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Hydrogen is widely considered a promising fuel for future transportation applications for both, internal combustion engines and fuel cells. Due to their advanced stage of development and immediate availability hydrogen combustion engines could act as a bridging technology towards a wide-spread hydrogen infrastructure. Although fuel cell vehicles are expected to surpass hydrogen combustion engine vehicles in terms of efficiency, the difference in efficiency might not be as significant as widely anticipated [1]. Hydrogen combustion engines have been shown capable of achieving efficiencies of up to 45 % [2]. One of the remaining challenges is the reduction of nitric oxide emissions while achieving peak engine efficiencies. This paper summarizes research work performed on a single-cylinder hydrogen direct injection engine at Argonne National Laboratory.

The autoignition resistance of a practical gasoline is best characterized by the Octane Index, OI, defined as RON-KS, where RON and MON are respectively, Research and Motor Octane Numbers, S is the sensitivity (RON-MON) and K is a constant depending on the pressure and temperature history of the fuel/air mixture in an engine. Experiments in knocking SI engines, HCCI engines and in premixed compression ignition (PCI) engines have shown that if two fuels of different composition have the same OI and experience the same pressure/temperature history, they will have the same autoignition phasing. A practical gasoline is a complex mixture of hydrocarbons and a simple surrogate is needed to describe its autoignition chemistry. A mixture of toluene and PRF (iso-octane + n-heptane), TPRF, can have the same RON and S as a target gasoline and so will have the same OI at any given K value and will be a very good surrogate for the gasoline.

The paper presents the results of co-combustion of diesel with hydrogen and biodiesel with hydrogen in a compression-ignition internal combustion engine. The results show that for both cases of combustion diesel with hydrogen and biodiesel with hydrogen a noticeable change in combustion phases were achieved. The addition of hydrogen causes the combustion process more efficient what also has a positive effect for thermal efficiency of dual fuel engine and showed an increase in the value of this parameter of 5% compared to diesel or biodiesel. Comparison of combustion process between conventional engine fueled by diesel or biodiesel and diesel with hydrogen or biodiesel with hydrogen shows the differences in character of heat release rate. The premixed combustion phase after addition of hydrogen to base liquid fuel show an increase in maximum value. The combustion stability of the engine described by the COVIMEP index and the IMEP normal distribution was also assessed.

Pre-chamber combustion (PCC) is a promising engine combustion concept capable of extending the lean limit at part load. The engine experiments in the literature showed that the PCC could achieve higher engine thermal efficiency and much lower NOx emission than the spark-ignition engine. Improved understanding of the detailed flow and combustion physics of PCC is important for optimizing the PCC combustion. In this study, we investigated the gas exchange and flame jet from a narrow throat pre-chamber (PC) by only fueling the PC with methane in an optical engine. Simultaneous negative acetone planar laser-induced fluorescence (PLIF) imaging and OH* chemiluminescence imaging were applied to visualize the PC jet and flame jet from the PC, respectively. Results indicate a delay of the PC gas exchange relative to the built-up of the pressure difference (△ P) between PC and the main chamber (MC). This should be due to the gas inertia inside the PC and the resistance of the PC nozzle.

Pre-chamber combustion (PCC) allows an extension on the lean limit of an internal combustion engine (ICE). This combustion mode provides lower NOx emissions and shorter combustion durations that lead to a higher indicated efficiency. In the present work, a narrow throat pre-chamber was tested, which has a unique nozzle area distribution in two rows of six nozzle holes each. Tests were carried out in a modified heavy-duty engine for optical visualization. Methane was used as fuel for both the pre-chamber and the main chamber. Seven operating points were tested, including passive pre-chamber mode as a limit condition, to study the effect of pre- and main-chamber fuel addition on the pre-chamber jets and the main chamber combustion via chemiluminescence imaging. A typical cycle of one of the tested conditions is explained through the captured images. Observations of the typical cycle reveal a predominant presence of only six jets (from the lower row), with well-defined jet structures.

The increasing demand for high-octane fuels is pushing the combustion research towards investigating new potential fuels and octane boosters. In addition to their high-octane, those additives should be environmentally friendly. In this study, the anti-knock properties of Dicyclopentadiene (DCPD) as an additive to primary reference fuels (PRF) and toluene primary reference fuels (TPRF) have been investigated. The Research octane number (RON) and Motor octane number (MON) were measured using Cooperative Fuels Research (CFR) engine for four different fuel blends; PRF 60 + 10% DCPD, PRF 60 + 20% DCPD, PRF 70 + 10% DCPD and TPRF 70 + 10% DCPD. In addition, homogenous charge compression ignition (HCCI) was also performed using the CFR engine to show the effect of DCPD on suppressing low temperature chemistry of reference fuels.

Increasing regulatory demand for efficiency has led to development of novel combustion modes such as HCCI, GCI and RCCI for gasoline light duty engines. In order to realize HCCI as a compression ignition combustion mode system, in-cylinder compression temperatures must be elevated to reach the autoignition point of the premixed fuel/air mixture. This should be co-optimized with appropriate fuel formulations that can autoignite at such temperatures. CFD combustion modeling is used to model the auto ignition of gasoline fuel under compression ignition conditions. Using the fully detailed fuel mechanism consisting of thousands of components in the CFD simulations is computationally expensive. To overcome this challenge, the real fuel is represented by few major components of create a surrogate fuel mechanism. In this study, 9 variations of gasoline fuel sets were chosen as candidates to run in HCCI combustion mode.

Past experimental studies conducted by the current authors on a 13 liter 16.7:1 compression ratio heavy-duty diesel engine have shown that diesel-Compressed Natural Gas (CNG) Reactivity Controlled Compression Ignition (RCCI) combustion targeting low NOx emissions becomes progressively difficult to control as the engine load is increased. This is mainly due to difficulty in controlling reactivity levels at higher loads. For the current study, CFD investigations were conducted in CONVERGE using the SAGE combustion solver with the application of the Rahimi mechanism. Studies were conducted at a load of 5 bar BMEP to validate the simulation results against RCCI experimental data. In the low load study, it was found that the Rahimi mechanism was not able to predict the RCCI combustion behavior for diesel injection timings advanced beyond 30 degCA bTDC. This poor prediction was found at multiple engine speed and load points.

Gasoline compression ignition (GCI) technology shows the potential to obtain high thermal efficiencies while maintaining low soot and NOx emissions in light-duty engine applications. Recent experimental studies and numerical simulations have indicated that high reactivity gasoline-like fuels can further enable the benefits of GCI combustion. However, there is limited empirical data in the literature studying the gasoline compression ignition process at relevant in-cylinder conditions, which are required for further optimizing combustion system designs. This study investigates the temporal and spatial evolution of the compression ignition process of various high reactivity gasoline fuels with research octane numbers (RON) of 71, 74 and 82, as well as a conventional RON 97 E10 gasoline fuel. A ten-hole prototype gasoline injector specifically designed for GCI applications capable of injection pressures up to 450 bar was used.

It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil-derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter.

The application of hydrogen (H2) as an internal combustion (IC) engine fuel has been under investigation for several decades. The favorable physical properties of hydrogen make it an excellent alternative fuel for fuel cells as well as IC engines and hence it is widely regarded as the energy carrier of the future. The potential of hydrogen as an IC engine fuel can be optimized by direct injection (DI) as it provides multiple degrees of freedom to influence the in-cylinder combustion processes and consequently the engine efficiency and exhaust emissions. This paper studies a single-hole nozzle and examines the effects of injection strategy on engine efficiency, combustion behavior and NOx emissions. The experiments for this study are done on a 0.5 liter single-cylinder research engine which is specifically designed for combustion studies and equipped with a cylinder head that allows side as well as central injector location.

Blending gasoline with oxygenates like ethanol, MTBE or ETBE has a proven potential to increase the thermodynamic efficiency by enhancing knock resistance. The present research focuses on assessing the capability of a 2- and tert-butanol mixture as a possible alternative to state-of-the-art oxygenates. The butanol mixture was blended into a non-oxygenated reference gasoline with a research octane number (RON) of 97. The butanol blending ratios were 15% and 30% by mass. Both the thermodynamic potential and the impact on emissions were investigated. Tests are performed on a highly boosted single-cylinder gasoline engine with high load capability and a direct injecting fuel system using a solenoid-actuated multi-hole injector. The engine is equipped with both intake and exhaust cam phasers. The engine has been chosen for the fuel investigation, as it represents the SI technology with a strongly increasing market share.

Interest in natural gas as a fuel for light-duty transportation has increased due to its domestic availability and lower cost relative to gasoline. Natural gas, comprised mainly of methane, has a higher knock resistance than gasoline making it advantageous for high load operation. However, the lower flame speeds of natural gas can cause ignitability issues at part-load operation leading to an increase in the initial flame development process. While port-fuel injection of natural gas can lead to a loss in power density due to the displacement of intake air, injecting natural gas directly into the cylinder can reduce such losses. A study was designed and performed to evaluate the potential of natural gas for use as a light-duty fuel. Steady-state baseline tests were performed on a single-cylinder research engine equipped for port-fuel injection of gasoline and natural gas, as well as centrally mounted direct injection of natural gas.

As SI engines strive for higher efficiency they are more likely to encounter knock and fuel anti-knock quality, which is currently measured by RON and MON, becomes more important. However, the RON and MON scales are based on primary reference fuels (PRF) - mixtures of iso-octane and n-heptane - whose autoignition chemistry is significantly different from that of practical fuels. Hence RON or MON alone can truly characterize a gasoline for its knock behavior only at their respective test conditions. The same gasoline will match different PRF fuels at different operating conditions. The true anti-knock quality of a fuel is given by the octane index, OI = RON −KS where S = RON − MON, is the sensitivity. K depends on the pressure and temperature evolution in the unburned gas during the engine cycle and hence is different at different operating conditions and is negative in modern engines.

Homogeneous charge compression ignition (HCCI) offers the potential for significant improvements in efficiency with a substantial reduction in emissions. However, achieving heavy-duty (HD) HCCI engine operation at practical loads and speeds presents numerous technical challenges. Successful expansion of the HCCI operating range to include the full range of load and speed must be accomplished while maintaining proper combustion phasing, control of maximum cylinder pressure and pressure rise rates, and low emissions of NOx and particulate matter (PM). Significant progress in this endeavour has been made through a collaborative research effort between Caterpillar and ExxonMobil. This paper evaluates fuel effects on HCCI engine operating range and emissions. Test fuels were developed in the gasoline and diesel boiling range covering a broad range of ignition quality, fuel chemistry, and volatility.

The capability to detect combustion in a diesel engine has the potential of being an important control feature to meet increasingly stringent emission regulations and for the development of alternative combustion strategies such as HCCI and PCCI. In this work, block mounted accelerometers are investigated as potential feedback sensors for detecting combustion characteristics in a high-speed, high pressure common rail (HPCR), 1.9L diesel engine. Accelerometers are positioned in multiple placements and orientations on the engine, and engine testing is conducted under motored, single and pilot-main injection conditions. Engine tests are then conducted at varying injection timings to observe the resulting time and frequency domain changes of both the pressure and acceleration signals.

The favorable physical properties of hydrogen (H2) make it an excellent alternative fuel for internal combustion (IC) engines and hence it is widely regarded as the energy carrier of the future. Hydrogen direct injection provides multiple degrees of freedom for engine optimization and influencing the in-cylinder combustion processes. This paper compares the results in the mixture formation and combustion behavior of a hydrogen direct-injected single-cylinder research engine using two different injector locations as well as various injector nozzle designs. For this study the research engine was equipped with a specially designed cylinder head that allows accommodating a hydrogen injector in a side location between the intake valves as well as in the center location adjacent to the spark plug.

One-dimensional single-zone and two-zone analyses have been exercised to calculate the mass fraction burned in an engine operating on ethanol/gasoline-blended fuels using the cylinder pressure and volume data. The analyses include heat transfer and crevice volume effects on the calculated mass fraction burned. A comparison between the two methods is performed starting from the derivation of conservation of energy and the method to solve the mass fraction burned rates through the results including detailed explanation of the observed differences and trends. The apparent heat release method is used as a point of reference in the comparison process. Both models are solved using the LU matrix factorization and first-order Euler integration.

The effect of fuel equivalence ratio on the autoignition and combustion processes in a Homogeneous Charge Compression Ignition (HCCI) engine has been studied using a primary reference fuel (PRF60). Experiments have been performed on a single-cylinder engine operated in an alternate-fire mode. The operating conditions of the engine used in this work were an intake air pressure and temperature of 1.5 bar and 75°C respectively, an engine speed of 1200 rpm, compression ratio of 12:1, with varying fuel equivalence ratio (φ). A single zone CHEMKIN model using reduced chemical kinetic model of 560 species and 2818 reactions based on a 5 components gasoline surrogate from Reaction Design's Model Fuels Consortium was used to predict the HCCI engine combustion behavior for different fuel equivalence ratios.

Detailed combustion studies have historically been conducted in simplified reacting systems, such as shock-tubes and rapid compression machines. The reciprocating internal combustion engine presents many challenges when used to isolate the effects of fuel chemistry from thermodynamics. On the other hand, the conditions in such engines are the most representative in terms of pressure and temperature histories. This paper describes the use of a single-cylinder research engine as an advanced reactor to better determine fuel effects experimentally. In particular, a single-cylinder engine was operated in a manner that allowed the effects of changes in charge composition and temperatures to be isolated from changes in equivalence ratio. An example study is presented where the relative effects of low-temperature and high-temperature chemistry, and their effects on combustion phasing, are isolated and examined.