression ratios, with more advanced and optimal spark timing, as well as eliminating the need of fuel enrichment at high load. Computational fluid dynamics simulations are a powerful tool to provide more in-depth details on the thermo-fluid dynamics involved in engine operations with water injection.