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A cooperative vehicle exhaust emissions test program was conducted by the California Air Resources Board and Chevron Research and Technology Company. The focus of the program was to determine the effect of aromatics content on nitrogen oxides (NOx) emissions. The program consisted of testing nine vehicles on three different fuels. The fuels ranged in aromatics content from 10% to 30%.* Other fuel properties were held as constant as possible. The tests were conducted in two different laboratories. In addition to the measurement of criteria emissions (hydrocarbons, carbon monoxide, and NOx), some of the hydrocarbon emissions were speciated and a reactivity of the exhaust was calculated. Only slight changes in the exhaust emissions and reactivity were observed for a change in aromatics content from 30% to 10%.

Emissions from heavy-duty vehicles are a major contributor to California's air quality problems. Emissions from these vehicles account for approximately 30% of the nitrogen oxide and 75% of the particulate matter emissions from the entire on-road vehicle fleet. Additionally, excessive exhaust smoke from in-use heavy-duty diesel vehicles is a target of numerous public complaints. In response to these concerns, California has adopted an in-use Heavy-Duty Vehicle Smoke and Tampering Inspection Program (HDVIP) designed to significantly reduce emissions from these vehicles. Pending promulgation of HDVIP regulations, vehicles falling prescribed test procedures and emission standards will be issued citations. These citations mandate expedient repair of the vehicle and carry civil penalties ranging from $300 to $1800. Failure to clear citations can result in the vehicle being removed from service.

Since the mid-1990s, light-duty vehicles equipped with gasoline direct injection (GDI) engines have been added to the vehicle fleet in increasing numbers. Compared to conventional port fuel injection (PFI) engines, GDI engines provide higher power output for the same size engine, higher fuel efficiency, and lower carbon dioxide (CO₂) emissions. Due to the paucity of particulate matter (PM) emission data for light-duty gasoline vehicles in general and the increasing interest in these emissions relative to climate and air quality concerns, it is important to investigate PM emissions from current-generation GDI technologies. In this study, nine 2007-2010 light-duty GDI vehicles equipped with either wall-guided or spray-guided fuel injection systems were tested using California commercial gasoline fuel containing six percent ethanol by volume. Criteria pollutants including gaseous and PM emissions were measured over the Federal Test Procedure (FTP) transient test cycle.

Heavy-duty vehicles account for approximately 30 percent of the oxides of nitrogen (NOx) and 65 percent of the particulate matter (PM) emissions from the entire California on-road fleet, despite the fact that these vehicles comprise only 2 percent of the same. To meet legislative mandates to reduce excess smoke emissions from in-use heavy-duty diesel-powered vehicles, the Air Resources Board (ARB or Board) adopted, in December 1997, amendments to the regulations governing the operation and enforcement of the Heavy-Duty Vehicle Inspection Program (HDVIP or the “roadside” program) and the Periodic Smoke Inspection Program (PSIP or the “fleet” program). The initial roadside program was adopted in November 1990 in response to Senate Bill (SB) 1997 (stat. 1988, ch. 1544, Presley), and enforced from 1991 to 1993. It was suspended in October 1993, when the Board redirected staff to investigate reformulated fuels issues.

In order to demonstrate the performance of a retrofitted selective catalytic reduction (SCR) system while also addressing the issues associated with greater use of biodiesel, a 2005 International 9200i tractor owned by the City of Santa Monica was retrofitted with a titania-vanadia-tungsten catalyst and a urea dosing system supplied by Extengine Systems, Inc. This tractor was operated under normal service conditions within the City of Santa Monica refuse collection and transportation fleet. An on-board emissions measurement system supplied by Engine, Fuel, and Emissions Engineering, Inc. was installed on the vehicle; it measured the emissions and fuel use of the vehicle while it operated on ultra-low-sulfur diesel (ULSD), 20% biodiesel (B20), and 99% biodiesel (B99) on consecutive days.

When the California Air Resources Board (ARB) adopted automotive exhaust emission standards for Super Ultra-Low-Emission Vehicles (SULEV), new challenges were encountered for accurately measuring exhaust emissions. This is especially true for measuring NMOG emissions (NMHC and carbonyls) where the SULEV standard is 0.010 g/mi. One of the challenges in accurately measuring NMHC emissions is to find a clean sample bag material that has no or very low outgassing of hydrocarbons. Tedlar, the bag material commonly used for exhaust emission sampling, has been found to emit N,N- dimethylacetamide (DMAc), which interferes with hydrocarbon measurements and can contribute to significant error in SULEV hydrocarbon emission measurements. Several fluorocarbon materials were tested for hydrocarbon (HC) outgassing and carbon dioxide (CO2) permeation. The materials include Tedlar, Baked Tedlar, KynarFlex 2750, Baked KynarFlex 2800, Teflon FEP, TFM TFE, Tefzel, and Halar.

The use of a partial flow sampling system (PFSS) to measure nonroad steady-state diesel engine particulate matter (PM) emissions is a technique for certification approved by a number of regulatory agencies around the world including the US EPA. Recently, there have been proposals to change future nonroad tests to include testing over a nonroad transient cycle. PFSS units that can quantify PM over the transient cycle have also been discussed. The full flow constant volume sampling (CVS) technique has been the standard method for collecting PM under transient engine operation. It is expensive and requires large facilities as compared to a typical PFSS. Despite the need for a cheaper alternative to the CVS, there has been a concern regarding how well the PM measured using a PFSS compared to that measured by the CVS. In this study, three PFSS units, including AVL SPC, Horiba MDLT, and Sierra BG-2 were investigated in parallel with a full flow CVS.

The use of methanol as a “clean fuel” appears to be a viable approach to reduce air pollution. However, concern has been expressed about potentially high formaldehyde emissions from stoichiometrically operated light-duty vehicles. This paper presents results from an emission test program conducted for the California Air Resources Board (CARB) and the South Coast Air Quality Management District (SCAQMD) to identify and evaluate advanced catalyst technology to reduce formaldehyde emissions without compromising regulated emission control. An earlier paper presented the results of evaluating eighteen different catalyst systems on a hybrid methanol-fueled test vehicle. (1)* This paper discusses the optimization of three of these catalyst systems on four current technology methanol-fueled vehicles. Emission measurements were conducted for formaldehyde, nonmethane organic gases (NMOG), methanol, carbon monoxide, and oxides of nitrogen emissions.

Heavy duty diesel vehicle (HDDV) emissions are known to affect air quality, but few studies have quantified the real-world contribution to the inventory. The objective of this study was to provide data that may enable ambient emissions investigators to m,odel the air quality more accurately. The 25 vehicles reported in this paper are from the first phase of a program to determine representative regulated emissions from Heavy Heavy-Duty Diesel Trucks (HHDDT) operating in Southern California. Emissions data were gathered using a chassis dynamometer, full flow dilution tunnel, and research grade analyzers. The subject program employed two truck test weights and four new test modes (one was idle operation), in addition to the Urban Dynamometer Driving Schedule (UDDS), and the AC50/80 cycle. The reason for such a broad test cycle scope was to determine thoroughly how HHDDT emissions are influenced by operating cycle to improve accuracy of models.

A novel in situ method was performed for measuring emissions and fuel consumption of transport refrigeration units (TRUs). The test matrix included two fuels, two exhaust configurations, and two TRU engine operating speeds. The test fuels were California ultra low sulfur diesel and gas-to-liquid (GTL) diesel. The exhaust configurations were a stock original equipment manufacturer (OEM) muffler and a Thermo King pDPF™ diesel particulate filter. The two TRU engine operating speeds were high and low, as controlled by the TRU user interface. Test results indicate that GTL diesel fuel reduces all regulated emissions at high and low engine operating speeds. Separately, the application of a Thermo King pDPF reduced regulated emissions, in some cases almost entirely. Finally, the application of both GTL diesel and a Thermo King pDPF reduced regulated emissions at high engine operating speed, but with an increase in oxides of nitrogen (NOx) at low engine speed.

This paper covers work performed for the California Air Resources Board and US Environmental Protection Agency by Southwest Research Institute. Emission measurements were made on four in-use off-road two-stroke motorcycles and all-terrain vehicles utilizing oxygenated and non-oxygenated fuels. Emission data was produced to augment ARB and EPA's off-road emission inventory. It was intended that this program provide ARB and EPA with emission test results they require for atmospheric modeling. The paper describes the equipment and engines tested, test procedures, emissions sampling methodologies, and emissions analytical techniques. Fuels used in the study are described, along with the emissions characterization results. The fuel effects on exhaust emissions and operation due to ethanol content and fuel components is compared.

The U.S. EPA and the California Air Resources Board have adopted standards to reduce emissions from recreational marine vessels. Existing regulations focus on reducing hydrocarbons. There are no regulations on particulate emissions; particulate is expected to be reduced as a side benefit of hydrocarbon control. The goal of this study was to develop a sampling methodology to measure particulate emissions from marine outboard and personal watercraft engines. Eight marine engines of various engine technologies and power output were tested. Emissions measured in this program included hydrocarbons, carbon monoxide, oxides of nitrogen. Particulate emissions will be presented in a follow-up paper.

While most studies addressing the fuel effects are based on the Federal Test Procedure (FTP), there are limited studies investigating the fuel effects outside FTP test conditions. In this study, we investigated the differences in exhaust emissions from California Phase 1 to Phase 2 reformulated gasoline over a wide range of speed and ambient temperatures. Eleven catalyst equipped passenger vehicles were tested. The vehicles were comprised of three fuel delivery system configurations, namely, three from carburetor (CARBU), three from throttle body injection (TBI), and five from multi-port fuel injection (MPFI) group. Each vehicle was given 60 tests with the combination of two reformulated fuels: Phase 1 (without oxygenates) and Phase 2 (with oxygenates), three temperatures (50, 75, and 100 °F), and ten speed cycles (average speed ranges from 4 mph to 65 mph).

The California Air Resources Board (CARB) examined the performance of a Partial Flow Sampling System (PFSS) against a reference Constant Volume Sampling (CVS) system in measuring emissions from a heavy-duty vehicle (HDV) during dynamometer testing at CARB's Stockton Heavy-Duty Emissions Laboratory (SL). The SL PFSS system is a Sierra BG-2 system that uses flow-based (rather than CO2-based) dilution. The CVS system uses the University of California, Riverside's (UCR) Mobile Emissions Laboratory (MEL). The test vehicle was a 2000 model-year HD tractor powered by a CAT C-15 engine. Exhaust samples were collected simultaneously with the SL and MEL systems and analyzed for total particulate matter (PM), oxides of nitrogen (NOx), carbon dioxide (CO2), carbon monoxide (CO), and total hydrocarbons (THC). The samples were taken during steady-state vehicle operation. Each test mode was repeated seven times in each of two patterns: consecutive and sequential.

The goal of the project was to reduce tailpipe-out hydrocarbon (HC) plus oxides of nitrogen (NOx) emissions to 50 percent or less of the current California Air Resources Board (CARB) useful life standard of 12 g/hp-hr for Class I engines, or 9 g/hp-hr for Class II engines. Low-emission engines were developed using three-way catalytic converters, passive secondary-air induction (SAI) systems, and in two cases, enleanment. Catalysts were integrated into the engine's mufflers, where feasible, to maintain a compact package. Due to the thermal sensitivity of these engines, carburetor calibrations were left unchanged in four of the six engines, at the stock rich settings. To enable HC oxidation under such rich conditions, a simple passive supplemental air injection system was developed. This system was then tuned to achieve the desired HC+NOx reduction.

Programs to control motor vehicle emissions originated in California as a result of Professor A.J. Haagen-Smit of the California Institute of Technology discovering that two invisible automobile emissions, hydrocarbons and oxides of nitrogen, react together in the presence of sunlight to form oxidants such as ozone, a principal ingredient of the infamous Los Angeles area “smog”. The State of California became the first government to regulate the emissions of new automobiles when it adopted requirements for the use of positive crankcase ventilation (PCV) valves beginning with the 1963 model year.

Gasohol, a blend of 90 percent unleaded gasoline and 10 percent ethanol, has been represented as an alternative to pure gasoline which can reduce the nation’s crude oil dependence. However, a systems analysis of the gasohol production processes indicates that gasohol is increasing rather than decreasing the nation’s dependence on crude oil. Alternative uses of the petroleum and natural gas currently used to manufacture ethanol would reduce the nation’s demand for oil. At the present time, every gallon of crude oil “saved” by substituting ethanol for gasoline results in a need to import approximately two gallons of crude oil. The federal government’s claim that gasohol can reduce the nation’s dependence on imported energy appears, to be based principally on political considerations, but also on the assumption that coal will eventually replace the petroleum and natural gas currently used in the gasohol production wherever possible.

The California Air Resources Board conducted an extensive field test program to evaluate a vehicle exhaust recirculation system for control of oxides of nitrogen. The system utilized hot exhaust gases from the crossover and included certain modifications to the carburetion, choke, and crank case ventilation system. It was tested on two fleets of automobiles equipped wtih California approved HC and CO emission control devices. The test program involved periodic measurements of exhaust emissions and fuel consumption. The effect of the system on vehicle drivability, engine deposits, wear, and oil deterioration was also studied. The Atlantic Richfield Company, under contract to the Air Resources Board, equipped the vehicles with the recirculation system and performed the final engine inspection.

There have been a half dozen surveys performed by the California Air Resources Board in California from December, 1977 to July, 1982 to determine the rate of vehicle misfueling in California. There has been great concern raised over misfueling which leads to the poisoning of catalysts and the subsequent increases in emissions of hydrocarbons, carbon monoxide and oxides of nitrogen. The results of observing refueling at service stations indicate a misfueling rate of about 2% which is much lower than what the U. S. Environmental Protection Agency figures indicate. Misfueling at self-serve stations is more than twice that noted at full-serve stations. The primary reasons given by motorists for misfueling are cheaper price of unleaded gasoline, performance (including pinging) and unavailability of unleaded fuel. Misfueling was accomplished primarily as a result of a modified restrictor or filler neck.

Current California law requires the implementation of a mandatory annual vehicle emissions inspection and maintenance program in the South Coast Air Basin by 1978. The pilot phase of this inspection program is now in operation in the City of Riverside. This paper evaluates the Riverside program and an alternate program for their abilities to detect gross emitters and provide cost/effective emissions reductions. A surveillance program was conducted to evaluate the Riverside loaded-mode inspection regime and an alternate idle inspection regime. Emissions and fuel economy tests indicated that there was no significant difference between the two regimes. Each regime resulted in immediate reductions on repaired vehicles of 35-40% in hydrocarbon emissions and 30-35% in carbon monoxide emissions, with no significant change in oxides of nitrogen emissions. There was a small (1-4%) improvement in fuel economy, and the average repair cost was $20-25.