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The Vapor Phase Catalytic Ammonia Removal (VPCAR) system is being developed to recycle water for future NASA Exploration Missions [1,2,3,4,5]. Reduced gravity testing of the VPCAR System has been initiated to identify any potential problems with microgravity operation. Two microgravity testing campaigns have been conducted on NASA's C-9B Reduced Gravity Aircraft. These tests focused on the fluid dynamics of the unit's Wiped-Film Rotating Disk (WFRD) evaporator. The experiments used a simplified system to study the process of forming a thin film on a rotating disk. The configuration simulates the application of feed in the VPCAR's WFRD evaporator. The first round of aircraft testing, which was completed in early 2006, indicated that a problem with microgravity operation of the WFRD existed. It was shown that in reduced gravity the VPCAR wiper did not produce a uniform thin film [6]. The film was thicker near the axis of rotation where centrifugal forces are small.

The Vapor Phase Catalytic Ammonia Removal (VPCAR) technology has been previously discussed as a viable option for the Exploration Water Recovery System. This technology integrates a phase change process with catalytic oxidation in the vapor phase to produce potable water from exploration mission wastewaters. A developmental prototype VPCAR was designed, built and tested under funding provided by a National Research Announcement (NRA) project. The core technology, a Wiped Film Rotating Device (WFRD) was provided by Water Reuse Technologies under the NRA, whereas Hamilton Sundstrand Space Systems International performed the hardware integration and acceptance test of the system. Personnel at the Ames Research Center performed initial systems test of the VPCAR using ersatz solutions. To assess the viability of this hardware for Exploration Life Support (ELS) applications, the hardware has been modified and tested at the MSFC ECLS Test Facility.

Direct osmotic concentration (DOC) is a membrane treatment process for reclamation of space craft wastewater. It incorporates a novel system architecture that includes a forward osmosis (FO) and reverse osmosis (RO) subsystem for hygiene (gray) water, and a membrane distillation subsystem for the treatment of urine and humidity condensate. The products of these subsystems are combined and then post-treated by a catalytic oxidation subsystem. This paper documents progress made during the second year of a three year Rapid Technology Development Team (RTDT) effort.

For wastewater treatment applications, membrane processes are known to provide excellent treatment but are subject to failure due to membrane fouling. The Direct Osmotic Concentration (DOC) system evaluated in this study provides a membrane based primary treatment process capable of overcoming this problem. A full scale test apparatus containing full scale test module membrane cells has been developed and has undergone preliminary testing that provides a basis for comparison with other primary water recycle process concepts. This study confirms and extends the initial testing of this hardware and determines the required improvements to the existing test mo dules. These improvements, in addition to future testing, are intended to complete the validation of the concept and mature the hardware to the point that human rated test equipment design and development can be based directly on the test module derived data.

The purification of waste water is a critical element of any long-duration space mission. The Vapor Phase Catalytic Ammonia Removal (VPCAR) system offers the promise of a technology requiring low quantities of expendable material that is suitable for exploration missions. NASA has funded an effort to produce an engineering development unit specifically targeted for integration into the NASA Johnson Space Center's Integrated Human Exploration Mission Simulation Facility (INTEGRITY) formally known in part as the Bioregenerative Planetary Life Support Test Complex (Bio-Plex) and the Advanced Water Recovery System Development Facility. The system includes a Wiped-Film Rotating-Disk (WFRD) evaporator redesigned with micro-gravity operation enhancements, which evaporates wastewater and produces water vapor with only volatile components as contaminants. Volatile contaminants, including organics and ammonia, are oxidized in a catalytic reactor while they are in the vapor phase.

An energy-efficient lyophilization technique is being developed to recover water from highly contaminated spacecraft waste streams. In the lyophilization process, water in an aqueous waste is frozen and then sublimed, separating the waste into a dried solid material and liquid water. This technology is ideally suited to applications such as the Mars Reference Mission, where water recovery rates approaching 100% are desirable but production of CO2 is not. Candidate wastes include feces, concentrated brines from water processors, and other solid wastes that contain water. To operate in microgravity, and to minimize power consumption, thermoelectric heat pumps can be used in place of traditional fluid cycle heat pumps. A mathematical model of a thermoelectric lyophilizer is described and used to generate energy use and processing rate estimates.

This project is a Phase III SBIR contract between NASA and Water Reuse Technology (WRT). It covers the redesign, modification, and construction of the Wiped-Film Rotating-Disk (WFRD) evaporator for use in microgravity and its integration into a Vapor Phase Catalytic Ammonia Removal (VPCAR) system. VPCAR is a water processor technology for long duration space exploration applications. The system is designed as an engineering development unit specifically aimed at being integrated into NASA Johnson Space Center's Bioregenerative Planetary Life Support Test Complex (BIO-Plex). The WFRD evaporator and the compressor are being designed and built by WRT. The balance of the VPCAR system and the integrated package are being designed and built by Hamilton Sundstrand Space Systems International, Inc. (HSSSI) under a subcontract with WRT. This paper provides a description of the VPCAR technology and the advances that are being incorporated into the unit.

Direct osmotic concentration (DOC) has been identified as a potential wastewater treatment process for potable reuse in advanced life support systems (ALSS). As a result, further development of the DOC process is being supported by a NASA Rapid Technology Development Team (RTDT) program. DOC is an integrated membrane system combining three unique membrane separation processes including forward osmosis (FO), membrane distillation (MD), and reverse osmosis (RO) that is designed to treat separate wastewater streams comprising hygiene wastewater, humidity condensate, and urine. An aqueous phase catalytic oxidation (APCO) process is incorporated as post treatment for the product water. In an ongoing effort to improve the DOC process and make it fully autonomous, further development of the three membrane technologies is being pursued.

This study introduces new concepts in the function and placement of membrane based water treatment processes in Exploration Life Support (ELS) System design. These differences are in both form and function and have the potential to radically alter the current paradigms of thought within the ELS research community with regards to the limitations of conventional membrane water treatment. More importantly, they have the potential to change the placement of water processing by quite literally moving it “out of the box”, or in the case of ELS, the standard rack volume. Two possible systems, extremely small scale personal urine treatment and recycle (CEV Lightweight Contingency Water Treatment) and a similar but scaled up habitat wall embedded membrane water treatment pouch, are used to demonstrate the concepts involved.

The Vapor Phase Catalytic Ammonia Removal (VPCAR) system is being developed to recycle water for future NASA Exploration Missions. Testing was recently conducted on NASA's C-9B Reduced Gravity Aircraft to determine the microgravity performance of a key component of the VPCAR water recovery system. Six flights were conducted to evaluate the fluid dynamics of the Wiped-Film Rotating Disk (WFRD) distillation component of the VPCAR system in microgravity, focusing on the water delivery method. The experiments utilized a simplified system to study the process of forming a thin film on a disk similar to that in the evaporator section of VPCAR. Fluid issues are present with the current configuration, and the initial alternative configurations were only partial successful in microgravity operation. The underlying causes of these issues are understood, and new alternatives are being designed to rectify the problems.

Dewatering of wet waste during space exploration missions is important for crew safety as it stabilizes the waste. It may also be used to recover water and serve as a preconditioning step for waste compaction. A thermoelectric cooler (TEC)- driven lyophilizer is under development at NASA Ames Research Center for this purpose. It has three major components: (i) an evaporator section where water vapor sublimes from the frozen waste, (ii) a condenser section where this water vapor deposits as ice, and (iii) a TEC section which serves as a heat pump to transfer heat from the condenser to the evaporator. This paper analyses the heat and mass transfer processes in the lyophilizer in an effort to understand the ice formation behavior in the condenser. The analysis is supported by experimental observations of ice formation patterns in two different condenser units.

Mixed liquid/solid wastes, including feces, water processor effluents, and food waste, can be lyophilized (freeze-dried) to recover the water they contain and stabilize the solids that remain. Our previous research has demonstrated the potential benefits of using thermoelectric heat pumps to build a lyophilizer for processing waste in microgravity. These results were used to build a working prototype suitable for ground-based human testing. This paper describes the prototype design and presents results of functional and performance tests.

This paper describes the results of performance testing of the Vapor Phase Catalytic Ammonia Removal (VPCAR) technology. The VPCAR technology is currently being developed by NASA as a Mars transit vehicle water recycling system. NASA has recently completed a grant to develop a next generation VPCAR system. This grant concluded with the shipment of the final deliverable from Water Reuse Technology Inc. to NASA on August 31, 2003. This paper presents the results of initial performance testing of the VPCAR-EDU. Mass, power, volume, and acoustic measurements are reported. Product water purity analysis for a Mars transit mission and a planetary base simulated wastewater feeds are also reported.

This paper presents the results of a program to develop the next generation Vapor Phase Catalytic Ammonia Removal (VPCAR) system. VPCAR is a spacecraft water recycling system designed by NASA and constructed by Water Reuse Technology Inc. The technology has been identified by NASA to be the next generation water recycling system [1]. It is designed specifically for a Mars transit vehicle mission. This paper provides a description of the process and an evaluation of the performance of the new system. The equivalent system mass (ESM) is calculated and compared to the existing state-of-the art. A description of the contracting mechanism used to construct the new system is also provided.

This paper presents results of research on a solid waste dryer, based of the process of lyophilization, which recovers water and stabilizes solid waste. A lyophilizer has been developed and tested that uses thermoelectric heat pumps (TECs) to recycle heat during drying. The properties of TECs facilitate direct measurement of heat flow rates, and heat flow data are used to evaluate a heat and mass transfer model of the thermoelectric lyophilizer. Data are consistent with the theoretical model in most respects. Practical problems such as insulation and vacuum maintenance are minor in this system. However, the model’s assumption of a uniformly retreating ice layer during drying is valid only for the first 30% of water removed. Beyond this point, a shrinking core or lens model is more appropriate. Heat transfer to the shrinking core surrounded by dried material is slow.

This paper provides an assessment of the technical readiness of the Vapor Phase Catalytic Ammonia Removal Process (VPCAR). The VPCAR technology is a fully regenerative water recycling technology designed specifically for applications such as a near term Mars exploration mission. The VPCAR technology is a highly integrated distillation/catalytic oxidation based water processor. It is designed to accept a combined wastewater stream (urine, condensate, and hygiene) and produces potable water in a single process step which requires no regularly scheduled re-supply or maintenance for a 3 year mission. The technology is designed to be modular and to fit into a volume comparable to a single International Space Station Rack (when sized for a crew of 6). This paper provides a description of the VPCAR technology and a summary of the current performance of the technology.

The Lightweight Contingency Water Recovery System (LWC-WRS) harvests water from various sources in or around the Orion spacecraft in order to provide contingency water at a substantial mass savings when compared to stored emergency water supplies. The system uses activated carbon treatment (for urine) followed by forward osmosis (FO). The LWC-WRS recovers water from a variety of contaminated sources by directly processing it into a fortified (electrolyte and caloric) drink. Primary target water sources are urine, seawater, and other on board vehicle waters (often referred to as technical waters). The product drink provides hydration, electrolytes, and caloric requirements for crew consumption. The system hardware consists of a urine collection device containing an activated carbon matrix (Stage 1) and an FO membrane treatment element (or bag) which contains an internally mounted cellulose triacetate membrane (Stage 2).