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In this work, a 5-zone model has been applied to replicate the in-cylinder conditions evolution of a Rapid Compression-Expansion Machine (RCEM) in order to improve the chemical kinetic analyses by obtaining more accurate simulation results. To do so, CFD simulations under motoring conditions have been performed in order to identify the proper number of zones and their relative volume, walls surface and temperature. Furthermore, experiments have been carried out in an RCEM with different Primary Reference Fuels (PRF) blends under homogeneous conditions to obtain a database of ignition delays and in-cylinder pressure and temperature evolution profiles. Such experiments have been replicated in CHEMKIN by imposing the heat losses and volume profiles of the experimental facility using a 0-D 1-zone model. Then, the 5-zone model has been analogously solved and both results have been compared to the experimental ones.

A fundamental study to experimentally analyze the effect of cavitation in common-rail diesel nozzles on the soot formation process was carried out. The soot content was characterized by measuring the soot radiation, and an original methodology was developed to suitably characterize the soot formation process from this soot content. After a significant effort to overcome the different difficulties when analyzing the experimental data, the results seem to show a promising conclusion: cavitation reduces the soot formation rate. This reduction is explained, on the one hand, because it leads to a reduction in the effective diameter, thus diminishing the equivalence fuel/air ratio at the lift-off length; and, on the other hand, because it provokes an increase in effective velocity, thus increasing the lift-off length and reducing the corresponding equivalence fuel/air ratio.