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The emissions reduction potential of neat GTL (Gas to Liquids: Fischer-Tropsch synthetic gas-oil derived from natural gas) fuels has been preliminarily evaluated by three different latest-generation diesel engines with different displacements. In addition, differences in combustion phenomena between the GTL fuels and baseline diesel fuel have been observed by means of a single cylinder engine with optical access. From these findings, one of the engines has been modified to improve both exhaust emissions and fuel consumption simultaneously, assuming the use of neat GTL fuels. The conversion efficiency of the NOx (oxides of nitrogen) reduction catalyst has also been improved.

The effects of high boiling point fuel additives on deposits were investigated in a commercial turbocharged direct injection gasoline engine. It is known that high boiling point substances have a negative effect on deposits. The distillation end points of blended fuels containing these additives may be approximately 15°C higher than the base fuel (end point: 175°C). Three additives with boiling points between 190 and 196°C were examined: 4-tert-Butyltoluene (TBT), N-Methyl Aniline (NMA), and 2-Methyl-1,5-pentanediamine (MPD). Aromatics and anilines, which may be added to gasoline to increase its octane number, might have a negative effect on deposits. TBT has a benzene ring. NMA has a benzene ring and an amino group. MPD, which has no benzene ring and two amino groups, was selected for comparison with the former two additives.

The effects of Hydrotreated vegetable oil (HVO) on combustion and emission characteristics in a diesel engine were investigated by using spray analyzer, engine dynamometer and vehicle tests. Spray analysis showed that spray characteristics was virtually the same for HVO and diesel. From the results of the engine dynamometer and the vehicle tests, it was found that the high cetane number and the zero aromatics of HVO could reduce in HC and PM emissions. Moreover, as a result of optimized engine calcification, HVO is capable of improving partial fuel consumption and full-load torque. These results indicate that HVO has beneficial fuel characteristics for diesel engine.

Reduction of exhaust emissions was investigated in a modern diesel engine equipped with advanced diesel after treatment system using a Gas-to-Liquid (GTL) fuel, a cleaner burning alternative diesel fuel. This fuel has near zero sulfur and aromatics and high cetane number. Some specially prepared GTL fuel samples were used to study the effects of GTL fuel distillation characteristics on exhaust emissions before engine modification. Test results indicated that distillation range of GTL fuels has a significant impact on engine out PM. High cetane number also improved HC and CO emissions, while these fuel properties have little effect on NOx emissions. From these results, it was found that low distillation range and high cetane number GTL fuel can provide a favorable potential in NOx/PM emissions trade-off. In order to improve the tail-pipe emissions in the latest diesel engine system, the engine modifications were carried out for the most favorable GTL fuel sample.

Gas To Liquid (GTL) fuels synthesized from natural gas are known as clean fuels. Therefore, GTL fuels have been expected to be a promising option that can reduce the NOx and PM emissions from diesel engines and contribute to the energy security. In this study, in order to clarify the emission reduction potentials, the improvement of DI diesel engine and aftertreatment systems were investigated by utilizing GTL fuels characteristics. To achieve a further reduction of both NOx and PM emissions, the combustion chamber, injection pattern and EGR calibration were modified. From the results of tests, the engine out NOx emissions were reduced to the Euro 6 regulation level and in parallel the expected deteriorations of HC emission and fuel consumption were suppressed because of the characteristics of high cetane number and zero poly-aromatics hydrocarbons. Additionally, an aftertreatment system was optimized to GTL fuel in order to improve NOx conversion efficiency.

Effects of fuel distillation characteristics and cetane number on premixed charge compression ignition (PCCI) combustion were investigated for the purpose of reducing NOx and PM emissions from a direct injection diesel engine. The test engine had a hole type injection nozzle for conventional diesel combustion at high load operation. A low compression ratio and cooled EGR were applied to the test engine in order to reduce the compression temperature for avoiding pre-ignition. The investigation results show that, in the case of ignition control by EGR, a light fuel with lower distillation characteristics had an advantage of reducing smoke at higher loads. This means that high volatility fuel is effective in promoting lean mixture formation of fuel and air during the ignition delay. Moreover, lowering the cetane number was effective in reducing NOx emissions by suppression of combustion temperature.

The Diesel Dual Fuel (DDF) vehicle is one of the technologies to convert diesel vehicles for natural gas usage. The purpose of this research was to study the possibility of a DDF vehicle to meet emission standards for diesel vehicles. This research was done for small passenger vehicles and commercial vehicles. The exhaust emissions compliance of such vehicles in a New European Driving Cycle (NEDC) mode which was composed of Urban Driving Cycles (UDC) and an Extra Urban Driving Cycle (EUDC) was evaluated. (see APPENDIXFigure A1) In this study, the passenger vehicle engine, compliant with the EURO4 standard, was converted to a DDF engine. Engine bench tests under steady state conditions showed similar result to previous papers. Total hydrocarbon (HC) emission was extremely high, compared to diesel engine. The NEDC mode emissions of the DDF vehicle were estimated based on these engine bench test results.