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Fuels derived from biomass will most likely contain oxygen due to the high amount of hydrogen needed to remove oxygen in the production process. Today, alcohol fuels (e. g. ethanol) are well understood for spark ignition engines. The Institute for Combustion Engines at RWTH Aachen University carried out a fuel investigation program to explore the potential of alcohol fuels as candidates for future compression ignition engines to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. The soot formation and oxidation process when using alcohol fuels in diesel engines is not yet sufficiently understood. Depending on the chain length, alcohol fuels vary in cetane number and boiling temperature. Decanol possesses a diesel-like cetane number and a boiling point in the range of the diesel boiling curve. Thus, decanol was selected as an alcohol representative to investigate the influence of the oxygen content of an alcohol on the combustion performance.

The requirement of reducing worldwide CO₂ emissions and engine pollutants are demanding an increased use of bio-fuels. Ethanol with its established production technology can contribute to this goal. However, due to its resistive auto-ignition behavior the use of ethanol-based fuels is limited to the spark-ignited gasoline combustion process. For application to the compression-ignited diesel combustion process advanced ignition systems are required. In general, ethanol offers a significant potential to improve the soot emission behavior of the diesel engine due to its oxygen content and its enhanced evaporation behavior. In this contribution the ignition behavior of ethanol and mixtures with high ethanol content is investigated in combination with advanced ignition systems with ceramic glow-plugs under diesel engine relevant thermodynamic conditions in a high pressure and temperature vessel.