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Source apportionment analysis for exposure to air toxics from conventional and oxygenated fuel was performed for different microenvironments. Personal toxic exposure data were taken from previous studies conducted in areas where MTBE oxygenated fuels were used. Refueling, commuting, and occupational microenvironments were all examined. The emission source, either tailpipe or evaporative, was estimated using the ratio of MTBE/benzene as an emission finger print. ASPEN simulations were completed to estimate the MTBE to benzene ratio for evaporative emissions from vapor above the fuel using vapor-liquid equilibrium models. Expected MTBE to benzene ratios in the tailpipe exhaust were obtained from previous studies. Refueling exposure was found to be dominated by evaporative emissions, specifically flash from the fuel tank for stations with Stage I controls, and evaporation of whole fuel for stations with Stage II controls.

The role of the catalyst in regeneration of catalytic particulate traps was found to be the oxidation of gaseous fuel species, such as carbon monoxide and hydrocarbons, in the exhaust. Energy released by the oxidation of fuel on the catalyst surface heats the trap to the temperature at which combustion of trapped particulate matter can occur. Experiments with both commercial and prototype catalytic particulate traps demonstrated that the traps could be reliably regenerated by enriching the exhaust with either propane or diesel fuel. Using a DD6V-71N coach engine and a prototype catalytic particulate trap, a trap regeneration system was developed which delivers vaporized diesel fuel to the exhaust, upstream of the catalytic particulate trap. The system has no moving parts in contact with the exhaust gas and allows reliable trap regeneration under full exhaust flow. An un-optimized fuel efficiency penalty of less than 1.6% was demonstrated for this regeneration method.

Methane emissions from lean-burn natural gas engines can be relatively high. As natural gas fueled vehicles become more prevalent, future regulations may restrict these emissions. Preliminary reports indicated that conventional, precious metal oxidation catalysts rapidly deactivate (in less than 50 hours) in lean-burn natural gas engine exhaust. This investigation is directed at quantifying this catalyst deactivation and understanding its cause. The results may also be relevant to oxidation of lean-burn propane and gasoline engine exhaust. A platinum/palladium on alumina catalyst and a palladium on alumina catalyst were aged in the exhaust of a lean-burn natural gas engine (Cummins B5.9G). The engine was fueled with compressed natural gas. Catalyst aging was accomplished through a series of steady state cycles and heavy-duty transient tests (CFR 40 Part 86 Subpart N) lasting 10 hours. Hydrocarbons in the exhaust were speciated by gas chromatography.

Regulated emissions (THC, CO, NOx, and PM) and particulate SOF and sulfate fractions were determined for a 1995 Detroit Diesel Series 50 urban bus engine at varying fuel sulfur levels, with and without catalytic converters. When tested on EPA certification fuel without an oxidation catalyst this engine does not appear to meet the 1994 emissions standards for heavy duty trucks, when operating at high altitude. An ultra-low (5 ppm) sulfur diesel base stock with 23% aromatics and 42.4 cetane number was used to examine the effect of fuel sulfur. Sulfur was adjusted above the 5 ppm level to 50, 100, 200, 315 and 500 ppm using tert-butyl disulfide. Current EPA regulations limit the sulfur content to 500 ppm for on highway fuel. A low Pt diesel oxidation catalyst (DOC) was tested with all fuels and a high Pt diesel oxidation catalyst was tested with the 5 and 50 ppm sulfur fuels.

Natural gas presents several challenges to engine manufacturers for use as a heavy-duty, lean burn engine fuel. This is because natural gas can vary in composition and the variation is large enough to produce significant changes in the stoichiometry of the fuel and its octane number. Similarly, operation at high altitude can present challenges. The most significant effect of altitude is lower barometric pressure, typically 630 mm Hg at 1600 m compared to a sea level value of 760 mm. This can lower turbocharger boost at low speeds leading to mixtures richer than desired. The purpose of this test program was to determine the effect of natural gas composition and altitude on regulated emissions and performance of a Cummins B5.9G engine. The engine is a lean-burn, closed loop control, spark ignited, dedicated natural gas engine. For fuel composition testing the engine was operating at approximately 1600 m (5,280 ft) above sea level.

The objective of the work described here is to test the performance of closed-loop controlled, heavy-duty CNG engines in-use, on fuels of different methane content; and to compare their performance with similar diesel vehicles. Performance is measured in terms of pollutant emissions, fuel economy, and driveability. To achieve this objective, three buses powered by closed-loop controlled, dedicated natural gas engines were tested on the heavy-duty chassis dynamometer facility at the Colorado Institute for Fuels and High Altitude Engine Research (CIFER). Emissions of regulated pollutants (CO, NOx, PM, and THC or NMHC), as well as emissions of alde-hydes for some vehicles, are reported. Two fuels were employed: a high methane fuel (90%) and a low methane fuel (85%). It was found that the NOx, CO, and PM emissions for a given cycle and vehicle are essentially constant for different methane content fuels.

Emissions of six 32 passenger transit buses were characterized using one of the West Virginia University (WVU) Transportable Heavy Duty Emissions Testing Laboratories, and the fixed base chassis dynamometer at the Colorado Institute for Fuels and High Altitude Engine Research (CIFER). Three of the buses were powered with 1997 ISB 5.9 liter Cummins diesel engines, and three were powered with the 1997 5.9 liter Cummins natural gas (NG) counterpart. The NG engines were LEV certified. Objectives were to contrast the emissions performance of the diesel and NG units, and to compare results from the two laboratories. Both laboratories found that oxides of nitrogen and particulate matter (PM) emissions were substantially lower for the natural gas buses than for the diesel buses. It was observed that by varying the rapidity of pedal movement during accelerations in the Central Business District cycle (CBD), CO and PM emissions from the diesel buses could be varied by a factor of three or more.