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Journal Article

A History of Space Toxicology Mishaps: Lessons Learned and Risk Management

2009-07-12
2009-01-2591
After several decades of human spaceflight, the community of space-faring nations has accumulated a diverse and sometimes harrowing history of toxicological events that have plagued human space endeavors almost from the very beginning. Some lessons have been learned in ground-based test beds and others were discovered the hard way - when human lives were at stake in space. From such lessons one can build a risk-management framework for toxicological events to minimize the probability of a harmful exposure, while recognizing that we cannot predict all possible events. Space toxicologists have learned that relatively harmless compounds can be converted by air revitalization systems into compounds that cause serious harm to the crew.
Journal Article

Measuring Diesel Ash Emissions and Estimating Lube Oil Consumption Using a High Temperature Oxidation Method

2009-06-15
2009-01-1843
Diesel engine ash emissions are composed of the non-combustible portions of diesel particulate matter derived mainly from lube oil, and over time can degrade diesel particulate filter performance. This paper presents results from a high temperature oxidation method (HTOM) used to estimate ash emissions, and engine oil consumption in real-time. Atomized lubrication oil and diesel engine exhaust were used to evaluate the HTOM performance. Atomized fresh and used lube oil experiments showed that the HTOM reached stable particle size distributions and concentrations at temperatures above 700°C. The HTOM produced very similar number and volume weighted particle size distributions for both types of lube oils. The particle number size distribution was unimodal, with a geometric mean diameter of about 23 nm. The volume size distribution had a geometric volume mean diameter of about 65 nm.
Journal Article

Design Description and Initial Characterization Testing of an Active Heat Rejection Radiator with Digital Turn-Down Capability

2009-07-12
2009-01-2419
NASA's proposed lunar lander, Altair, will be exposed to vastly different external temperatures following launch till its final destination on the moon. In addition, the heat rejection is lowest at the lowest environmental temperatures (0.5 kW @ 4K) and highest at the highest environmental temperature (4.5 kW @ 215K). This places a severe demand on the radiator design to handle these extreme turn-down requirements. A radiator with digital turn-down capability is currently under study at JPL as a robust means to meet the heat rejection demands and provide freeze protection while minimizing mass and power consumption. Turndown is achieved by independent control of flow branches with isolating latch valves and a gear pump to evacuate the isolated branches. A bench-top test was conducted to characterize the digital radiator concept. Testing focused on the demonstration of proper valve sequencing to achieve turn-down and recharge of flow legs.
Journal Article

Investigation of Fuel Effects on In-Cylinder Reforming Chemistry Using Gas Chromatography

2016-04-05
2016-01-0753
Negative Valve Overlap (NVO) is a potential control strategy for enabling Low-Temperature Gasoline Combustion (LTGC) at low loads. While the thermal effects of NVO fueling on main combustion are well-understood, the chemical effects of NVO in-cylinder fuel reforming have not been extensively studied. The objective of this work is to examine the effects of fuel molecular structure on NVO fuel reforming using gas sampling and detailed speciation by gas chromatography. Engine gas samples were collected from a single-cylinder research engine at the end of the NVO period using a custom dump-valve apparatus. Six fuel components were studied at two injection timings: (1) iso-octane, (2) n-heptane, (3) ethanol, (4) 1-hexene, (5) cyclohexane, and (6) toluene. All fuel components were studied neat except for toluene - toluene was blended with 18.9% nheptane by liquid volume to increase the fuel reactivity.
Journal Article

Late Intake Valve Closing as an Emissions Control Strategy at Tier 2 Bin 5 Engine-Out NOx Level

2008-04-14
2008-01-0637
A fully flexible valve actuation (FFVA) system was developed for a single cylinder research engine to investigate high efficiency clean combustion (HECC) in a diesel engine. The main objectives of the study were to examine the emissions, performance, and combustion characteristics of the engine using late intake valve closing (LIVC) to determine the benefits and limitations of this strategy to meet Tier 2 Bin 5 NOx requirements without after-treatment. The most significant benefit of LIVC is a reduction in particulates due to the longer ignition delay time and a subsequent reduction in local fuel rich combustion zones. More than a 95% reduction in particulates was observed at some operating conditions. Combustion noise was also reduced at low and medium loads due to slower heat release. Although it is difficult to assess the fuel economy benefits of LIVC using a single cylinder engine, LIVC shows the potential to improve the fuel economy through several approaches.
Journal Article

Emissions Effects of Hydrogen as a Supplemental Fuel with Diesel and Biodiesel

2008-04-14
2008-01-0648
A 1.9 liter Volkswagen TDI engine has been modified to accomodate the addition of hydrogen into the intake manifold via timed port fuel injection. Engine out particulate matter and the emissions of oxides of nitrogen were investigated. Two fuels,low sulfur diesel fuel (BP50) and soy methyl ester (SME) biodiesel (B99), were tested with supplemental hydrogen fueling. Three test conditions were selected to represent a range of engine operating modes. The tests were executed at 20, 40, and 60 % rated load with a constant engine speed o 1700 RPM. At each test condition the percentage of power from hydrogen energy was varied from 0 to 40 %. This corresponds to hydrogen flow rates ranging from 7 to 85 liters per minute. Particulate matter (PM) emissions were measured using a scaning mobility particle sizer (SMPS) and a two stage micro dilution system. Oxides of nitrogen were also monitored.
Journal Article

A Freezable Heat Exchanger for Space Suit Radiator Systems

2008-06-29
2008-01-2111
During an ExtraVehicular Activity (EVA), both the heat generated by the astronaut's metabolism and that produced by the Portable Life Support System (PLSS) must be rejected to space. The heat sources include the heat of adsorption of metabolic CO2, the heat of condensation of water, the heat removed from the body by the liquid cooling garment, the load from the electrical components and incident radiation. Although the sublimator hardware to reject this load weighs only 1.58 kg (3.48 lbm), an additional 3.6 kg (8 lbm) of water are loaded into the unit, most of which is sublimated and lost to space, thus becoming the single largest expendable during an eight-hour EVA. Using a radiator to reject heat from the astronaut during an EVA can reduce the amount of expendable water consumed in the sublimator. Radiators have no moving parts and are thus simple and highly reliable. However, past freezable radiators have been too heavy.
Technical Paper

Access Systems for Partial Gravity Exploration & Rescue: Results from Prototype Testing in an Analog Environment

2007-07-09
2007-01-3033
An EVA simulation with a medical contingency scenario was conducted in 2006 with the NASA Haughton-Mars and EVA Physiology System and Performance Projects, to develop medical contingency management and evacuation techniques for planetary surface exploration. A rescue/evacuation system to allow two rescuer astronauts to evacuate one incapacitated astronaut was evaluated. The rescue system was utilized effectively to extract an injured astronaut up a slope of15-25° and into a surface mobility rover for transport to a simulated habitat for advanced medical care. Further research is recommended to evaluate the effects of reduced gravity and to develop synergies with other surface systems for carrying out the contingency procedures.
Technical Paper

Weathering of Thermal Control Coatings

2007-07-09
2007-01-3020
Spacecraft radiators reject heat to their surroundings. Radiators can be deployable or mounted on the body of the spacecraft. NASA's Crew Exploration Vehicle is to use body mounted radiators. Coatings play an important role in heat rejection. The coatings provide the radiator surface with the desired optical properties of low solar absorptance and high infrared emittance. These specialized surfaces are applied to the radiator panel in a number of ways, including conventional spraying, plasma spraying, or as an appliqué. Not specifically designed for a weathering environment, little is known about the durability of conventional paints, coatings, and appliqués upon exposure to weathering and subsequent exposure to solar wind and ultraviolet radiation exposure. In addition to maintaining their desired optical properties, the coatings must also continue to adhere to the underlying radiator panel.
Technical Paper

IVA/EVA Life Support Umbilical System

2007-07-09
2007-01-3228
For NASA's Constellation Program, an Intravehicular Activity (IVA) and Extravehicular Activity (EVA) Life Support Umbilical System (LSUS) will be required to provide environmental protection to the suited crew during Crew Exploration Vehicle (CEV) cabin contamination or depressurization and contingency EVAs. The LSUS will provide the crewmember with ventilation, cooling, power, communication, and data, and will also serve as a crew safety restraint during contingency EVAs. The LSUS will interface with the Vehicle Interface Assembly (VIA) in the CEV and the Suit Connector on the suit. This paper describes the effort performed to develop concept designs for IVA and EVA umbilicals, universal multiple connectors, handling aids and stowage systems, and VIAs that meet NASA's mission needs while adhering to the important guiding principles of simplicity, reliability, and operability.
Technical Paper

Space Suit Radiator Performance in Lunar and Mars Environments

2007-07-09
2007-01-3275
During an ExtraVehicular Activity (EVA), both the heat generated by the astronaut's metabolism and that produced by the Portable Life Support System (PLSS) must be rejected to space. The heat sources include the heat of adsorption of metabolic CO2, the heat of condensation of water, the heat removed from the body by the liquid cooling garment and the load from the electrical components. Although the sublimator hardware to reject this load weighs only 1.58 kg (3.48 lbm), an additional 3.6 kg (8 lbm) of water are loaded into the unit, most of which is sublimated and lost to space, thus becoming the single largest expendable during an eight-hour EVA. Using a radiator to reject heat from the astronaut during an EVA can reduce the amount of expendable water consumed in the sublimator. Last year we reported on the design and initial operational assessment tests of a novel radiator designated the Radiator And Freeze Tolerant heat eXchanger (RAFT-X).
Technical Paper

Continuously Regenerable Freeze-Out CO2 Control Technology

2007-07-09
2007-01-3270
Carbon dioxide (CO2) removal technology development for portable life support systems (PLSS) has traditionally concentrated in the areas of solid and liquid chemical sorbents and semi-permeable membranes. Most of these systems are too heavy in gravity environments, require prohibitive amounts of consumables for operation on long term planetary missions, or are inoperable on the surface of Mars due to the presence of a CO2 atmosphere. This paper describes the effort performed to mature an innovative CO2 removal technology that meets NASA's planetary mission needs while adhering to the important guiding principles of simplicity, reliability, and operability. A breadboard cryogenic carbon dioxide scrubber for an ejector-based cryogenic PLSS was developed, designed, and tested. The scrubber freezes CO2 and other trace contaminants out of expired ventilation loop gas using cooling available from a liquid oxygen (LOX) based PLSS.
Technical Paper

Crew Exploration Vehicle Environmental Control and Life Support Fire Protection Approach

2007-07-09
2007-01-3255
As part of preparing for the Crew Exploration Vehicle (CEV), the National Aeronautics and Space Administration (NASA) worked on developing the requirements to manage the fire risk. The new CEV poses unique challenges to current fire protection systems. The size and configuration of the vehicle resembles the Apollo capsule instead of the current Space Shuttle or the International Space Station. The smaller free air volume and fully cold plated avionic bays of the CEV requires a different approach in fire protection than the ones currently utilized. The fire protection approach discussed in this paper incorporates historical lessons learned and fire detection and suppression system design philosophy spanning from Apollo to the International Space Station.
Technical Paper

Inhibition of Biofilm Formation on the Service and Performance Heat Exchanger by Quorum Sensing Inhibition

2007-07-09
2007-01-3143
Shortly after installation of the service and performance heat exchanger (SPCU HX) in 2001, samples collected from the coolant fluid indicated the presence of nickel accompanied by a subsequent decrease in phosphate concentration along with a high microbial load. When the SPCU HX was replaced and evaluated post-flight, it was expected that the heat exchanger would have significant biofilm and corrosion present given the composition of the coolant fluid; however, there was no evidence of either. Early results from two experiments imply that the heat exchanger materials themselves are inhibiting biofilm formation. This paper discusses the results of one set of experiments and puts forward the inhibition of quorum sensing as a possible mechanism for the lack of biofilm formation.
Technical Paper

Digital Learning Network Education Events for the Desert Research and Technology Studies

2007-07-09
2007-01-3063
NASA's Digital Learning Network (DLN) reaches out to thousands of students each year through video conferencing and webcasting. As part of NASA's Strategic Plan to reach the next generation of space explorers, the DLN develops and delivers educational programs that reinforce principles in the areas of science, technology, engineering and mathematics. The DLN has created a series of live education videoconferences connecting the Desert Research and Technology Studies (RATS) field test to students across the United States. The programs are also extended to students around the world via live webcasting. The primary focus of the events is the Vision for Space Exploration. During the programs, Desert RATS engineers and scientists inform and inspire students about the importance of exploration and share the importance of the field test as it correlates with plans to return to the Moon and explore Mars. This paper describes the events that took place in September 2006.
Technical Paper

ISRU Production of Life Support Consumables for a Lunar Base

2007-07-09
2007-01-3106
Similar to finding a home on Earth, location is important when selecting where to set up an exploration outpost. Essential considerations for comparing potential lunar outpost locations include: (1) areas nearby that would be useful for In-Situ Resource Utilization (ISRU) oxygen extraction from regolith for crew breathing oxygen as well as other potential uses; (2) proximity to a suitable landing site; (3) availability of sunlight; (4) capability for line-of-sight communications with Earth; (5) proximity to permanently-shadowed areas for potential in-situ water ice; and (6) scientific interest. The Mons Malapert1 (Malapert Mountain) area (85.5°S, 0°E) has been compared to these criteria, and appears to be a suitable location for a lunar outpost.
Technical Paper

Characterization of Exhaust Particulate Emissions from a Spark Ignition Engine

1998-02-23
980528
Exhaust particulate emissions from a 4-cylinder, 2.25 liter spark ignition engine were measured and characterized. A single-stage ejector-diluter system was used to dilute and cool the exhaust sample for measurement. The particulate measurement equipment included a condensation nucleus counter and a scanning mobility particle sizer. Exhaust measurements were made both upstream and downstream of the catalytic converter using three different fuels. Unlike particulate emissions in diesel engines, spark ignition exhaust particle emissions were found to be highly unstable. Typically, a stable “baseline” concentration on the order of 105 particles/cm3 is emitted. Occasionally, however, a “spike” in the exhaust particle concentration is observed. The exhaust particle concentrations observed during these spikes can increase by as much as two orders of magnitude over the baseline concentration.
Technical Paper

Diesel Exhaust Particle Size: Measurement Issues and Trends

1998-02-23
980525
Exhaust particle number concentrations and size distributions were measured from the exhaust of a 1995 direct injection, Diesel engine. Number concentrations ranged from 1 to 7.5×107 particles/cm3. The number size distributions were bimodal and log-normal in form with a nuclei mode in the 7-15 nm diameter range and an accumulation mode in the 30-40 nm range. For nearly all operating conditions, more than 50% of the particle number, but less than 1% of the particle mass were found in the nuclei mode. Preliminary indications are that the nuclei mode particles are solid and formed from volatilization and subsequent nucleation of metallic ash from lubricating oil additives. Modern low emission engines produce low concentrations of soot agglomerates. The absence of these agglomerates to act as sites for adsorption or condensation of volatile materials makes nucleation and high number emissions more likely.
Technical Paper

Comparing Measurements of Carbon in Diesel Exhaust Aerosols Using the Aethalometer, NIOSH Method 5040, and SMPS

2007-04-16
2007-01-0334
Combustion aerosols consist mainly of elemental and organic carbon (EC and OC). Since EC strongly absorbs light and thus affects atmospheric visibility and radiation balance, there is great interest in its measurement. To this end, the National Institute for Occupational Safety and Health (NIOSH) published a standard method to determine the mass of EC and OC on filter samples. Another common method of measuring carbon in aerosols is the aethalometer, which uses light extinction to measure “black carbon” or BC, which is considered to approximate EC. A third method sometimes used for estimating carbon in submicron combustion aerosols, is to measure particle size distributions using a scanning mobility particle sizer (SMPS) and calculate mass using the assumptions that the particles are spherical, carbonaceous and of known density.
Technical Paper

Significance of Fuel Sulfur Content and Dilution Conditions on Particle Emissions from a Heavily-Used Diesel Engine During Transient Operation

2007-04-16
2007-01-0319
The effects of fuel sulfur content and dilution conditions on diesel engine PM number emissions have been researched extensively through steady state testing. Most results show that the concentration of nuclei-mode particles emitted increases with fuel sulfur content. A few studies further observed that fuel sulfur content has little effect on the emissions of heavily-used engines. It has also been found that primary dilution conditions can have a large impact on the size and number distribution of the nuclei-mode particles. These effects, however, have not yet been fully understood through transient testing, the method used by governments worldwide to certify engines and regulate emissions, and a means of experimentation which generates realistic conditions of on-road vehicles by varying the load and speed of the engine.
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