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Developing relatively cheap and widely available resources for heterogeneous solid catalyst synthesis is a promising approach for biodiesel fuel industry. Seashell which is essentially calcium carbonate can be used as a basic support for transesterification heterogeneous catalysts. In the present investigation, the alcoholysis of waste frying oil has been carried out using seashell-supported K3 PO4 as solid catalyst. Presenter Essam Oun Al-Zaini, PhD student, UNSW

Abstract A methodology for the development of catalyst models is presented. Also, a methodology of the implementation of such models into a modular simulation tool, which simulates the units in succession, is presented. A case study is presented illustrating how suitable models can be found and used for simulations. Such simulations illustrate the behavior of the individual units and the overall system. It is shown how, by simulating the units in succession, the entire after treatment system can be tested and optimized, because the integration makes it possible to observe the effect of the modules on one another.

Abstract Dynamic stresses exist in parts of a catalyst muffler caused by the vibration of a moving vehicle, and it is important to clarify and predict the vibration response properties for preventing fatigue failures. Assuming a vibration isolating installation in the vehicle frame, the vibration transmissibility and local dynamic stress of the catalyst muffler were examined through a vibration machine. Based on the measured data and by systematically taking vibration theories into consideration, a new prediction method of the vibration modes and parameters was proposed that takes account of vibration isolating and damping. A lumped vibration model with the six-element and one mass point was set up, and the vibration response parameters were analyzed accurately from equations of motion. In the vibration test, resonance peaks from the hanging bracket, rubber bush, and muffler parts were confirmed in three excitation drives, and local stress peaks were coordinate with them as well.

Abstract The selective catalytic reduction (SCR) of nitrogen oxides seems to be the most promising technique to meet prospective emission regulations of diesel-driven commercial vehicles. In the case of developing cost-effective catalytic converters with comparably high activity, selectivity, and resistance against aging, ion-exchanged zeolites play a major role. This study presents, firstly, a brief literature review and subsequently a discussion of an extensive conversion analysis of exemplary Cu/ and Fe/zeolites, as well as a homogeneous admixture of both. The aging stages of SCR catalysts deserve particular attention in this study. In addition, the aging condition of the diesel oxidation catalyst (DOC) was analyzed, which influences the nitrogen dioxide (NO2) formation, because the NO2/nitrogen oxides (NOx) ratio upstream from the SCR converter could be identified as a key factor for low temperature NOx conversion.

Abstract Powertrain simulations and catalyst studies showed the efficiency credits and feasibility of onboard reforming as a way to recover waste heat from heavy duty vehicles (HDVs) fueled by natural gas (NG). Onboard reforming involves 1) injecting NG into the exhaust gas recycle (EGR) loop of the HDV, 2) reforming NG on a catalyst in the EGR loop to hydrogen and carbon monoxide, and 3) combusting the reformed fuel in the engine. The reformed fuel has increased heating value (4-10% higher LHV) and flame speed over NG, allowing stable flames in spark ignition (SI) engines at EGR levels up to 25-30%. A sulfur-tolerant reforming catalyst was shown to reform a significant amount of NG (15-30% conversion) using amounts of precious metal near the current practice for HDV emissions control (10 g rhodium). Engine simulations showed that the high EGR levels enabled by onboard reforming are used most effectively to control engine load instead of waste-gating or throttling.

With the growing environmental concerns, biodegradable materials are gaining more importance. Biocomposites which are made from a combination of biological fiber such as flax and hemp together with plastics are finding a good number of applications in day to day life. Flax has good physical and mechanical properties that can be utilized in areas like construction, biomedical & bioproducts and electronics applications. The quality of fiber depends upon various unit operations used in the processing. Drying is one of the most important unit operations which significantly affect the quality of the fiber. The method of drying for removal of moisture from the fiber significantly affects the drying time and quality. In the present study the raw flax fiber was subjected to drying before and after chemical treatment. The physical properties such as; tensile strength, color and structural changes were measured for raw and chemically treated flax fibers.

Selective Catalytic Reduction (SCR) catalysts have been demonstrated as an effective solution for controlling NOx emissions from diesel engines. There is a drive to reduce the overall packaging volume of the aftertreatment system for these applications. In addition, more active SCR catalysts will be needed as the applications become more challenging: e.g. lower temperatures and higher engine out NOx, for fuel consumption improvements. One approach to meet the challenges of reduced volume and/or higher NOx reduction is to increase the active site density of the SCR catalyst by coating higher amount of SCR catalyst on high porosity substrates (HPS). This approach could enable the reduction of the overall packaging volume while maintaining similar NOx conversion as compared to 2010/2013 systems, or improve the NOx reduction performance for equivalent volume and NH3 slip.

Recent advances in natural gas (NG) recovery technologies and availability have sparked a renewed interest in using NG as a fuel for commercial vehicles. NG can potentially provide both reduced operating cost and reductions in CO2 emissions. Commercial NG vehicles, depending on application and region, have different performance and fuel consumption targets and are subject to various emissions regulations. Therefore, different applications may require different combustion strategies to achieve specific targets and regulations. This paper summarizes an evaluation of combustion strategies and parameters available to meet these requirements while using NG in a spark ignited engine. A single-cylinder research engine using a modified diesel cylinder head was employed for this study. Both stoichiometric combustion with cooled exhaust gas recirculation (EGR) and lean-burn were evaluated.

Catalysts and filters continue to be applied widely to meet particulate matter regulations across new and retrofit diesel engines. Soot management of the filter continues to be enhanced, including regeneration methodologies. Concerns regarding in-cylinder post-injection of fuel for active regeneration increases interests in directly injecting this fuel into the exhaust. Performance of secondary fuel injection layouts is discussed, and sensitivities on thermal uniformity are measured and analyzed, providing insight to packaging challenges and methods to characterize and improve application designs. Influences of end cone geometries, mixers, and injector mounting positions are quantified via thermal distribution at each substrate's outlet. A flow laboratory is applied for steady state characterization, repeated on an engine dynamometer, which also provides transient results across the NRTC.

Engine mounts are an integral part of the vehicle that helps in reducing the vibrations generated from the engine. Engine mounts require a simple yet complicated amalgamation of two very different materials, steel and rubber. Proper adhesion between the two is required to prevent any part failure. Therefore, it becomes important that a comprehensive study is done to understand the mating phenomenon of both. A good linking between rubber and metal substrate is governed by surface pretreatment. Various methodologies such as mechanical and chemical are adopted for the same. This paper aims to present a comparative study as to which surface pretreatment has an edge over other techniques in terms of separation force required to break the bonding between the two parts. The study also presents a cost comparison between the techniques so that the best possible technique can be put to use in the commercial vehicle industry.

Euro 6 emission norms are getting implemented in India from April 2020 and it is being viewed as one of the greatest challenges ever faced by the Indian automotive industry. In order to achieve such stringent emission norms along with top performance for vehicle, a good strategy should be incorporated to control system out NOx emissions and soot regeneration. Extruded Vanadium catalyst is deployed for this passive regeneration system with DOC (Diesel Oxidation Catalyst), DPF (Diesel Particulate Filter) and SCR (Selective Catalyst Reduction), where the amount of catalyst loading in DOC plays an apex role in deciding conversion efficiency of SCR and passive regeneration capabilities. This study mainly focuses on the impact of catalyst loading of DOC over SCR efficiency. NO2 to NOx ratio should be close to 0.5 for optimum conversion efficiency of SCR. Catalyst loading in DOC decides the amount of NO2 coming upstream to SCR.

1 One issue raised by the use of austenitic stainless steels in commercial vehicles is the increase in material costs. To reduce those material costs, a nitric acid electropolishing treatment was applied to SUS436L (18 Cr - 1.5 Mo - 0.4 Nb) and corrosion tests were conducted to compare its corrosion resistance to that of SUS316L(16 Cr - 12 Ni - 2 Mo). Compared to SUS316L, SUS436L subjected to nitric acid electropolishing indicated superior corrosion resistance. In addition, XPS and TEM analyses showed that while the SUS436L passivation film layer contained approximately twice as much chromium, its thickness was also generally reduced by approximately half, to 2 nm. These results suggest that electropolishing with nitric acid, which is highly oxidative, formed a fine passivation film.

In this study a 1-dimensional computational model of a Fe-Zeolite catalyst, implementing conservation of mass, species and energy for both gas and catalyst surface phases has been developed to simulate emissions conversion performance. It is applied to both a fresh catalyst and one that has been aged through exposure to the exhaust system of a Heavy Duty Diesel engine performing in the field for 376K miles. Details of the chemical kinetics associated with the various NOx reduction reactions in the two Fe-Zeolite configurations have been examined and correlated with data from a synthetic gas rig test bench. It was found that the Standard reaction, (4NH3 + 4NO + O2 → 2N2 + 6H2O), which is one of the main reactions for NOx reduction, degraded significantly at the lower temperatures for the aged system.

This paper describes the potential for the use of Dedicated EGR® (D-EGR®) in a gasoline powered medium truck engine. The project goal was to determine if it is possible to match the thermal efficiency of a medium-duty diesel engine in Class 4 to Class 7 truck operations. The project evaluated a range of parameters for a D-EGR engine, including displacement, operating speed range, boosting systems, and BMEP levels. The engine simulation was done in GT-POWER, guided by experimental experience with smaller size D-EGR engines. The resulting engine fuel consumption maps were applied to two vehicle models, which ran over a range of 8 duty cycles at 3 payloads. This allowed a thorough evaluation of how D-EGR and conventional gasoline engines compare in fuel consumption and thermal efficiency to a diesel. The project results show that D-EGR gasoline engines can compete with medium duty diesel engines in terms of both thermal efficiency and GHG emissions.

Control of N2O emissions is a significant challenge for manufacturers of HDD On-Road engines and vehicles due to requirements for NOx control and Green House Gas (GHG) Phases I & II requirements. OEMs continually strive to improve BSFE which often results in increased engine out NOx (EO NOx) emissions. Consequently, the necessity for higher NOx conversions results in increased N2O emissions over traditional SCR and SCR+ASC catalysts systems [1]. This study explores methods to improve NOx conversion while reducing the SCR contribution of N2O across the exhaust after treatment systems. For example, combinations of two traditional SCR catalysts, one Iron based and another Copper based, can be utilized at various proportions by volume to optimize their SCR efficiency while minimizing the N2O emissions. Results show that a proper combination of catalysts volume can significantly reduce N2O levels while simultaneously reaching the highest levels of NOx performance achieved in the study.

Research activities in the development of reliable computational models for aftertreatment systems are constantly increasing in the automotive field. These investigations are essential in order to get a complete understanding of the main catalytic processes which clearly have a great impact on tailpipe emissions. In this work, a 1D chemical reaction model to simulate the catalytic activity of a Pd/Rh Three-Way Catalyst (TWC) for a Natural Gas heavy-duty engine is presented. An extensive database of tests carried out with the use of a Synthetic Gas Bench (SGB) has been collected to investigate the methane abatement pathways, linked to the lambda variation and oxide formation on palladium surface. Specific steady-state tests have shown a dynamics of the methane conversion even at fixed λ and temperature conditions, essentially due to the Pd/PdO ratio.

This SAE Standard provides a comprehensive list of requirements for the selection, identification, and control of metric and inch sized fasteners for use in shipboard applications for both shipbuilder installed joints and for use in shipboard components. The fastener selection requirements include the following: a Materials b Thread selection c Plating, coatings, and surface treatments d Locking devices and elements e Screw thread fastener inserts f Fastener part or identifying numbers g Identification markings

This Hydrospace Information Report (HIR) identifies the general environmental considerations for the design, development, evaluation, and testing of advanced surface craft, submersible vehicles, and other marine craft. This HIR provides criteria on the environmental limits within which marine vehicles, related components, and associated equipment should operate satisfactorily and reliably. This HIR is intended for use as a guide for the development of specific environmental requirements to be included in detailed specifications for marine vehicles and associated equipment. Specific requirements are in a state of continual change as our knowledge of the ocean environment increases. The ocean environment varies with location and time. Changes in the ocean environment can occur not only on a seasonal basis but also monthly, weekly, daily, and in some cases even hourly.

This Hydrospace Information Report (HIR) identifies the general environmental considerations for the design, development, evaluation, and testing of advanced surface craft, submersible vehicles, and other marine craft. This HIR provides criteria on the environmental limits within which marine vehicles, related components, and associated equipment should operate satisfactorily and reliably.

La1-xAxNi1-yByO3 nanostructured perovskite-type oxides catalysts (where A = Na, K, Rb and B = Cu; x = 0, 0.2 and y = 0, 0.05, 0.1), also supporting 2% in weight of gold, were prepared via the so-called “Solution Combustion Synthesis (SCS)” method, and characterized by means of XRD, BET, FESEM-EDS and TEM analyses. The performance of these catalysts towards the simultaneous oxidation of soot and CO was evaluated. The 2 wt.% Au-La0.8K0.2Ni0.9Cu0.1O3 showed the best performance with a peak carbon combustion temperature of 367 °C and the half conversion of CO reached at 141 °C. The same nanostructured catalyst, deposited by in situ SCS directly over a SiC filter and tested on real diesel exhaust gases, fully confirmed the encouraging results obtained on the powder catalyst.