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Several different possibilities will be described and discussed on the processes of reducing NOx in lean-burn gasoline and diesel engines. In-company studies were conducted on zeolitic catalysts. With lean-burn spark-ignition engines, hydrocarbons in the exhaust gas act as a reducing agent. In stationary conditions at λ = 1.2, NOx conversion rates of approx. 45 % were achieved. With diesel engines, the only promising variant is SCR technology using urea as a reducing agent. The remaining problems are still the low space velocity and the narrow temperature window of the catalyst. The production of reaction products and secondary reactions of urea with other components in the diesel exhaust gas are still unclarified.

The combustion characteristics of a HSDI diesel engine were analyzed numerically using a reduced chemical kinetics. The reaction mechanism consisting of 26 steps and 17 species including the Zel'dovich NOx mechanism for the higher hydrocarbon fuel was implemented in the KIVA-3V. The characteristic time scale model was adopted to account for the effects of turbulent mixing on the reaction rates. The soot formation and oxidation processes are represented by Hiroyasu's model and NSC's model. The validation cases include the homogenous fuel/air mixture and the spray combustion in a constant volume chamber. After the validation, the present approach was applied to the analysis of the spray combustion processes in a HSDI diesel engine. The present approach reasonably well predicts the ignition delay, combustion processes, and emission characteristics in the high-pressure turbulent spray flame-field encountered in the practical HSDI diesel engines.

The Representative Interactive Flamelet(RIF) concept has been applied to numerically simulate the combustion processes and pollutant formation in the direct injection diesel engine. Due to the ability for interactively describing the transient behaviors of local flame structures with CFD solver, the RIF concept has the capabilities to predict the auto-ignition and subsequent flame propagation in the diesel engine combustion chamber as well as to effectively account for the detailed mechanisms of soot and NOx formation. In order to account for the spatial inhomogeneity of the scalar dissipation rate, the Eulerian Particle Flamelet Model using the multiple flamelets has been employed. Special emphasis is given to the turbulent combustion model which properly accounts for vaporization effects on turbulence-chemistry interaction.

Flow control by fluidic devices - without moving parts - offers advantages of reliability and low cost. As an example of their automobile application based on authors'' long-time experience the paper describes a fluidic valve for switching exhaust gas flow in a NOx absorber into a by-pass during regeneration phase. The unique feature here is the fluidic valve being of monostable and of axisymmetric design, integrated into the absorber body. After development in aerodynamic laboratory, the final design was tested on engine test stand and finally in a car. This proved that the performance under high temperature and pulsation existing in exhaust systems is reliable and promising. Fluidic valves require, however, close matching with aerodynamic load. To optimize the exhaust system layout for the whole load-speed range and reaching minimum counter- pressure, both the components of exhaust system and control strategy have to be properly adopted.

The residual gas in SI engines is one of important factors on emission and performance such as combustion stability. With high residual gas fractions, flame speed and maximum combustion temperature are decreased and there are deeply related with combustion stability, especially at Idle and NOx emission at relatively high engine load. Therefore, there is a need to characterize the residual gas fraction as a function of the engine operating parameters. A model for predicting the residual gas fraction has been formulated in this paper. The model accounts for the contribution due to the back flow of exhaust gas to the cylinder during valve overlap and it includes in-cylinder pressure prediction model during valve overlap. The model is derived from the one dimension flow process during overlap period and a simple ideal cycle model.

Diesel engines are the most commonly used power train of the freight and public transportations in the world. From the viewpoint of global warming restraint, however, reduction of exhaust emissions from the diesel engine is urgent demand. Stringent emission regulations are being proposed with growing concern on NOx, PM and CO2 emissions. Future emission regulations require advanced emission control technologies, such as SCR(Selective Catalytic Reduction), LNT(Lean NOx Trap) and EGR(Exhaust Gas Recirculation). The EGR is a commonly used technique to reduce emission. In this study, a LP-EGR(Low Pressure Exhaust Gas Recirculation) system was investigated to evaluate its potential on emission reduction and fuel economy improvement, especially for a passenger diesel engine. A 3.0ℓ diesel engine equipped with the LP-EGR system was tested using an in-house control algorithm.

As environmental problems such as global warming are emerging, regulations on automobile exhaust gas are strengthened and various exhaust gas reduction technologies are being developed in various countries in order to satisfy exhaust emission regulations. Exhaust gas recirculation (EGR) technology is a very effective way to reduce nitrogen oxides (NOx) at high combustion temperatures by using EGR coolers to lower the combustion temperature. This EGR cooler has been mass-produced in stainless steel, but it is expensive and heavy. Recently, high efficiency and compactness are required for the EGR cooler to meet the new emission regulation. If aluminum material is applied to the EGR cooler, heat transfer efficiency and light weight can be improved due to high heat transfer coefficient of aluminum compared to conventional stainless steel, but durability is insufficient. Therefore, the aluminum EGR cooler has been developed to enhance performance and durability.

The author's new approach, diesel and gasoline dual fuel powered combustion system based on diesel CI triggered ignition control, provides not only how key ideas extracted from LTC concept could be established in a small bore HSDI turbocharged diesel engine but also which mechanism works to bring almost same benefits as we have experienced in both conventional diesel combustion and LTC based advanced combustion systems like HCCI, PCCI and PPCI combustions. The combustion system presented in the paper physically combines both mixing controlled diesel compression ignition combustion and gasoline premixed charge combustion in one power generation cycle. Gasoline fuel in the system is provided by the conventional gasoline PFI system firstly into the cylinder in which premixed charge spreads out. In compression stroke, the exact amount of diesel fuel is injected into the highly diluted EGR ambient with premixed gasoline charge.

The EPEFE study (European Programme on Emissions, Fuels and Engine Technologies), /1/ and other programmes have identified an increase in tailpipe NOx emissions with reduced gasoline aromatics content for modern 3-way controlled catalyst vehicles. This effect occurs with fully warmed-up catalyst under closed-loop operation. In order to understand the reasons for this effect VW and Shell have mechanistically investigated the effects of fuel properties on EMS (engine management system) and catalyst performance. Fuels with independent variation of oxygen, aromatics and mid-range volatility were tested in different VW engines. λ was monitored using sensors located both pre and post catalyst. The results confirmed that reducing gasoline aromatics content reduced engine-out emissions but increased tailpipe NOx emissions. It could be shown that differences in H/C ratio led to differences in the hydrogen content of engine-out emissions which affected the reading of the λ sensor.

Within the European research programme IDEA (Integrated Diesel European Action), detailed experimental and theoretical studies of the fundamental phenomena of the Diesel engine like flow, injection, mixture formation, auto-ignition, combustion and pollutant formation were carried out to improve knowledge and to set up models for a simulation code. Because this basic research of the Diesel combustion process is very complex and cost intensive, it was carried out jointly by the JRC (Joint Research Committee), an association of European car manufacturers (Fiat, Peugeot SA, Renault, Volvo and Volkswagen). The activities were also subsidized by the Commission of the European Communities and the Swedish National Board of Technical Development. The results of the research work will support the design of even more efficient engines and the further reduction of soot and NOx emissions and will also enable the companies to reduce time and cost in developing new engines.

The NO formation is essentially determined by the flame temperature. In an engine the latter depends on the composition of the fuel and the intake gas. In this study the efficiency of various NO reducing measures is analysed by means of a comparison of measurements and computations for the Most frequent operation point of a 1.9 1 DI Diesel engine. The O2 concentration, which is shown to be the dominant source of influence on the flame temperature and NO formation, is varied using synthetic gas mixtures or by EGR. The molar heat capacity of CO2 and H2O in the recirculated exhaust gas, the intake temperature and the H/C ratio in the fuel are less important for the formation of NO. Measures which reduce the NO formation increase the ignition delay and thereby the fraction of the premixed combustion. The impact of EGR on the combustion process is illustrated by high speed filming.

Strategic Materials at Reaction Temperatures (SMART) is an approach used to design washcoat systems for passive 4-way emission control catalysts. Light duty diesel vehicles need to meet the European Motor Vehicle Emissions Group (MVEG) cycle or U. S. Federal test procedure (FTP 75). Emissions that are monitored include hydrocarbon (HC), nitrogen oxides (NOx), carbon monoxide (CO) and total particulate matter (TPM). Low engine-exhaust temperatures (< 200°C during city driving) and high temperatures (> 500-800°C under full load and wide-open throttle) make emission control a formidable task for the catalyst designer Gas phase HC, CO and NOx reactions must be balanced with the removal of the soluble organic fraction for the vehicle to be in compliance with regulations. The SMART approach uses model gases under typical operating conditions in the laboratory to better understand the function of individual washcoat components.

In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.

In direct-injection gasoline (GDI) engines with charge stratification, minimizing engine-out nitrogen oxide (NOx) emission is crucial since exhaust-gas aftertreatment tolerates only limited amounts of NOx. Reduced NOx production directly lowers the frequency of energy-inefficient catalyst regeneration cycles. In this paper we investigate NO formation in a realistic GDI engine. Quantitative in-cylinder measurements of NO concentrations are carried out via laser-induced fluorescence imaging with excitation of NO (A-X(0,2) band at 248 nm), and subsequent fluorescence detection at 220-240 nm. Engine modifications were kept to a minimum in order to provide results that are representative of practical operating conditions. Optical access via a sapphire ring enabled identical engine geometry as a production line engine. The engine is operated with commercial gasoline (“Super-Plus”, RON 98).

A physics-based model for SCR (Selective Catalytic Reduction) was developed based on five independent SGB (Synthetic Gas Bench) tests. There are NH3 adsorption & desorption test, NO oxidation test, NH3 oxidation test, SCR reaction (NOx & NH3) test and SV (Space Velocity) test. To validate the accuracy of SCR model’s prediction, transient reactor tests were conducted at four different input conditions. A newly developed SCR model showed more than 90% prediction accuracy in transient test conditions in view of cumulative NOx. Validation of SCR model was conducted on 1.6L light duty diesel vehicle in the WLTC (Worldwide Harmonized Light vehicles Test Cycle). Based upon this SCR model, vehicle level SCR calibrations used for urea dosing control were made and validated in the emission test cycles like WLTC.

In a consortium of European industrial partners and research institutes, a combination of industrial development and scientific research was organised. The objective was to improve the catalytic NOx conversion for lean burn cars and heavy-duty trucks, taking into account boundary conditions for the fuel consumption. The project lasted for three years. During this period parallel research was conducted in research areas ranging from basic research based on a theoretical approach to full scale emission system development. NOx storage catalysts became a central part of the project. Catalysts were evaluated with respect to resistance towards sulphur poisoning. It was concluded that very low sulphur fuel is a necessity for efficient use of NOx trap technology. Additionally, attempts were made to develop methods for reactivating poisoned catalysts. Methods for short distance mixing were developed for the addition of reducing agent.

Improved Lean NOx Trap (LNT) catalysts with enhanced NH3 generation feature were developed for the small diesel engine. The next generation LNT system needs to perform good NOx conversions over the wide temperature range including below 200°C for urban driving and above 400°C for motorway of real road driving. However, the extended use of BaO, a component of LNT known to be very effective for high temperature NOx storage, results in the decrease of low temperature NOx conversion due to the degradation of NO oxidation associating with sulfur over time. The improvement of the low-temperature LNT performance is a key requirement for the real driving emission control as the best operation temperature for urea-SCR is above ~250°C. In this study, our next generation LNT with new washcoat architecture has demonstrated improved NOx removal efficiencies under the wider operation temperature window than the current production technology.

In diesel engine development, the new technology is coming out to meet the stringent exhaust emission regulation. The regulation demands more eco-friendly vehicles. Euro6c demands to meet not only WLTP mode, but also RDE(Real Driving Emission). In order to satisfy RDE mode, the new technology to reduce emissions should cover all operating areas including High Load & High Speed. It is a big challenge to reduce NOx on the RDE mode and a lot of DeNOx technologies are being developed. So the new DeNOx technology is needed to cover widened operating area and strict acceleration / deacceleration. The existing LNT(Lean NOx Trap) and Urea SCR(Selective Catalytic Reduction) is necessary to meet the typical NEDC or WLTP, but the RDE mode demands the powerful DeNOx technology. Therefore, the LNT & Urea SCR on DPF was developed through this study.

The reduction of both harmful emissions (CO, HC, NOx, etc.) and gases responsible for greenhouse effects (especially CO2) are mandatory aspects to be considered in the development process of any kind of propulsion concept. Focusing on ICEs, the main development topics are today not only the reduction of harmful emissions, increase of thermodynamic efficiency, etc. but also the decarbonization of fuels which offers the highest potential for the reduction of CO2 emissions. Accordingly, the development of future ICEs will be closely linked to the development of CO2 neutral fuels (e.g. biofuels and e-fuels) as they will be part of a common development process. This implies an increase in development complexity, which needs the support of engine simulations. In this work, the virtual modeling of real fuel behavior is addressed to improve current simulation capabilities in studying how a specific composition can affect the engine performance.

The integration of SCR catalyst into diesel-particulate filter (SDPF) may be one of most viable ways to meet upcoming stringent emission regulations with new test protocols such as Worldwide harmonized Light vehicles Test Cycles (WLTC) and Real Driving Emissions (RDE) requirements. The chabazite-structured SSZ-13-based catalysts enabled the wide implementation of urea-SCR technology for mobile applications due to their robust thermal stability up to 750°C compared to the thermally unstable ZSM-5-based technologies. However, the thermally stable Cu-SSZ-13 catalyst starts losing its initial activity with the increase of aging time at 850°C, where the SCR catalyst on SDPF can possibly be exposed during filter regeneration under a drop-to-idle (DTI) condition. Therefore, more durable SCR catalysts that survive under higher temperatures have been strongly desired in automotive industry. Recently, we found Cu-exchanged high silica LTA revealed an excellent hydrothermal stability.