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Homogeneous Charge Induced Ignition (HCII) combustion utilizes a port injection of high-volatile fuel to form a homogeneous charge and a direct injection of high ignitable fuel near the Top Dead Center (TDC) to trigger combustion. Compared to Conventional Diesel Combustion (CDC) with high injection pressures, HCII has the potential to achieve diesel-like thermal efficiency with significant reductions in NOx and PM emissions with relatively low-pressure injections, which would benefit the engine cost saving remarkably. In the first part of current investigation, experiments were conducted at medium load with single diesel injection strategy. HCII exhibited great potential of using low injection pressures to achieve low soot emissions. But the engine load for HCII was limited by high heat release rate. Thus, in the second and third part, experiments were performed at high and low load with double diesel injection strategy.

Diesel soot suppression effects of catalytic fuel additives for a range of fuels with different properties were investigated with calcium naphthenate. A single cylinder DI diesel engine and a thermobalance were used to determine the soot reduction and its mechanism for seven kinds of fuels. Experimental results showed that the catalytic effect of the fuel additive was different for the different fuels, and could be described by a parameter considering cetane number and kinematic viscosity. The fuel additives reduced soot more effectively for fuels with higher cetane number and lower kinematic viscosity. This result was explained by soot oxidation characteristics for the different fuels. Oxidation of soot with the metallic additive proceeds in two stages: stage I, a very rapid oxidation stage; and stage II, a following slow or ordinary oxidation stage.

This research investigates the influences of the injection timing, injection pressure, and compression ratio on the combustion and exhaust emissions in a single cylinder 1.0 L DI diesel engine operating with ultra-high EGR. Longer ignition delays due to either advancing or retarding the injection timing reduced the smoke emissions, but advancing the injection timing has the advantages of maintaining the thermal efficiency and preventing misfiring. Smokeless combustion is realized with an intake oxygen content of only 9-10% regardless of the injection pressure. Reduction in the compression ratio is effective to reduce the in-cylinder temperature and increase the ignition delay as well as to expand the smokeless combustion range in terms of EGR and IMEP. However, the thermal efficiency deteriorates with excessively low compression ratios.

Diesel combustion and emissions with four kinds of oxygenated agents as main fuels were investigated. Significant improvements in smoke, particulate matter, NOx, THC, and thermal efficiency were simultaneously realized with the oxygenates, and engine noise was also remarkably reduced for the oxygenates with higher ignitability. The improvements in the exhaust emissions and the thermal efficiency depended almost entirely on the oxygen content in the fuels regardless of the oxygenate to diesel fuel blend ratios and type of oxygenate. The unburned THC emission and odor intensity under starting condition with an oxygenate were also much lower than with conventional diesel fuel.

Soot emission from diesel engines generally increases with shorter ignition lags. However, the detailed process and mechanism of this phenomenon has not been well understood. This investigation attempts to observe and analyze the in-chamber soot formation process at various ignition lags by high-speed photography of the direct flame images and laser shadowgraphs as well as the laser light extinction. In the experiment, the separation of soot concentration from the soot-fuel mixture concentration was established by subtracting the laser light extinction intensity through a non-firing chamber from that through a firing chamber. It was found that the soot concentration in the swirl chamber reached a maximum value immediately after the start of combustion, and then decreased rapidly. With shorter ignition lags, the maximum and final soot concentrations in the chamber increased.

NOx -SCR over Ag/ Al2O3 catalyst using ethanol (C2H5OH) as a reductant has proven its ability to significantly reduce NOx emission in a simulated engine exhaust gas environment. However the real engine exhaust gas environment is too complicated to be simulated. Therefore, the performance evaluation of the Ag/ Al2O3 catalyst in real exhaust gas environment is necessary. Moreover, the ethanol dosing device and control strategy also need to be validated for the practical use. In this paper, firstly the catalyst performance and its sulfur tolerance was tested on an engine test bench and the effect of the catalyst on PM emission was investigated. Then the aftertreatment system composed of Ag/Al2O3 catalyst + Cu/TiO2 catalyst + Pt/TiO2 catalyst and ethanol dosing control based on open loop control was designed, and the diesel engine emission with the aftertreatment system was tested according to ESC test cycle.

Soot emissions in the combustion process of diesel engines are greatly harmful to the environment and human health. Consequently, there is large interest and great efforts in decreasing soot emission from diesel engines to meet the increasingly stringent emission standards. The mechanisms of soot formation and oxidation so far have not been well understood. Laser induced incandescence (LII) is particularly suited to measure the instantaneous spatial distribution of the soot volume concentration, which can offer much needed detailed information of soot distribution for better understanding of soot formation and oxidation. In this paper, a two-color laser induced incandescence (2C-LII) technique was implemented for measuring absolute soot volume fraction in a laminar diesel fuel diffusion flame.

Urea Selective Catalytic Reduction (SCR) has been proven to significantly reduce NOx emissions from diesel engines. The thermal decomposition of urea, which forms the ammonia as the reactant, has a crucial effect on the performance and durability of the NOx-SCR system. The incomplete thermal decomposition of urea not only reduces the NOx conversion ratio and increases the ammonia slip, but also leads to deposit formation on the catalyst surface, which will block the pore and the active sites of the catalyst and then decreases the durability of the SCR systems. In this paper, the urea thermolysis was measured using the Thermal Gravimetric Analysis (TGA) and Fourier Transform Infrared Spectroscopy (FTIR). Then, the performance of the SCR systems under different injection parameters of the Urea-water solution was investigated on a diesel engine test bench. Finally, the deposits on the catalyst were also analyzed using TGA and FTIR.

Biodiesel is an alternative, renewable, clean fuel, which can effectively reduce emissions from diesel engines. However, the effects of biodiesel on engine emissions vary due to the difference in source. In this paper, performance of five different biodiesels was studied: CME, SME, RME, PME and WME. Engine power, fuel consumption, gaseous emissions and PM, DS and none soot fraction (NSF) were investigated in a Cummins ISBe6 Euro III diesel engine fueled with five biodiesels respectively and compared with the diesel fuel. Results revealed that using different biodiesels resulted in PM reductions ranging from 53% to 69%, which included DS reduction ranging from 79% to 83%. Observations showed that fuel oxygen content and viscosity had obvious effects on DS. Higher oxygen content biodiesels produced less DS at high load while lower viscosity biodiesels produced less DS at low load.

Beijing will implement the 4th stage emission regulations (equivalent to Euro IV) in 2008 ahead of other provinces or cites in China. Beijing Environmental Protection Bureau (EPB) organized petroleum corporations, automobile and engine manufactories as well as research institutes to test the adaptability of the fuels from Chinese refineries to the modern vehicles or engines on the road running conditions in China. In this paper, the effects of diesel fuel quality on combustion and emission of a Euro IV heavy-duty diesel engine as one part of the program were studied to provide technical data to stipulate the feasible diesel fuel standard, which should guarantee modern vehicles or engines to meet the 4th stage regulations. Eight kinds of diesel fuels with different properties, such as cetane number, distillation temperature (T90) and sulfur content, were tested on a Euro IV Cummins heavy-duty diesel engine with urea SCR after-treatment.

Beijing will implement the national 4th stage emissions standards (equivalent to Euro IV emissions standards) in advance in China from 2008. The objective of this study was to provide some technical support for proposing automotive gasoline fuel standards matching with the emission standards. In this paper, tests were conducted on two engines and one gasoline passenger vehicle meeting Euro III or IV emission standards to study the correlation between gasoline fuel properties and engine performances, including power, fuel consumption and emissions. Test results showed that the effect of octane number on engine power depended on engine technologies. High octane number had a negative effect on fuel consumption and emissions. As olefin content increased, the engine-out THC emissions decreased significantly. The vehicle test results also showed that high olefin content greatly reduced the tailpipe THC emissions.

According to China's “oil-poor, gas-litte, coal-rich” structure of energy resources, to promote the development of coal-based methanol fuel as a clean alternative to gasoline and diesel fuel is one of the most realistic options. So the adaptability of methanol gasoline blend fuel used in the gasoline engine and vehilce should be investigated. Engine load performance, engine out emission, air fuel ratio variation and combustion characteristics were tested in a PFI Euro III gasoline engine using gasoline, M10, M15, M20, M30 as fuel without any modification of the engine. Air fuel ratio, light-off temperature and load characteristics of catalystic conversion coefficient were also investigated. And effects of methanol content on fuel consumption and vehicle out emissions of a Euro - vehicle are analyzed.

In a DI diesel engine, THC emissions increase significantly with lower compression ratios, a low coolant temperature, or during the transient state. During the transient after a load increase, THC emissions are increased significantly to very high concentrations from just after the start of the load increase until around the 10th cycle, then rapidly decreased until the 20th cycle, before gradually decreasing to a steady state value after 1000 cycles. In the fully-warmed steady state operation with a compression ratio of 16 and diesel fuel, THC is reasonably low, but THC increases with lower coolant temperatures or during the transient period just after increasing the load. This THC increase is due to the formation of over-lean mixture with the longer ignition delay and also due to the fuel adhering to the combustion chamber walls. A low distillation temperature fuel such as normal heptane can eliminate the THC increase.

Knocking is the main obstacle of increasing compression ratio to improve the thermal efficiency of gasoline engines. In this paper, the concept of stratified stoichiometric mixture (SSM) was proposed to suppress knocking in gasoline engines. The rich mixture near the spark plug increases the speed of the flame propagation and the lean mixture in the end gas suppresses the auto ignition. The overall air/fuel ratio keeps stoichiometric to solve the emission problem using three way catalysts (TWC). Moreover, both the rich zone and lean zone lead to soot free combustion due to homogeneous mixture. The effect on the knocking of homogeneous and stratified mixture was studied in a direct injection spark ignition (DISI) engine using numerical simulation and experimental investigation respectively.

The thermal cracking and polyaromatic hydrocarbon (PAH) formation processes of dimethyl ether (DME), ethanol, and ethane were investigated with chemical kinetics to determine the soot formation mechanism of oxygenated fuels. The modeling analyzed three processes, an isothermal constant pressure condition, a temperature rising condition under a constant pressure, and an unsteady condition approximating diesel combustion. With the same mole number of oxygen atoms, the DME rich mixtures form much carbon monoxide and methane and very little non-methane HC and PAH, in comparison with ethanol or ethane mixtures. This suggests that the existence of the C-C bond promotes the formation of PAH and soot.

Time resolved changes in unburned hydrocarbon emissions and their components were investigated in a DI diesel engine with a specially developed gas sampling system and gas chromatography. The tested transient operations include starting and increasing loads. At start-up with high equivalence ratios the total hydrocarbon (THC) at first increased, and after a maximum gradually decreased to reach a steady state value. Reducing the equivalence ratio of the high fueling at start-up and shortening the high fueling duration are effective to reduce THC emissions as long as sufficient startability is maintained. Lower hydrocarbons, mainly C1-C8, were the dominant components of the THC and mainly determined the THC behavior in the transient operations while the proportion of hydrocarbon (HC) components did not significantly change. The unregulated toxic substances, 1,3 butadiene and benzene were detected in small quantities.

The combustion characteristics in a partially premixed charge compression ignition (PCCI) engine with n-hexane were compared with ordinary diesel fuel to evaluate combustion improvements with lower distillation-temperature fuels. In the PCCI engine, a lean mixture was formed reasonably with early stage injection and the additional fuel was supplied with a second stage fuel injection after ignition. With n-hexane, thermal efficiency improved while simultaneously maintaining low NOx and smokeless combustion. A CFD analysis simulated the mixture formation processes and showed that the uniformity of the mixture with the first stage injection improves with lower distillation-temperature fuels.

Smokeless and ultra low NOx combustion without knocking in a dual-fuel diesel engine with induced LPG as the main fuel was established with a uniquely developed piston cavity divided by a lip in the sidewall. A small quantity of diesel fuel was directly injected at early compression stroke into the lower part of the cavity as an ignition source for this confined area, and this suppressed explosively rapid combustion just after ignition and spark-knock like combustion at later stage. A combination of the divided cavity, EGR, and intake air throttling was effective to simultaneously eliminate knocking, and reduce THC and NOx significantly.

The fundamental parameters related to engine combustion and performances, such as, heating value, theoretical air-fuel ratio, adiabatic flame temperature, carbon dioxide (CO2), and nitric oxide (NO) emissions, specific heat and engine thermal efficiency were investigated with computations for a wide range of oxygenated fuels. The computed results showed that almost all of the above combustion-related parameters are closely related to oxygen content in the fuels regardless of the kinds or chemical structures of oxygenated fuels. An interesting finding was that with the increase in oxygen content in the fuels NO emission decreased linearly, and the engine thermal efficiency was almost unchanged below oxygen content of 30 wt-% but gradually decreased above 30 wt-%.

Most countries consider it is harmful for humans to inhale SPM of fine organic particles and elemental carbon less than 2.5 μ in diameter1,2). It is generally believed that organic matters in SPM are mainly composed of diesel exhaust particulate and soot from residential chimneys or industrial smokestacks3,4). To determine the contribution ratios of several organic substances to SPM, we characterized SPM, diesel exhaust particulate (DEP), powdered summer radial tire, and bitumen, using high performance liquid chromatography, field desorption mass spectrometry and linear theory.