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This paper describes the development of a 0-D-sulfur poisoning model for a NOx storage catalyst (NSC). The model was developed and calibrated using findings and data obtained from a passenger car diesel engine used on testbed. Based on an empirical approach, the developed model is able to predict not only the lower sulfur adsorption with increasing temperature and therefore the higher SOx (SO2 and SO3) slip after NSC, but also the sulfur saturation with increasing sulfur loading, resulting in a decrease of the sulfur adsorption rate with ongoing sulfation. Furthermore, the 0-D sulfur poisoning model was integrated into an existing 1-D NOx storage catalyst kinetic model. The combination of the two models results in an “EAS Model” (exhaust aftertreatment system) able to predict the deterioration of NOx-storage in a NSC with increasing sulfation level, exhibiting higher NOx-emissions after the NSC once it is poisoned.

In relation to further tightening of the emissions legislation for on-road heavy duty Diesel engines, the future potential of cooled exhaust gas recirculation (EGR) as a result of developments in the cooling systems of such engines has been evaluated. Four basic engine concepts were investigated: an engine with SCR exhaust gas aftertreatment for control of the nitrogen oxides (NOx), an engine with cooled EGR and particulate (PM) filtration, an engine with low pressure EGR and PM filtration and an engine with two stage low temperature cooled EGR also with a particulate filter. A 10.5 litre engine was calibrated and tested under conditions representative for each concept, such that 1.7 g/kWh (1.3 g/bhp-hr) NOx could be achieved over the ESC and ETC. This corresponds to emissions 15% below the Euro 5 legislation level.

Current progress in the development of diesel engines substantially contributes to the reduction of NOx and Particulate Matter (PM) emissions but will not succeed to eliminate the application of Diesel Particulate Filters (DPFs) in the future. In the past we have introduced a Multi-Functional Reactor (MFR) prototype, suitable for the abatement of the gaseous and PM emissions of the Low Temperature Combustion (LTC) engine operation. In this work the performance of MFR prototypes under both conventional and advanced combustion engine operating conditions is presented. The effect of the MFR on the fuel penalty associated to the filter regeneration is assessed via simulation. Special focus is placed on presenting the performance assessment in combination with the existing differences in the morphology and reactivity of the soot particles between the different modes of diesel engine operation (conventional and advanced). The effect of aging on the MFR performance is also presented.

This paper describes development challenges for Heavy-Duty (HD) on-highway Diesel Direct Injection (DDI™) engines to meet the extremely advanced US-EPA 2010 (later named US 2010) emission limits while further increasing power density in combination with competitive engine efficiency. It discusses technologies and solutions for lowest engine-out emissions in combination with most competitive fuel consumption values and excellent dynamic behavior. To achieve these challenging targets, base engine hardware requirements are described. In detail the development of EGR systems, especially the challenges of running high EGR rates over the whole engine speed range also at high load, the dynamic EGR control for transient engine operation to achieve lowest NOx emissions at the smoke limit with excellent load response is discussed. Also the effect of the turbo-machinery on power density and transient engine behavior is shown.

The HSDI Diesel engine contributes substantially to the decrease of fleet fuel consumption thus to the reduction of CO2 emissions. This results in the rising market acceptance which is supported by desirable driving performance as well as greatly improved NVH behavior. In addition to the above mentioned requirements on driving performance, fuel economy and NVH behavior, continuously increasing demands on emissions performance have to be met. From today's view the Diesel particulate trap presents a safe technology to achieve the required reduction of the particle emission of more than 95%. However, according to today's knowledge a further, substantial NOx engine-out emission reduction for the Diesel engine is counteracts with the other goal of reduced fuel consumption. To comply with current and future emission standards, Diesel engines will require DeNOx technologies.

The reduction of nitrous oxides in the exhaust gases of internal combustion engines using a urea water solution is gaining more and more importance. While maintaining the future exhaust gas emission regulations, like the Euro 6 for passenger cars and the Euro 5 for commercial vehicles, urea dosing allows the engine management to be modified to improve fuel economy as well. The system manufacturer Robert Bosch has started early to develop the necessary dosing systems for the urea water solution. More than 300.000 Units have been delivered in 2007 for heavy duty applications. Typical dosing quantities for those systems are in the range of 0.01 l/h for passenger car systems and up to 10 l/h for commercial vehicles. During the first years of development and application of urea dosing systems, instantaneous flow measuring devices were used, which were not operating fully satisfactory.

The introduction of more stringent standards for engine emissions requires continuous improvement of exhaust gas aftertreatment systems. Modern systems require a combined design and application of different aftertreatment devices. Computer simulation helps to investigate the complexity of different system layouts. This study presents an overall aftertreatment modeling framework comprising dedicated models for pipes, oxidation catalysts, wall flow particulate filters and selective catalytic converters. The model equations of all components are discussed. The individual behavior of all components is compared to experimental data. With these well calibrated models a simulation study on a DOC-DPF-SCR exhaust system is performed. The impact of pipe wall insulation on the overall NOx conversion performance is investigated during four different engine operating conditions taken from a heavy-duty drive cycle.

Representative Interactive Flamelets (RIF) have proven successful in predicting Diesel engine combustion. The RIF concept is based on the assumption that chemistry is fast compared to the smallest turbulent time scales, associated with the turnover time of a Kolmogorov eddy. The assumption of fast chemistry may become questionable with respect to the prediction of pollutant formation; the formation of NOx, for example, is a rather slow process. For this reason, three different approaches to account for NOx emissions within the flamelet approach are presented and discussed in this study. This includes taking the pollutant mass fractions directly from the flamelet equations, a technique based on a three-dimensional transport equation as well as the extended Zeldovich mechanism. Combustion and pollutant emissions in a Common-Rail DI Diesel engine are numerically investigated using the RIF concept. Special emphasis is put on NOx emissions.

The future worldwide emission regulations will request a drastic decrease of Diesel engine tailpipe emissions. Depending on the planned application and the real official regulations, a further strong decrease of engine out emissions is necessary, even though the utilized exhaust after-treatment systems are very powerful. To reduce NOx emissions internally, the external exhaust gas recirculation (EGR) is known as the most effective way. Due to the continuously increasing requirements regarding specific power, dynamic behavior and low emissions, future air path systems have to fulfill higher requirements and, consequently, become more and more complex, e.g. arrangements with a 2-stage turbo charging or 2-stage EGR system with different stages of cooling performance.

Fuels derived from biomass will most likely contain oxygen due to the high amount of hydrogen needed to remove oxygen in the production process. Today, alcohol fuels (e. g. ethanol) are well understood for spark ignition engines. The Institute for Combustion Engines at RWTH Aachen University carried out a fuel investigation program to explore the potential of alcohol fuels as candidates for future compression ignition engines to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. The soot formation and oxidation process when using alcohol fuels in diesel engines is not yet sufficiently understood. Depending on the chain length, alcohol fuels vary in cetane number and boiling temperature. Decanol possesses a diesel-like cetane number and a boiling point in the range of the diesel boiling curve. Thus, decanol was selected as an alcohol representative to investigate the influence of the oxygen content of an alcohol on the combustion performance.

The European research co-operation Lotus is presented. The main objectives of the project were i) to show the potential for a urea-based SCR system to comply with the EU standard of years 2005 and 2008 for heavy-duty Diesel engines for different driving conditions with optimal fuel consumption, ii) to reach 95 % conversion of NOx at steady state at full load on a Euro III engine, iii) to reach 75 % NOx reduction for exhaust temperatures between 200-300°C, and 85 % average NOx reduction between 200-500°C. The energy content of the consumed urea should not exceed 1.0 %, calculated as specific fuel consumption. These targets were met in May 2003 and the Lotus SCR system fulfilled the Euro V NOx legislative objectives for year 2008.

Emission standards as proposed in Europe and the United States for heavy duty diesel engines will require a NOx and particulate reduction of more than 90%. This cannot be achieved by internal engine measures alone. Aftertreatment systems, for either one or both emission components, plus sophisticated electronic control strategies will be required. Various strategies to comply with EU 4, 5 and US 2007 are discussed, also showing their impact on engine performance. For typical 1 and 2 liter per cylinder engines, emission reduction concepts are assessed to identify the most suitable technology for major worldwide markets. The assessment is based on thermodynamic studies, test-bed results and estimates on cost and infrastructure implications.

In the near future the effort on the development of exhaust gas treatment systems must be increased to meet the stringent emission requirements. If the relevant physical and chemical models are available, the numerical simulation is an important tool for the design of these systems. This work presents a CFD model that allows to cover the full range of applications in this area. After a detailed presentation of the theoretical background and the modeling strategies results for the simulation of a close-coupled catalyst are shown. The presented model is also applied to the oxidation of nitrogen oxides, to a diesel particle filter and a fuel-cell reformer catalyst.

This paper focuses on start-up technology for fuel processing systems with special emphasis on gasoline fueled burners. Initially two different fuel processing systems, an autothermal reformer with preferential oxidation and a steam reformer with membrane, are introduced and their possible starting strategies are discussed. Energy consumption for preheating up to light-off temperature and the start-up time is estimated. Subsequently electrical preheating is compared with start-up burners and the different types of heat generation are rated with respect to the requirements on start-up systems. Preheating power for fuel cell propulsion systems necessarily reaches up to the magnitude of the electrical fuel cell power output. A gasoline fueled burner with thermal combustion has been build-up, which covers the required preheating power.

A TGDI (turbocharged gasoline direct injection) engine is developed to realize both excellent fuel economy and high dynamic performance to guarantee fun-to-drive. In order to achieve this target, it is of great importance to develop a superior combustion system for the target engine. In this study, CFD simulation analysis, steady flow test and transparent engine test investigation are extensively conducted to ensure efficient and effective design. One dimensional thermodynamic simulation is firstly conducted to optimize controlling parameters for each representative engine operating condition, and the results serve as the input and boundary condition for the subsequent Three-dimensional CFD simulation. 3D CFD simulation is carried out to guide intake port design, which is then measured and verified on steady flow test bench.

A calibration and validation workflow will be presented in this paper, which utilizes common static global models for fuel consumption, NOx and soot. Due to the applicability for warm-up tests, e.g. New European Driving Cycle (NEDC), the models need to predict the temperature influence and will be fitted with measuring data from a conditioned engine test bed. The applied model structure consisting of a number of global data-based sub-models is configured especially for the requirements of multi-injection strategies of common rail systems. Additionally common global models for several constant coolant water temperature levels are generated and the workflow tool supports the combination and segmentation of global nominal map with temperature correction maps for seamless and direct ECU setting.

Accurate simulation tools are needed for rapid and cost effective engine development in order to meet ever tighter pollutant regulations for future internal combustion engines. The formation of pollutants such as soot and NOx in Diesel engines is strongly influenced by local concentration of the reactants and local temperature in the combustion chamber. Therefore it is of great importance to model accurately the physics of the injection process, combustion and emission formation. It is common practice to approximate Diesel fuel as a single compound fuel for the simulation of the injection and combustion process. This is in many cases sufficient to predict the evolution of the in-cylinder pressure and heat release in the combustion chamber. The prediction of soot and NOx formation depends however on locally component resolved quantities related to the fuel liquid and gas phase as well as local temperature.

The paper describes a feasibility test program on a 2 liter, 4 cylinder DI/TCI passenger car engine operated on the new alternative fuel Dimethyl Ether (DME, CH3 - O - CH3) with the aim of demonstrating its potential of meeting ULEV emissions (0.2 g/mi NOx in the FTP 75 test cycle) when installed in a full size passenger car. Special attention is drawn to the fuel injection equipment (FIE) as well as combustion system requirements towards the reduction of NOx and combustion noise while keeping energetic fuel consumption at the level of the baseline DI/TCI diesel engine. FIE and combustion system parameters were optimized on the steady state dynamometer by variation of a number of parameters, such as rate of injection, number of nozzle holes, compression ratio, piston bowl shape and exhaust gas recirculation.

An optical sensor system provides access to standard SI engine combustion chambers via the cylinder head gasket. Flame radiation within the plane of the gasket is observed with optical fibers which are arranged to allow the tomographic reconstruction of flame distribution. The effect of convective in-cylinder air motion generated by variations of inlet ports and combustion chamber geometries on flame propagation is directly visible. A high degree of correlation between flame intensity distribution and NOx emission levels yields a useful assessment of combustion chamber configurations with minimum emission levels. The location of knock centers is identified.

Future legislation, like EURO IV and EURO V or the US 2007 HD regulation will have massive reduction of particulate emission limits. For this beside improvement of engine combustion also exhaust aftertreatment systems are under investigation, like Diesel Particulate Filters (DPF), or Selective Catalytic Reduction (SCR) of Nitrogen Oxides. For all those tasks transient soot emission monitoring is one of the key features. To meet this demand a new device for the on-line measurement of soot emitted by combustion engines has been developed. Based on the photoacoustic principle, which has been optimized for automotive applications and easy use in test cells, the instrument shows a sensitivity of 5μg/m3, which is lower than current particulate immission standards in ambient air, and a time resolution of 1 sec. In the paper first the principles of measurement are shown, and then the specifications and results from measurements of very low soot concentration in the exhaust gas are presented.