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In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. This report is designed to determine how high biodiesel blends affect oil quality through testing on 2005 regulations engines with DPFs. When blends of 10-20% rapeseed methyl ester (RME) with diesel fuel are employed with 10W-30 engine oil, the oil change interval is reduced to about a half due to a drop in oil pressure. The oil pressure drop occurs because of the reduced kinematic viscosity of engine oil, which resulting from dilution of poorly evaporated RME with engine oil and its accumulation, however, leading to increased wear of piston top rings and cylinder liners.

Diesel emissions are significant issue worldwide, and emissions requirements have become so tough that. the application of after-treatment systems is now indispensable in many countries To meet even more stringent future emissions requirements, it has become apparent that the improvement of market fuel quality is essential as well as the development in engine and exhaust after-treatment technology. Japan Clean Air Program II (JCAP II) is being conducted to assess the direction of future technologies through the evaluation of current automobile and fuel technologies and consequently to realize near zero emissions and carbon dioxide (CO2) emission reduction. In this program, effects of fuel properties on the performance of diesel engines and a vehicle equipped with two types of diesel NOx emission after-treatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined.

An investigation of throttle response of engines during warm-up was conducted using various gasolines. Test data were obtained from an engine on a test bench at intermediate temperature around 20∼ 30 °C. By using the engine test bench data, correlation coefficients between engine response time and gasoline characteristics were calculated. The result shows that the middle range of distillation temperature is an important factor in gasoline characteristics for warm-up driveability of fuel injected engines. It also shows that 50% distillation temperature can be used as one indication of warm-up driveability. This indication is effective only for hydrocarbon type gasolines. In the case of MTBE blended gasoline, the distillation temperature becomes low when MTBE is blended to gasoline, but throttle response was not improved. It is also found that the effect of gasoline distillation on throttle response is enhanced by intake valve deposits.

Fifty percent distillation temperature (T50) can be used as a warm-up driveability indicator for a hydrocarbon-type gasoline. MTBE-blended gasoline, however, provides poorer driveability than a hydrocarbon-type gasoline with the same T50. The purposes of this paper are to examine the reason for poor engine driveability caused by MTBE-blended gasolines, and to propose a new driveability indicator for gasolines including MTBE-blended gasolines. The static and dynamic evaporation characteristics of MTBE-blended gasolines such as the evaporation rate and the behavior of each component during evaporation were analyzed mainly by using Gas Chromatography/Mass Spectrometry. The results of the analysis show that the MTBE concentration in the vapor, evaporated at ambient temperature (e.g. 24°C), is higher than that in the original gasoline. Accordingly, the fuel vapor with enriched MTBE flows into the combustion chamber of an engine just after the throttle valve is opened.

An improvement of thermal efficiency of internal combustion engines is strongly required. Meanwhile, from the viewpoint of refinery, CO2 emissions and gasoline price decrease when lower octane gasoline can be used for vehicles. If lower octane gasoline is used for current vehicles, fuel consumption rate would increase due to abnormal combustion. However, if a Homogeneous Charge Compression Ignition (HCCI) engine were to be used, the effect of octane number on engine performance would be relatively small and it has been revealed that the thermal efficiency is almost unchanged. In this study, the engine performance estimation of HCCI combustion using lower octane gasoline as a vision of the future engine was achieved. To quantitatively investigate the fuel consumption performance of a gasoline HCCI engine using lower octane fuel, the estimation of fuel consumption under different driving test cycles with different transmissions is carried out using 1D engine simulation code.

Engine dynamometer tests were conducted to evaluate the effect of detergent additives and gasoline components on Combustion Chamber Deposits (CCD). Additives with polyether amine (PEA) and with polyolefin amine (POA) chemicals were used. Three kinds of POA additives were used. Our results show that some kinds of additives and aromatics in gasoline increase CCD formation. Different polyolefin detergents show different tendency of CCD formation. The amount of CCD showed good relationship with the unwashed gum level of the gasoline. In general, smaller dosages produce less CCD. This means that detergents which have good IVD and PFID effectiveness at smaller dosage are better with regard to CCD. We analyzed the CCD by C13-NMR, GPC and IR method. The detergent contributes to CCD. Vehicle emissions tests were carried out to evaluate the effects of CCD on exhaust emissions.

The properties of diesel fuels were investigated in terms of particulate emissions to clarify the specification of such a diesel fuel for minimizing particulate emissions. Diesel fuels were analyzed using thin layer chromatography (TLC), and gas chromatography/mass spectrometry (GC/MS). These analysis revealed the entire composition of hydrocarbons in diesel fuels according to molecular formula. The entire composition of hydrocarbons in diesel fuels could be expressd on a three-dimensional graph: the X-axis as carbon number, the Y-axis as H/C ratio and the Z-axis as the amount of hydrocarbons of identical molecular formula. By using the graph, the properties reported so far were investigated. Also, simplified images of the fuel sprayed into a cylinder and its flame were derived from the observational results previously reported.

In recent years, alternative sources of fuel are receiving a lot of attention in the automotive industry. Fuels derived from an agricultural feedstock are an attractive option. Bio-fuels based on vegetable oils offer the advantage being a sustainable, annually renewable source of automobile fuel. One of key issues in using vegetable oil based fuels is its oxidation stability. Since diesel fuels from fossil oil have good oxidation stability, automobile companies have not considered fuel degradation when developing diesel engines and vehicles as compared with gasoline engines. This paper presents the results of oxidation stability testing on bio-fuels. Oxidation stability was determined using three test methods, ASTM D525, EN14112 and ASTM D2274. The effects of storage condition, bio-fuel composition and antioxidants on the degradation of bio-fuels were all investigated. ASTM D525 is an effective test method to determine the effects of storage condition on bio-fuels stability.

Combustion chamber deposits (CCD) in wall-guided stratified charged direct injection spark ignition (DISI) engines affect combustion significantly because CCD may disturb the air-fuel mixture formation and, as a result, cause emission deterioration. For the design of engines and fuels, it is therefore important to determine the effects of CCD on emissions from DISI engines. In this study, the effects of CCD on emissions from a DISI engine using different fuel distillation properties were investigated. The study results show that, during stratified charged operation, an increase in CCD increased the total hydrocarbon (THC) emissions under high speed conditions and the NOx emissions under the low speed conditions.