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An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

An experimental study was conducted on a spark-ignited direct-injection engine burning fuels with different evaporation and autoignition characteristics. The test engine was a single-cylinder Direct-Injection Stratified-Charge (DISC) engine incorporating a combustion process similar to the Texaco Controlled Combustion System. Two fuels were tested and compared with a baseline gasoline fuel: diesel fuel, and gasoline mixed with an ignition improver. The tests were done at low to medium engine loads. Diesel fuel was found to have similar levels of hydrocarbon (HC) emissions as gasoline but had different characteristics. The optimum timing for diesel fuel was retarded from that for gasoline and combustion variability was much less with diesel than with gasoline. Gasoline with a commercial ignition improver normally used to increase the cetane number of diesel fuel was also tested. The effect of changing the autoignition quality of the fuel depended on the injector used.

In order to understand better the operation of spark-ignition engines during the warm-up period, a computer model had been developed which simulates the thermal processes of the engine. This model is based on lumped thermal capacitance methods for the major engine components, as well as the exhaust system. Coolant and oil flows, and their respective heat transfer rates are modeled, as well as friction heat generation relations. Piston-liner heat transfer is calculated based on a thermal resistance method, which includes the effects of piston and ring material and design, oil film thickness, and piston-liner crevice. Piston/liner crevice changes are calculated based on thermal expansion rates and are used in conjunction with a crevice-region unburned hydrocarbon model to predict the contribution to emissions from this source.

The flow and heat transfer phenomena in the intake port of a spark ignition engine with port fuel injection play a significant role in the mixture preparation process, especially at part load. The backflow of the hot burned gas from the cylinder into the intake port when the intake valve is opened breaks up any liquid film around the inlet valve, influences gas and wall temperatures, and has a major effect on the fuel vaporization process. The backflow of in-cylinder mixture with its residual component during the compression stroke prior to inlet valve closing fills part of the port with gas at higher than fresh mixture temperature. To quantify these phenomena, time-resolved measurements of the hydrocarbon concentration profile along the center-line of the intake port were made with a fast-response flame ionization detector, and of the gas temperature with a fine wire resistance thermometer, in a single-cylinder engine running with premixed propane/air mixture.

In the study of internal combustion engines, gas temperatures within the system are of significant importance. The adverse conditions under firing operation, however, make measurements by any means very difficult. This current study seems to have gone the farthest to date for velocity of sound gas temperature measurements in internal combustion engine applications. An ultrasound signal is sent by a transmitting transducer, through the gas medium, and into the receiving transducer. The received signal is recorded, and the gas temperature determined from the time of flight. In-cylinder and exhaust manifold gas temperatures under fired conditions are presented, and are all consistent. Impacts of operating parameters like mixture equivalence ratio and coolant temperature are investigated.

Time-resolved heat flux and gas temperature measurements in the intake port of a spark ignition engine are presented. Experiments were pursued for motored, propane fired, and liquid fuel operation. Heat transfer coefficients were built from the dry data. Also, heat transfer rates in the port and off the back of the intake valve were integrated over the main flow phases. For a typical low-load propane-fired operating condition, heat transfer in the port caused a mean intake air temperature increase of approximately 10°C. The main different intake flow phases, induction or forward flow, displacement backflow, and valve overlap backflow, contributed approximately 10°C, 3°C, and negative 3°C, respectively. These mixture temperature changes are expected to be also applicable for liquid fuel injected cases. While the heat flux instrumentation was primarily intended for dry operation of the engine, liquid fuel experiments were also pursued.

Previous research has shown the potential benefits of running an engine with excess air. The challenges of running lean have also been identified, but not all of them have been fundamentally explained. Under high dilution levels, a lean limit is reached where combustion becomes unstable, significantly deteriorating drivability and engine efficiency, thus limiting the full potential of lean combustion. This paper expands the understanding of lean combustion by explaining the fundamentals behind this rapid rise in combustion variability and how this instability can be reduced. A flame entrainment combustion model was used to explain the fundamentals behind the observed combustion behavior in a comprehensive set of lean gasoline and hydrogen-enhanced cylinder pressure data in an SI engine. The data covered a wide range of operating conditions including different compression ratios, loads, types of dilution, fuels including levels of hydrogen enhancement, and levels of turbulence.

For some time, spatial nonuniformities in the unburned mixture within a spark ignition engine have been suspected of contributing to cycle-by-cycle variations in combustion. In this work, an experimental structure was developed that allowed the effects of fuel/air nonuniformity and residual gas/fresh charge nonuniformity to be separately addressed, with special regard given to their impact on the flame development process and combustion rate. Under the conditions of light loads and low speed, it was found that a decrease in fuel-air nonuniformity caused a slight reduction in the variation of the early flame development angle but had no significant impact on the statistics of the main combustion phase or IMEP. Eliminating residual gas nonuniformity by skip firing the engine and adding equivalent residual to the fresh mixture prior to entry to the cylinder had no detectable impact on the flame development process.

The oil control ring is the most critical component for oil consumption and friction from the piston system in internal combustion engines. Three-piece oil control rings are widely used in Spark Ignition (SI) engines. However, the dynamics and lubrication of three piece oil control rings have not been thoroughly studied from the theoretical point of view. In this work, a model was developed to predict side sealing, bore sealing, friction, and asperity contact between rails and groove as well as between rails and the liner in a Three Piece Oil Control Ring (TPOCR). The model couples the axial and twist dynamics of the two rails of TPOCR and the lubrication between two rails and the cylinder bore. Detailed rail/groove and rail/liner interactions were considered. The pressure distribution from oil squeezing and asperity contact between the flanks of the rails and the groove were both considered for rail/groove interaction.

Experiments were conducted to determine the effects of substantial spark retard on combustion, hydrocarbon (HC) emissions, and exhaust temperature, under cold engine conditions. A single-cylinder research engine was operated at 20° C fluid temperatures for various spark timings and relative air/fuel ratios. Combustion stability was observed to decrease as the phasing of the 50% mass fraction burned (MFB) occurred later in the expansion stroke. A thermodynamic burn rate analysis indicated combustion was complete at exhaust valve opening with -20° before top dead center (BTDC) spark timings. Chemical and thermal energy of the exhaust gas was tracked from cylinder-exit to the exhaust runner. Time-resolved HC concentrations measured in the port and runner were mass weighted to obtain an exhaust HC mass flow rate. Results were compared to time averaged well downstream HC levels.

Experiments to study the effects of oxygenated fuels on emissions and combustion were performed in a single-cylinder direct-injection (DI) diesel engine. A matrix of oxygen containing fuels assessed the impact of weight percent oxygen content, oxygenate chemical structure, and oxygenate volatility on emissions. Several oxygenated chemicals were blended with an ultra-low sulfur diesel fuel and evaluated at an equivalent energy release and combustion phasing. Additional experiments investigated the effectiveness of oxygenated fuels at a different engine load, a matched fuel/air equivalence ratio, and blended with a diesel fuel from the Fischer-Tropsch process. Interactions between emissions and critical engine operating parameters were also quantified. A scanning mobility particle sizer (SMPS) was used to evaluate particle size distributions, in addition to particulate matter (PM) filter and oxides of nitrogen (NOx) measurements.

A thermodynamic based cycle simulation which uses a thermal boundary layer, either, a fully mixed or layered adiabatic core, and a crevice combustion inefficiency routine has been used to explore the sensitivity of NO concentration predictions to critical physical modeling assumptions. An experimental database, which included measurements of residual gas fraction, was obtained from a 2.0 liter Nissan engine while firing on propane. A model calibration methodology was developed to ensure accurate predictions of in-cylinder pressure and burned gas temperature. Comparisons with experimental NO data then showed that accounting for temperature stratification during combustion with a layered adiabatic core and including a crevice/combustion inefficiency routine, improved the match of modeling predictions to data, in comparison to a fully mixed adiabatic core.

An experimental study was performed to investigate the effects of various intake charge motion control valves (CMCVs) on mixture preparation, combustion, and hydrocarbon (HC) emissions during the cold start-up process of a port fuel injected spark ignition (SI) engine. Different charge motions were produced by three differently shaped plates in the CMCV device, each of which blocked off 75% of the engine's intake ports. Time-resolved HC, CO and CO2 concentrations were measured at the exhaust port exit in order to achieve cycle-by-cycle engine-out HC mass and in-cylinder air/fuel ratio. Combustion characteristics were examined through a thermodynamic burn rate analysis. Cold-fluid steady state experiments were carried out with the CMCV open and closed. Enhanced charge motion with the CMCV closed was found to shorten the combustion duration, which caused the location of 50% mass fraction burned (MFB) to occur up to 5° CA earlier for the same spark timing.

In an effort to both increase engine efficiency and generate new, consistent, and reliable data useful for the development of engine concepts, a modern single-cylinder 4-valve spark-ignition research engine was used to determine the response of indicated engine efficiency to combustion phasing, relative air-fuel ratio, compression ratio, and load. Combustion modeling was then used to help explain the observed trends, and the limitations on achieving higher efficiency. This paper analyzes the logic behind such gains in efficiency and presents correlations of the experimental data. The results are helpful for examining the potential for more efficient engine designs, where high compression ratios can be used under lean or dilute regimes, at a variety of loads.

A set of experiments was performed to investigate the effects of relative air-fuel ratio, inlet boost pressure, and compression ratio on engine knock behavior. Selected operating conditions were also examined with simulated hydrogen rich fuel reformate added to the gasoline-air intake mixture. For each operating condition knock limited spark advance was found for a range of octane numbers (ON) for two fuel types: primary reference fuels (PRFs), and toluene reference fuels (TRFs). A smaller set of experiments was also performed with unleaded test gasolines. A combustion phasing parameter based on the timing of 50% mass fraction burned, termed “combustion retard”, was used as it correlates well to engine performance. The combustion retard required to just avoid knock increases with relative air-fuel ratio for PRFs and decreases with air-fuel ratio for TRFs.

A conventional spark plug and a spark plug with smaller electrodes were studied in M.I.T.'s transparent square piston engine. The purpose was to learn more about how the electrode geometry affects the heat losses to the electrodes and the electrical performance of the ignition system, and how this affects the flame development process in an engine. A schlieren system which provides two orthogonal views of the developing flame was used to define the initial flame growth process, for as many as 100 consecutive cycles. Voltage and current waveforms were recorded to characterize the spark discharge, and cylinder pressure data were used to characterize the engine performance. The spark plug with the smaller electrodes was shown to reduce the heat losses to the electrodes, and thereby extend the stable operating regime of the engine. At conditions close to the stable operating limit, cycle-by-cycle variations in heat losses cause significant cyclic variations in flame development.

This paper explores the modeling of a lean boosted engine concept. Modeling provides a useful tool for investigating different parameters and comparing resultant emissions and fuel economy performance. An existing architectural concept has been tailored to a boosted hydrogen-enhanced lean-burn SI engine. The simulation consists of a set of Matlab models, part physical and part empirical, which has been developed to simulate a working engine. The model was calibrated with production engine data and experimental data taken at MIT. Combustion and emissions data come from a single cylinder research engine and include changes in air/fuel ratio, load and speed, and different fractions of the gasoline fuel reformed to H2 and CO. The outputs of the model are brake specific NOx emissions and brake specific fuel consumption maps along with cumulative NOx emissions and fuel economy for urban and highway drive cycles.

The prediction of knock onset in spark-ignition engines requires a chemical model for the autoignition of the hydrocarbon fuel-air mixture, and a description of the unburned end-gas thermal state. Previous studies have shown that a reduced chemistry model developed by Keck et al. adequately predicts the initiation of autoignition. However, the combined effects of heat transfer and compression on the state of the end gas have not been thoroughly investigated. The importance of end-gas heat transfer was studied with the objective of improving the ability of our knock model to predict knock onset over a wide range of engine conditions. This was achieved through changing the thermal environment of the end gas by either varying the inlet air temperature or the coolant temperature. Results show that there is significant heating of the in-cylinder charge during intake and a substantial part of the compression process.

A single-zone burn-rate analysis based on measured cylinder pressure data proposed by Gatowski et al. in 1984 was evaluated over the full load and speed range of a spark-ignition engine. The analysis, which determines the fuel mass burning rate based on the First Law of Thermodynamics, includes sub-models for the effects of residual fraction, heat transfer, and crevices. Each of these sub-models was assessed and calibrated. Cylinder pressure data over the full engine operating range obtained from two different engines were used to examine the robustness of the analysis. The sensitivity of predictions to the parameters wall temperature, heat transfer model coefficients and exponent, swirl ratio, motoring polytropic constant, in-cylinder mass, and to uncertainty in pressure data was evaluated.

This paper provides an overview of spark-ignition engine unburned hydrocarbon emissions mechanisms, and then uses this framework to relate measured engine-out hydrocarbon emission levels to the processes within the engine from which they result. Typically, spark-ignition engine-out HC levels are 1.5 to 2 percent of the gasoline fuel flow into the engine; about half this amount is unburned fuel and half is partially reacted fuel components. The different mechanisms by which hydrocarbons in the gasoline escape burning during the normal engine combustion process are described and approximately quantified. The in-cylinder oxidation of these HC during the expansion and exhaust processes, the fraction which exit the cylinder, and the fraction oxidized in the exhaust port and manifold are also estimated.