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The understanding of deactivation mechanisms is critical to the development of NOx adsorber catalysts with improved durability. The thermal deactivation of a state-of-the-art Pt/Rh based NOx adsorber catalyst is evaluated following oven agings at 800 and 900°C. Sulfur poisoning during lean/rich cycling is studied as a function of catalyst inlet temperature and SO2 concentration. Complementing these studies utilizing synthetic exhaust gas compositions, deactivation resulting from three different engine aging schedules is examined. The performance of engine-aged catalysts is evaluated as received, and following desulfurization procedures differing in inlet temperature and air/fuel ratio. The impact of aging schedules on NOx adsorption and three-way catalyst function is discussed with respect to precious metal dispersion, washcoat sintering, as well as sulfur build-up and oil-derived poisonings.

The transition from Euro2 to Euro3 emission standards for passenger diesel vehicles requires very good hydrocarbon control coupled with moderate, passive NOx reduction. In some cases, CO and PM conversion is also required. Passive NOx reduction, that is, selective catalytic reduction of NOx by hydrocarbons without delivery of hydrocarbon specifically for this purpose, requires good management of a scarce hydrocarbon resource. At the same time, increased requirements for HC control demand that unconverted HC be further minimized. Appropriately designed lean NOx catalysts with hydrocarbon adsorber capabilities offer very good HC control with moderate NOx reduction performance when fresh. However, certain zeolite structures appear quite unstable under high temperature aging, yielding significant declines in aged NOx performance. Instabilities can be avoided through proper choice of molecular sieve structure and composition, together with suitable washcoat structure.

Increasing interest in lean NOx catalysis at temperatures between about 300-550°C has led to development of catalytic materials with thermal durability considerably improved over academic benchmark catalysts such as Cu-ZSM-5. The breaching of thermal durability barriers brings new obstacles into focus. Practical implementation of high temperature HC-based lean NOx catalysis entails delivery of hydrocarbons to the catalyst inlet at high temperatures. We have found initially unexpected, but scientifically precedented, phenomena regarding gas-phase kinetic instability of hydrocarbons in diesel exhaust atmospheres above 300°C. Around 300°C, homogeneous hydrocarbon oxidation can begin to occur. Rates of oxidation decrease between about 350-450°C and then increase again at higher temperatures. Some apparent NOx disappearance that does not correspond to chemical reduction of NOx can also occur homogeneously throughout this temperature range.

The aggressive reduction of future diesel engine NOx emission limits forces the heavy- and light-duty diesel engine manufacturers to develop means to comply with stringent legislation. As a result, different exhaust emission control technologies applicable to NOx have been the subject of many investigations. One of these systems is the NOx adsorber catalyst, which has shown high NOx conversion rates during previous investigations with acceptable fuel consumption penalties. In addition, the NOx adsorber catalyst does not require a secondary on-board reductant. However, the NOx adsorber catalyst also represents the most sulfur sensitive emissions control device currently under investigation for advanced NOx control. To remove the sulfur introduced into the system through the diesel fuel and stored on the catalyst sites during operation, specific regeneration strategies and boundary conditions were investigated and developed.

A main focus of development in modern SI engine technology is variable valve timing, which implies a high potential of improvement regarding fuel consumption and emissions. Variable opening, period and lift of inlet and outlet valves enable numerous possibilities to alter gas exchange and combustion. However, this additional variability generates special demands on the calibration process of specific engine control devices, particularly under cold start and warm-up conditions. This paper presents procedures, based on Hardware-in-the-Loop (HiL) simulation, to support the classical calibration task efficiently. An existing approach is extended, such that a virtual combustion engine is available including additional valve timing variability. Engine models based purely on physical first principles are often not capable of real time execution. However, the definition of initial parameters for the ECU requires a model with both real time capability and sufficient accuracy.

A vehicle investigation programme was initiated to evaluate the influence of diesel fuel sulfur content on the performance of a DeNOx catalyst for NOx control. The programme was conducted with a passive DeNOx catalyst, selected for its good NOx reduction performance and two specially prepared fuels with different sulfur contents. Regulated emissions were measured and analysed during the course of the programme. The NOx conversion efficiency of the DeNOx catalyst increased from 14 to 26% over the new European test cycle when the sulfur content of the diesel fuel was reduced from 49 to 6 wt.-ppm. In addition the number and size of particles produced using 6 wt.-ppm sulfur fuel were measured by two different techniques: mobility diameter by SMPS and aerodynamic diameter by impactor. The influence of the assumed density of the particulate on the apparent diameters measured by the two techniques is discussed.

The use of catalytic aftertreatment to reduce harmful gases in the exhaust streams of 2-wheel vehicles powered by small engines is becoming widespread as increasingly restrictive emissions standards are enacted. The primary exhaust gas pollutants are carbon monoxide (CO) and hydrocarbons (HC) for vehicles equipped with 2-stroke engines and CO for those using 4-stroke power plants. Because the exhaust streams of these small engines also contain significant concentrations of oxygen, catalytic aftertreatment is a very effective approach for oxidizing these contaminants to carbon dioxide and water. In order to assure the maximum long term benefits of catalytic aftertreatment, it is necessary to understand not only the factors responsible for high initial activity, but also the mechanisms by which a catalyst's performance is negatively impacted.