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The value of “ultracapacitors” (also referred to as “supercapacitors” or “electric double layer capacitors” in some literature) as an augmentation device when placed in parallel with “electrochemical” energy storage (i.e. battery) is presented in this paper. Since ultracapacitors possess unique attributes due to their higher value of energy storage density (or Joules/WattHrs per mass) compared to conventional capacitors while maintaining the peak power providing capability (to some degree) typical of conventional capacitors they may provide a near term solution in applications demanding longer battery operating life when placed in parallel. Such demands may be pronounced by the onset of More-Electric-Aircraft peak loads and “cold-crank” Auxiliary Power Unit (APU) electric-starting in demanding cold temperature environments.

This paper describes the development of a lead free, high temperature ceramic capacitor material having the base composition of (Na0.5 Bi0.5) TiO3. The goal is to modify this structure to create a material that has the relative permittivity of barium titanate with extended X7R-like properties to 250°C - an X14R. After an extensive compositional and theoretical modeling investigation a composition was selected and capacitors developed. The dielectric has a 1-kHz relative permittivity of ∼1200 with <±15% variation from -25 to +250°C and <5% loss from -55 to +250°C. These capacitors also have very low voltage coefficients, indeed they are positive at the low end of the temperature range, resulting in a combined TC-Vc capacitance variation 0%/-25% of nominal from -55 to +200°C with applied voltage stress from 20 to 260 V/mil.