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Journal Article

An Experimental Study on the Impact of Biodiesel Origin and Type on the Exhaust Emissions from a Euro 4 Pick-up Truck

2010-10-25
2010-01-2273
This study investigates the impact of mid-high biodiesel blends on the criteria and PAH emissions from a modern pick-up diesel vehicle. The vehicle was a Euro 4 (category N1, subclass III) compliant common-rail light-duty goods pick-up truck fitted with a diesel oxidation catalyst. Emission and fuel consumption measurements were performed on a chassis dynamometer equipped with CVS, following the European regulations. All measurements were conducted over the certification New European Driving Cycle (NEDC) and the real traffic-based Artemis driving cycles. Aiming to evaluate the fuel impact on emissions, a soy-based biodiesel, a palm-based biodiesel, and an oxidized biodiesel obtained from used frying oils were blended with a typical automotive ultra-low-sulfur diesel at proportions of 30, 50 and 80% by volume. The experimental results revealed that CO₂ emissions and fuel consumption exhibited an increase with biodiesel over all driving conditions.
Journal Article

Regulated and Unregulated Emissions of a Euro 4 SUV Operated with Diesel and Soy-based Biodiesel Blends

2009-11-02
2009-01-2690
In this study, regulated, unregulated exhaust emissions and fuel consumption with ultra low sulphur diesel and soy-based biodiesel blends at proportions of 10 and 30% v/v have been investigated. A Euro 4 compliant SUV, equipped with a 2.2 litre common-rail diesel engine and an oxidation catalyst was tested on a chassis dynamometer with constant volume sampling (CVS) technique. Emission and fuel consumption measurements were performed over the New European Driving Cycle (NEDC) and the non-legislated Artemis driving cycles which simulate urban, rural, and highway driving conditions in Europe. The regulated pollutants were characterized by determined NOx, PM, CO, and HC. CO2 was also quantified in the exhaust. Overall, 16 PAHs, 4 nitro-PAHs, 6 oxy-PAHs, 13 carbonyl compounds and particulate alkanes ranged from C13 to C35 were determined in the exhaust.
Journal Article

Impact of Biodiesel Blends on Fuel Consumption and Emissions in Euro 4 Compliant Vehicles

2010-05-05
2010-01-1484
Fatty Acid Methyl Ester (FAME) products derived from vegetable oils and animal fats are now widely used in European diesel fuels and their use will increase in order to meet mandated targets for the use of renewable products in road fuels. As more FAME enters the diesel pool, understanding the impact of higher FAME levels on the performance and emissions of modern light-duty diesel vehicles is increasingly important. Of special significance to Well-to-Wheels (WTW) calculations is the potential impact that higher FAME levels may have on the vehicle's volumetric fuel consumption. The primary objective of this study was to generate statistically robust fuel consumption data on three light-duty diesel vehicles complying with Euro 4 emissions regulations. These vehicles were evaluated on a chassis dynamometer using four fuels: a hydrocarbon-only diesel fuel and three FAME/diesel fuel blends containing up to 50% v/v FAME. One FAME type, a Rapeseed Methyl Ester (RME), was used throughout.
Technical Paper

A Methodology for Monitoring On-Road CO2 Emissions Compliance in Passenger Vehicles

2020-06-30
2020-37-0034
The European Union road transport CO2 emissions regulation foresees mandatory targets for passenger vehicles. However, several studies have shown that there is a divergence between official and real-world values that could range up to 40% compared to the NEDC reference value. The introduction of the Worldwide Harmonized Test Protocol (WLTP) limited this divergence, but it is uncertain whether it can adequately address the problem, particularly considering future evolutions of vehicle technology. In order to address this issue, the recent EU CO2-standards regulation introduces the monitoring of on-road fuel consumption and subsequently CO2 emissions by utilizing On-Board Fuel Consumption Meters (OBFCM). In the near future, all vehicles should provide instantaneous and lifetime-cumulative fuel consumption signals at the diagnostics port. Currently, the fuel consumption signal is not always available.
Journal Article

Emissions and Fuel Economy Evaluation from Two Current Technology Heavy-Duty Trucks Operated on HVO and FAME Blends

2016-04-05
2016-01-0876
Gaseous and particulate matter (PM) emissions were assessed from two current technology heavy-duty vehicles operated on CARB ultra-low sulfur diesel (ULSD), hydrotreated vegetable oil (HVO) blends, and a biodiesel blend. Testing was performed on a 2014 model year Cummins ISX15 vehicle and on a 2010 model year Cummins ISB6.7 vehicle. Both vehicles were equipped with diesel oxidation catalysts (DOC), diesel particulate filter (DPF), and selective catalytic reduction (SCR) systems. Testing was conducted over the Heavy-Duty Urban Dynamometer Driving Schedule (UDDS) and Heavy Heavy-Duty Diesel Truck (HHDDT) Transient Cycle. The results showed lower total hydrocarbons (THC), non-methane hydrocarbons (NMHC), and methane (CH4) emissions for the HVO fuels and the biodiesel blend compared to CARB ULSD. Overall, nitrogen oxide (NOx) emissions showed discordant results, with both increases and decreases for the HVO fuels.
Technical Paper

Engine-Out Emissions Characteristics of a Light Duty Vehicle Operating on a Hydrogenated Vegetable Oil Renewable Diesel

2020-04-14
2020-01-0337
We assessed the engine-out emissions of an ultra-low sulfur diesel (ULSD) and a neat hydrogenated vegetable oil (HVO) from a light-duty diesel truck equipped with common rail direct injection. The vehicle was tested at least twice on each fuel using the LA-92 drive cycle and at steady-state conditions at 30 mph and 50 mph at different loads. Results showed reductions in the engine-out total hydrocarbon (THC), carbon monoxide (CO), nitrogen oxide (NOx), and particulate emissions with HVO. The reductions in soot mass, solid particle number, and particulate matter (PM) mass emissions with HVO were due to the absence of aromatic and polyaromatic hydrocarbon compounds, as well as sulfur species, which are known precursors of soot formation. Volumetric fuel economy, calculated based on the carbon balance method, did not show statistically significant differences between the fuels.
Journal Article

A New Constant Dilution Ratio Concept for Vehicle and Engine Exhaust Particle Sampling

2008-04-14
2008-01-0762
This paper presents a new concept of a partial flow sampling system (PFSS), involving a two-stage dilutor which operates at underpressure, while exhaust is sampled through a capillary. The sample flowrate is in the order of few cubic centimeters per minute. Due to the low flowrate, no tight fixation is required between the exhaust line and the capillary inlet. The dilutor may sample from an opening in the exhaust line which freely exhausts to ambient pressure. As a result, the PFSS operates at constant pressure conditions even upstream of diesel particle filters (DPF). A straightforward mathematical model is then developed to calculate the dilution ratio (DR), depending on the dilution air flowrate and the dilutor underpressure. The model is validated using CO2 as a trace gas, and a very good agreement is demonstrated between the calculated and the measured DR values.
Journal Article

Calibration and Validation of a Diesel Oxidation Catalyst Model: from Synthetic Gas Testing to Driving Cycle Applications

2011-04-12
2011-01-1244
To meet future stringent emission regulations such as Euro6, the design and control of diesel exhaust after-treatment systems will become more complex in order to ensure their optimum operation over time. Moreover, because of the strong pressure for CO₂ emissions reduction, the average exhaust temperature is expected to decrease, posing significant challenges on exhaust after-treatment. Diesel Oxidation Catalysts (DOCs) are already widely used to reduce CO and hydrocarbons (HC) from diesel engine emissions. In addition, DOC is also used to control the NO₂/NOx ratio and to generate the exothermic reactions necessary for the thermal regeneration of Diesel Particulate Filter (DPF) and NOx Storage and Reduction catalysts (NSR). The expected temperature decrease of diesel exhaust will adversely affect the CO and unburned hydrocarbons (UHC) conversion efficiency of the catalysts. Therefore, the development cost for the design and control of new DOCs is increasing.
Journal Article

Influence of Different Natural Gas Blends on the Regulated Emissions, Particle Number and Size Distribution Emissions from a Refuse Hauler Truck

2012-09-10
2012-01-1583
Natural gas is a potential alternative to conventional liquid fuels for use in automotive internal combustion engines. The primary goal of this study is to understand how gas composition changes might impact the performance or emissions of a natural gas vehicle or engine. For this study, a waste hauler truck equipped with a 2001 Cummins 8.3L C Gas Plus lean burn spark-ignited engine and an oxidation catalyst was operated on the William H. Martin Refuse Truck Cycle (RTC). This cycle was developed to simulate waste hauler operation and consists of a transport segment, a curbside pickup segment, and a compaction segment.
Journal Article

Application of the Pegasor Particle Sensor for the Measurement of Mass and Particle Number Emissions

2013-04-08
2013-01-1561
The Pegasor Particle Sensor (PPS) is a small and lightweight sensor that can be used directly in raw exhaust to provide the mass and number concentration of exhaust aerosol. Its operation principle is based on the electrical charging of exhaust aerosol and determination of particle concentration by measuring the charge accumulated on the particles. In this paper we have applied the PPS in a variety of vehicle exhaust configurations to evaluate its performance characteristics. First, the output signal of the instrument was calibrated with diesel exhaust to deliver either the mass or the number concentration of exhaust aerosol. Linear response with the soot mass concentration measured by a Photo Acoustic Soot Sensor and number concentration measured by an Electrical Low Pressure Impactor was established.
Journal Article

Use of a Catalytic Stripper as an Alternative to the Original PMP Measurement Protocol

2013-04-08
2013-01-1563
The Particle Measurement Programme (PMP) developed an exhaust particle number measurement protocol that has been adopted by current light duty vehicle emission regulations in Europe. This includes thermal treatment of the exhaust aerosol to isolate solid particles only and a number counting device with a lower cutpoint of 23 nm to avoid measurement of smaller particles that may affect the repeatability of the measurement. In this paper, we examine a potential alternative to the PMP system, where the thermal treatment is replaced by a catalytic stripper (CS). This offers oxidation and not just evaporation of the volatile components. Alternative sampling systems, either fulfilling the PMP recommendations or utilizing a CS, have been explored in terms of their volatile particle removal efficiency. Tests have been conducted on diesel exhaust, diesel equipped with DPF and gasoline direct injection emissions.
Journal Article

A Complete Assessment of the Emissions Performance of Ethanol Blends and Iso-Butanol Blends from a Fleet of Nine PFI and GDI Vehicles

2015-04-14
2015-01-0957
Biofuels, such as ethanol and butanol, have been the subject of significant political and scientific attention, owing to concerns about climate change, global energy security, and the decline of world oil resources that is aggravated by the continuous increase in the demand for fossil fuels. This study evaluated the potential emissions impacts of different alcohol blends on a fleet of modern gasoline vehicles. Testing was conducted on a fleet of nine vehicles with different combinations of ten fuel blends over the Federal Test Procedure and Unified Cycle. The vehicles ranged in model year from 2007-2014 and included four vehicles with port fuel injection (PFI) fueling and five vehicles with direct injection (DI) fueling. The ten fuel blends included ethanol blends at concentrations of 10%, 15%, 20%, 51%, and 83% by volume and iso-butanol blends at concentrations of 16%, 24%, 32%, and 55% by volume, and an alcohol mixture giving 10% ethanol and 8% iso-butanol in the final blend.
Journal Article

Regulated Emissions, Air Toxics, and Particle Emissions from SI-DI Light-Duty Vehicles Operating on Different Iso-Butanol and Ethanol Blends

2014-04-01
2014-01-1451
Gasoline direct injection (GDI) engines have improved thermodynamic efficiency (and thus lower fuel consumption) and power output compared with port fuel injection (PFI) and their penetration is expected to rapidly grow in the near future in the U.S. market. In addition, the use of alternative fuels is expanding, with a potential increase in ethanol content beyond the current 10%. Increased emphasis has been placed on butanol due to its more favorable fuel properties, as well as new developments in production processes. This study explores the influence of mid-level ethanol and iso-butanol blends on criteria emissions, gaseous air toxics, and particulate emissions from two wall-guided gasoline direct injection passenger cars fitted with three-way catalysts. Emission measurements were conducted over the Federal Test Procedure (FTP) driving cycle on a chassis dynamometer.
Journal Article

Impact of FAME Content on the Regeneration Frequency of Diesel Particulate Filters (DPFs)

2014-04-01
2014-01-1605
Modern diesel vehicles utilize two technologies, one fuel based and one hardware based, that have been motivated by recent European legislation: diesel fuel blends containing Fatty Acid Methyl Esters (FAME) and Diesel Particulate Filters (DPF). Oxygenates, like FAME, are known to reduce PM formation in the combustion chamber and reduce the amount of soot that must be filtered from the engine exhaust by the DPF. This effect is also expected to lengthen the time between DPF regenerations and reduce the fuel consumption penalty that is associated with soot loading and regeneration. This study investigated the effect of FAME content, up to 50% v/v (B50), in diesel fuel on the DPF regeneration frequency by repeatedly running a Euro 5 multi-cylinder bench engine over the European regulatory cycle (NEDC) until a specified soot loading limit had been reached.
Technical Paper

Effect of Lube Oil on the Physicochemical Characteristics of Particulate Matter Emitted from a Euro 4 Light Duty Diesel Vehicle

2007-09-16
2007-24-0110
This paper investigates the effect of lubrication oil on the physical and chemical characteristics of the particulate matter (PM) emitted from a Euro 4 diesel vehicle. Two different lubrication oils were examined. A fully synthetic ACEA grade B3 service-fill oil of low sulfur content (1760 ppm wt.) falling into the OW-40 SAE viscosity grade and a mineral ACEA B2-98 motor oil of high sulfur (8890 ppm wt.), falling into the 15W-40 SAE viscosity grade. To exclude interferences from the fuel derived sulfur, a rather sulfur-free fuel (< 10 ppm wt.) was used in the experiments. The experiments included steady state tests, the certification cycle and real-world highspeed transient driving conditions. The properties measured included total particle mass collected on Teflon-coated filters, total particle number measured by a condensation particle counter, size distributions determined by a scanning mobility particle sizer.
Technical Paper

Experimental evaluation of cottonseed oil-diesel blends as automotive fuels via vehicle and engine measurements

2007-09-16
2007-24-0126
Vegetable oils blended with diesel fuel are recognised as biofuels by the European legislation and their application is an interesting option for increasing the market share of biofuels. This paper presents results from a detailed study conducted on a Euro 3 compliant diesel passenger car and a high injection pressure test bench engine using 10% Cottonseed oil- 90% Diesel blends as fuel. The tests included fuel consumption and emissions measurements. Aim of the experimental analysis was to accurately evaluate the effect of biofuel application on a common rail engine. The measurement protocol included measurements of regulated emissions, fuel consumption and in-cylinder pressure at various operation modes. Results from the bench engine measurements are in line with those retrieved from the vehicle and indicate that the fuel tested presents good characteristics and that under certain conditions it can be applied as automotive fuel in a broader scale.
Technical Paper

Effect of a DPF and Low Sulfur Lube Oil on PM Physicochemical Characteristics from a Euro 4 Light Duty Diesel Vehicle

2007-04-16
2007-01-0314
This paper studies the effect of a Catalyzed Diesel Particle Filter (CDPF) on the emission profile of a Euro 4 diesel vehicle operated on low sulfur fuel and lubrication oil. The vehicle was tested in its original configuration and with the CDPF retrofitted in place of its main underbody catalyst. Experiments included steady state tests, the certification cycle and real-world high speed transient driving conditions. Measurements included total particle mass collected on Teflon-coated filters, total particle number measured by a condensation particle counter, size distributions determined by a Scanning Mobility Particle Sizer and chemical analysis of the mass collected for elemental and organic carbon, ions, PAHs, and trace elements. Results showed that the vehicle complies with the Euro 4 emission limits when tested over the type-approval NEDC, but it emits more nitrogen oxides and, in some cases, more particulate matter when tested over real-world test cycles.
Technical Paper

Effect of Speed and Speed-Transition on the Formation of Nucleation Mode Particles from a Light Duty Diesel Vehicle

2007-04-16
2007-01-1110
This work studies the formation of nucleation mode (NM) particles from a Euro 3 passenger car operating on 280 ppm wt. sulfur fuel, during on-road plume chasing and in the laboratory. The vehicle produced a distinct NM when its speed exceeded 100 km/h in both sampling environments. A higher particle number (up to 8 times) after 4 min at constant speed was measured when this speed was approached from a lower than from a higher speed. The variability in the measurement of NM particles was explained using literature information on sulfur-to-sulfate conversion over a catalyst and, in particular, on the extent and rate of sulfate storage and release mechanisms. All evidence led to the conclusion that storage and release processes take several minutes to conclude after a step-wise change in speed and have significant implications in the total particle number measurements during steady-speed testing.
Technical Paper

Experimental Evaluation of the Fuel Consumption and Emissions Reduction Potential of Low Viscosity Lubricants

2009-06-15
2009-01-1803
Reducing fuel consumption and emissions from road transport is a key factor for tackling global warming, promoting energy security and sustaining a clean environment. Several technical measures have been proposed in this aspect amongst which the application of low viscosity engine lubricants. Low viscosity lubricants are considered to be an interesting option for reducing fuel consumption (and CO2 emissions) throughout the fleet in a relatively cost effective way. However limited data are available regarding their actual “real-world” performance with respect to CO2 and other pollutant emissions. This study attempts to address the issue and to provide experimental data regarding the benefit of low viscosity lubricants on fuel consumption and CO2 emissions over both the type-approval and more realistic driving cycles.
Technical Paper

The Effect of Biodiesel on PAHs, Nitro-PAHs and Oxy-PAHs Emissions from a Light Vehicle Operated Over the European and the Artemis Driving Cycles

2009-06-15
2009-01-1895
This study examines the effects of neat soy-based biodiesel (B100) and its 50% v/v blend (B50) with low sulphur automotive diesel on vehicle PAH emissions. The measurements were conducted on a chassis dynamometer with constant volume sampling (CVS) according to the European regulated technique. The vehicle was a Euro 2 compliant diesel passenger car, equipped with a 1.9 litre common-rail turbocharged direct injection engine and an oxidation catalyst. Emissions of PAHs, nitro-PAHs and oxy-PAHs were measured over the urban phase (UDC) and the extra-urban phase (EUDC) of the type approval cycle (NEDC). In addition, for evaluating realistic driving performance the non-legislated Artemis driving cycles (Urban, Road and Motorway) were used. Overall, 12 PAHs, 4 nitro-PAHs, and 6 oxy-PAHs were determined. The results indicated that PAH emissions exhibited a reduction with biodiesel during all driving modes.
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