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Exhaust and evaporative emissions systems have been developed to match the characteristics and usage of the Toyota THS II plug-in hybrid electric vehicle (PHEV). Based on the commercially available Prius, the Toyota PHEV features an additional external charging function, which allows it to be driven as an electric vehicle (EV) in urban areas, and as an hybrid electric vehicle (HEV) in high-speed/high-load and long-distance driving situations. To reduce exhaust emissions, the conventional catalyst warm up control has been enhanced to achieve emissions performance that satisfies California's Super Ultra Low Emissions Vehicle (SULEV) standards in every state of battery charge. In addition, a heat insulating fuel vapor containment system (FVS) has been developed using a plastic fuel tank based on the assumption that such a system can reduce the diffusion of vapor inside the fuel tank and the release of fuel vapor in to the atmosphere to the maximum possible extent.

The Homogenous Charge Compression Ignition (HCCI) engine is positioned as a next-generation internal combustion engine and has been the focus of extensive research in recent years to develop a practical system. One reason is that this new combustion system achieves lower fuel consumption and simultaneous reductions of nitrogen oxide (NOx) and particulate matter (PM) emissions, which are major issues of internal combustion engines today. However, the characteristics of HCCI combustion can prevent suitable engine operation owing to the rapid combustion process that occurs accompanied by a steep pressure rise when the amount of fuel injected is increased to obtain higher power output. A major issue of HCCI is to control this rapid combustion so that the quantity of fuel injected can be increased for greater power. Controlling the ignition timing is also an issue because it is substantially influenced by the chemical reactions of the fuel.

In this study, optical measurements were made of the combustion chamber gas during operation of a Homogeneous Charge Compression Ignition (HCCI) engine in order to obtain a better understanding of the ignition and combustion characteristics. The principal issues of HCCI engines are to control the ignition timing and to optimize the combustion state following ignition. Autoignition in HCCI engines is strongly influenced by the complex low-temperature oxidation reaction process, alternatively referred to as the cool flame reaction or negative temperature coefficient (NTC) region. Accordingly, a good understanding of this low-temperature oxidation reaction process is indispensable to ignition timing control. In the experiments, spectroscopic measurement methods were applied to investigate the reaction behavior in the process leading to autoignition.

The Homogenous Charge Compression Ignition (HCCI) engine is positioned as a next-generation internal combustion engine and has been the focus of extensive research in recent years to develop a practical system. One reason is that this new combustion system achieves lower fuel consumption and simultaneous reductions of nitrogen oxide (NOx) and particulate matter (PM) emissions, which are major issues of internal combustion engines today. However, the characteristics of HCCI combustion can prevent suitable engine operation owing to the rapid combustion process that occurs accompanied by a steep pressure rise when the amount of fuel injected is increased to obtain higher power output. A major issue of HCCI is to control this rapid combustion so that the quantity of fuel injected can be increased for greater power. Controlling the ignition timing is also an issue because it is substantially influenced by the chemical reactions of the fuel.

In this study, experiments were conducted using a blend of two types of fuel with different ignition characteristics. One was dimethyl ether (DME) that has a high cetane number, autoignites easily and displays low-temperature oxidation reaction mechanisms; the other was methane that has a cetane number of zero and does not autoignite easily. A mechanically driven supercharger was provided in the intake pipe to adjust the intake air pressure. Moreover, flame light in the combustion chamber was extracted using a system for observing light emission that occurred in the space between the cylinder head and the cylinder and in the bore direction of the piston crown. The results of previous studies conducted with a supercharged HCCI engine and a blended fuel of DME and methane have shown that heat release of the hot flame is divided into two stages and that combustion can be moderated by reducing the peak heat release rate (HRR).

A new liquid-liquid injection technique with a rigid swirling water flow and a single shot photograph was developed to make observation of a fuel-air mixing process, and then to understand its characteristic quantitatively. In this technique, a liquid fuel was injected into an other liquid to simulate the process of diffusion in a piston cavity of an actual engine. This experiment has been made employing four different configurations of plastic piston cavities; dish, troidal, bowl and square type. These cavities were filled with water and rotated to generate the rigid swirling water flow. Observations from the bottom and side view indicated that the mixing process in the square configuration markedly depends on the orientation of the spray, due to both effects of the swirl and the impingement of the spray on the side wall. The technique is a potential to visually understand the mixing process.

In this study, it was shown that Homogeneous Charge Compression Ignition (HCCI) combustion in a 4-stroke engine, operating under the conditions of a high compression ratio, wide open throttle (WOT) and a lean mixture, could be simulated by raising the compression ratio of a 2-stroke engine. On that basis, a comparison was then made with the characteristics of Active Thermo-Atmosphere Combustion (ATAC), the HCCI process that is usually accomplished in 2-stroke engines under the conditions of a low compression ratio, partial throttle and a large quantity of residual gas. One major difference observed between HCCI combustion and ATAC was their different degrees of susceptibility to the occurrence of cool flames, which was attributed to differences in the residual gas state. It was revealed that the ignition characteristics of these two combustion processes differed greatly in relation to the fuel octane number.

In this study, light emission and absorption spectroscopic measurement techniques were used to investigate the Homogeneous Charge Compression Ignition (HCCI) combustion process in detail, about which there have been many unclear points heretofore. The results made clear the formation behavior and wavelength bands of the chemical species produced during low-temperature reactions. Specifically, with a low level of residual gas, a light emission band was observed from a cool flame in a wavelength range of 370–470 nm. That is attributed to the light emission of formaldehyde (HCHO) produced in the cool-flame reactions. Additionally, it was found that these light emission spectra were no longer observable when residual gas was applied. The light emission spectra of the combustion flame thus indicated that residual gas has the effect of moderating cool-flame reactions.

The uniform lean methanol-air mixture was provided to the diesel engine and was ignited by the direct diesel fuel injection. The internal EGR is added to this ignition method in order to activate the fuel in the mixture and to increase the mixture temperature. The test engine was a 4-stroke, single- cylinder direct-injection diesel engine. The cooling system was forced-air cooling and displacement volume was about 211 (cm3). The compression ratio was about 19.9:1. The experiment was made under constant engine speed of 3000 (r/min). The boost pressure was maintained at 101.3 (kPa). Five values of mass flow rate of diesel fuel injection were selected from 0.060 (g/s) to 0.167 (g/s) and five levels of back pressure: 0), 26.7, 53.3, 80.0 and 106.6 (kPa) were selected for the experiment. The effect of internal EGR is varied by the back pressure level.

There is an urgent need today to improve the thermal efficiency of spark- ignition (SI) engines in order to reduce carbon dioxide emission and conserve energy in an effort to prevent global warming. However, a major obstacle to improving thermal efficiency by raising the compression ratio of SI engine is the easily occurrence of engine knocking. The result of studies done by numerous researchers have shown that knocking is an abnormal combustion in which the unburned gas in the end zone of the combustion chamber autoignites. However, the combustion reaction mechanism from autoignition to the occurrence of knocking is still not fully understood. The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.

There are strong demands today to further improve the thermal efficiency of internal combustion engines against a backdrop of various environmental issues, including rising carbon dioxide (CO2) emissions and global warming. One factor that impedes efforts to improve the thermal efficiency of spark ignition engines is the occurrence of knocking. The aim of this study was to elucidate the details of knocking based on spectroscopic measurements and visualization of phenomena in the combustion chamber of a test engine that was operated on three primary reference fuels with different octane ratings (0 RON, 30 RON, and 50 RON). The ignition timing was retarded in the experiments to delay the progress of flame propagation, making it easier to capture the behavior of low-temperature oxidation reactions at the time knocking occurred.

Attention has recently been focused on homogeneous charge compression ignition (HCCI) as an effective combustion process for resolving issues inherent to the nature of combustion. Dimethyl ether (DME; CH3OCH3) has attracted interest as a potential alternative fuel for compression ignition engines. We measured the HCCI process of DME in a test diesel engine by using a spectroscopic method. Simultaneous measurements were also done on exhaust emissions of hydrocarbons (HC), carbon monoxide (CO) and nitrogen oxides (NOx). Based on the experimental data, this paper discusses the relationship between the equivalence ratio and the observed tendencies.

This study attempted to elucidate combustion conditions in a progression from normal combustion to knocking by analyzing the ion current and light emission intensity that occurred during this transition. With the aim of understanding the combustion states involved, the ion current was measured at two positions in the combustion chamber. Light emission spectroscopy was applied to examine preflame reactions that are observed prior to autoignition in the combustion process of hydrocarbon fuels. The results obtained by analyzing the experimental data made clear the relationship between the ion current and light emission during the transition from normal combustion to knocking operation.

Regulations on exhaust emissions from light- and heavy-duty diesel engines have generated interest in high-pressure fuel injection systems. It has been recognized that high-pressure injection systems produce fuel sprays that may be more conductive to reducing exhaust emissions in direct-injection diesel engines. However, for such a system to be effective it must be matched carefully with the engine design and its operating parameters. A common-rail type of fuel injection system was investigated in the present study. The injection system utilizes an intensifier to generate injection pressures as high as 160 MPa. The fuel spray characteristics were evaluated on a test bench in a chamber containing pressurized nitrogen gas. The injection system was then incorporated in a single-cylinder diesel engine. The injection system parameters were adjusted to match engine specifications and its operating parameters.

Knocking is one phenomenon that can be cited as a factor impeding efforts to improve the efficiency of spark-ignition engines. With the aim of understanding knocking better, light emission spectroscopy was applied in this study to examine preflame reactions that can be observed prior to autoignition in the combustion reaction process of hydrocarbon fuels. Attention was focused on light emission behavior at wavelengths corresponding to those of formaldehyde (HCHO), Vaidya's hydrocarbon flame band (HCO) and the OH radical in a forced progression from normal combustion to a knocking state. Light emission behavior was measured simultaneously in the center and in the end zone of the combustion chamber when the engine was operated on two different test fuels. The test fuels used were n-heptane (0 RON) and a blended fuel (70 RON) consisting of n-heptane (0 RON) and iso-octane (100 RON).

Homogeneously charged natural gas was burned in a diesel engine assisted by a small amount of gas oil injection. The effects of the equivalence ratio of natural gas, the intake temperature and the EGR rate on ignition of gas oil, the burning rate of natural gas and the knock limit were clarified experimentally. As results, a marked improvement in the trade-off between smoke and NOx was obtained maintaining a high thermal efficiency by a combination between the natural gas charge rate, the EGR rate, the intake preheating and the nozzle orifice size suitable at each engine load.

This study examined the effects of fuel composition and intake pressure on two-stage high temperature heat release characteristics of a Homogeneous Charge Compression Ignition (HCCI) engine. Light emission and absorption spectroscopic measurement techniques were used to investigate the combustion behavior in detail. Chemical kinetic simulations were also conducted to analyze the reaction mechanisms in detail. Blended fuels of dimethyl ether (DME) and methane were used in the experiments. It was found that the use of such fuel blends together with a suitable intake air flow rate corresponding to the total injected heat value gave rise to two-stage heat release behavior of the hot flame, which had the effect of moderating combustion. The results of the spectroscopic measurements and the chemical kinetic simulations revealed that the main reaction of the first stage of the hot flame heat release was one that produced CO from HCHO.

The purpose of this research was to obtain a better understanding of engine knocking phenomena. Measurements were made of the behavior of formaldehyde (HCHO), an important intermediate product of cool flame reactions, and of the HCO radical, characterized by distinctive light emission during blue flame reactions. The test engine was operated on a blended fuel (50 RON) of n-heptane and iso-octane. Simultaneous measurements were made of the behavior of HCHO and the OH radical using absorption spectroscopy and of the behavior of HCO and OH radicals using emission spectroscopy. Absorbance spectroscopic measurements revealed behavior thought to correspond to the passage of a cool flame and emission spectroscopic measurements showed behavior thought to correspond to the passage of a blue flame.

Emission intensity was measured at a wavelength of 395 2 nm (corresponding to the characteristic spectrum of the HCHO radical) and absorbance was measured at 306 4 nm (corresponding to that of the OH radical). The emission intensity and absorbance waveforms recorded during engine operation on n-heptane show behavior indicative of the passage and degeneracy of cool flame in the preflame reaction interval. As the combustion chamber wall temperature approached an overheated state in the transition from normal combustion to knocking operation different preflame reaction behavior was observed which is thought to correspond to the presence of a negative temperature coefficient region related to the ignition delay time.

A newly-developed time resolved exhaust gas analysis system was utilized in this study. The hydrocarbon compositions upstream and downstream of the catalytic converter were investigated during cold start and warm up of the Federal Test Procedure(FTP), with three fuels of different aromatic contents. Although engine-out hydrocarbon emissions had high concentrations right after cold start, the specific reactivity was low. This can be explained by the selective adsorption of the high boiling point components which had a high Maximum Incremental Reactivity (MIR) in the intake manifold and engine-oil films. Thereafter, the high boiling point components were desorbed rapidly and consequently specific reactivity increased. Hydrocarbon adsorption of high boiling point components and hydrocarbon conversion of low boiling point components occurred simultaneously on the catalyst during warm up.