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Fundamental understanding of the sources of fuel-derived Unburned Hydrocarbon (UHC) emissions in heavy duty diesel engines is a key piece of knowledge that impacts engine combustion system development. Current emissions regulations for hydrocarbons can be difficult to meet in-cylinder and thus after treatment technologies such as oxidation catalysts are typically used, which can be costly. In this work, Computational Fluid Dynamics (CFD) simulations are combined with engine experiments in an effort to build an understanding of hydrocarbon sources. In the experiments, the combustion system design was varied through injector style, injector rate shape, combustion chamber geometry, and calibration, to study the impact on UHC emissions from mixing-controlled diesel combustion.

A number of oxidation catalysts have been prepared using different types of advanced support materials such as ceria-zirconia, silica-titania, spinels and perovskites. Active metals such as Pd and Au-Pd were loaded by conventional impregnation techniques and/or deposition-precipitation methods. A liquid hydrocarbon delivery system was designed and implemented for the catalyst test benches in order to simulate the diesel engine exhaust environment. The activity of fresh (no degreening) catalysts was evaluated with traditional CO and light hydrocarbons (C2H4, C3H6) as well as with heavy hydrocarbons such as C10 H22.

Increasing emphasis on natural gas as a clean, economical, and abundant fuel, encourages the search for the optimum approach to management of fuel, air and combustion to achieve the best results in power, fuel economy and low exhaust emissions. Electronic injection of fuel directly into the throttle body, intake ports or directly into the cylinder offers important advantages over carburetion or mixing valves. This is particularly true in the case of installations in which the gas supply is available at several atmospheres pressure above maximum intake manifold pressure. The use of choked-flow pulse- width-modulated electronic injectors offers precision control over the engine operating range with a wide variety of options for both stoichiometric and lean bum applications. A complete system utilizing commercially available components together with the application, calibration and engine mapping techniques is described.

Natural gas is a low cost, abundant and clean burning fuel. Current internal combustion engines can be readily adapted to use natural gas fuel either in conjunction with conventional liquid fuels or as dedicated systems. Use of modern electronic controls allows consideration of new engine management strategies that are not practical or even possible with mechanical systems. The preferred approach is pre-mixed lean burn with cylinder-by-cylinder fuel injection and full time control of optimized air/fuel ratio and ignition.

Dual-fuel pilot ignited natural gas engines have several intrinsic advantages relative to spark ignited; mainly higher thermal efficiency and lower conversion costs. The major drawback is associated with light loads. This paper discusses objectives, approaches, methods and results of the development of strategies which overcome the drawbacks and enhance the advantages. Development of a pilot fuel injection system, having a delivery of only 1 mm3 at a duration of 0.6 ms, was described in a previous paper. This paper concentrates on the results of strategies to reduce unburned methane in the exhaust and to increase the substitution of gas at light loads through skip-fire, by-passing boost air and exhaust gas recirculation techniques. Engine tests proved that with these strategies, diesel fuel replacement of more than 95% over the entire engine operating map, including idle, can be achieved and current and anticipated future emission standards satisfied.

Various gold catalysts were prepared using commercial and in-house fabricated advanced catalyst supports that included mesoporous silica, mesoporous alumina, sol-gel alumina, and transition metal oxides. Gold nanoparticles were loaded on the supports by co-precipitation, deposition-precipitation, ion exchange and surface functionalization techniques. The average gold particle size was ∼20nm or less. The oxidation activity of the prepared catalysts was studied using carbon monoxide and light hydrocarbons (ethylene, propylene and propane) in presence of water and CO2 and the results are presented.

This paper describes two independent studies on γ-alumina as a plasma-activated catalyst. γ-alumina (2.5 - 4.3 wt%) was coated onto the surface of mesoporous silica to determine the importance of aluminum surface coordination on NOx conversion in conjunction with nonthermal plasma. Results indicate that the presence of 5- and 6- fold aluminum coordination sites in γ-alumina could be a significant factor in the NOx reduction process. A second study examined the effect of changing the reducing agent on NOx conversion. Several hydrocarbons were examined including propene, propane, isooctane, methanol, and acetaldehyde. It is demonstrated that methanol was the most effective reducing agent of those tested for a plasma-facilitated reaction over γ-alumina.

Natural gas quality, in terms of the volume fraction of higher hydrocarbons, strongly affects the auto-ignition characteristics of the air-fuel mixture, the engine performance and its controllability. The influence of natural gas composition on engine operation has been investigated both experimentally and through chemical kinetic based cycle simulation. A range of two component gas mixtures has been tested with methane as the base fuel. The equivalence ratio (0.3), the compression ratio (19.8), and the engine speed (1000 rpm) were held constant in order to isolate the impact of fuel autoignition chemistry. For each fuel mixture, the start of combustion was phased near top dead center (TDC) and then the inlet mixture temperature was reduced. These experimental results have been utilized as a source of data for the validation of a chemical kinetic based full-cycle simulation.

This paper discusses the compression ratio influence on maximum load of a Natural Gas HCCI engine. A modified Volvo TD100 truck engine is controlled in a closed-loop fashion by enriching the Natural Gas mixture with Hydrogen. The first section of the paper illustrates and discusses the potential of using hydrogen enrichment of natural gas to control combustion timing. Cylinder pressure is used as the feedback and the 50 percent burn angle is the controlled parameter. Full-cycle simulation is compared to some of the experimental data and then used to enhance some of the experimental observations dealing with ignition timing, thermal boundary conditions, emissions and how they affect engine stability and performance. High load issues common to HCCI are discussed in light of the inherent performance and emissions tradeoff and the disappearance of feasible operating space at high engine loads.

Homogeneous Charge Compression Ignition (HCCI) has been proposed for natural gas engines in heavy duty stationary power generation applications. A number of researchers have demonstrated, through simulation and experiment, the feasibility of obtaining high gross indicated thermal efficiencies and very low NOx emissions at reasonable load levels. With a goal of eventual commercialization of these engines, this paper sets forth some of the primary challenges in obtaining high brake thermal efficiency from production feasible engines. Experimental results, in conjunction with simulation and analysis, are used to compare HCCI operation with traditional lean burn spark ignition performance. Current HCCI technology is characterized by low power density, very dilute mixtures, and low combustion efficiency. The quantitative adverse effect of each of these traits is demonstrated with respect to the brake thermal efficiency that can be expected in real world applications.

Previous research has shown that the homogeneous charge compression ignition (HCCI) combustion concept holds promise for reducing pollutants (i.e. NOx, soot) while maintaining high thermal efficiency. However, it can be difficult to control the operation of the HCCI engines even under steady state running conditions. Power density may also be limited if high inlet air temperatures are used for achieving ignition. A methodology using a small pilot quantity of diesel fuel injected during the compression stroke to improve the power density and operation control is considered in this paper. Multidimensional computations were carried out for an HCCI engine based on a CAT3401 engine. The computations show that the required initial temperature for ignition is reduced by about 70 K for the cases of the diesel pilot charge and a 25∼35% percent increase in power density was found for those cases without adversely impacting the NOx emissions.

A slipstream of exhaust from a Caterpillar 3126B engine was diverted into a plasma-catalytic NOx control system in the space velocity range of 7,000 to 100,000 hr-1. The stream was first fed through a non-thermal plasma that was formed in a coaxial cylinder dielectric barrier discharge reactor. Plasma treated gas was then passed over a catalyst bed held at constant temperature in the range of 573 to 773 K. Catalysts examined consisted of γ-alumina, indium-doped γ-alumina, and silver-doped γ-alumina. Road and rated load conditions resulted in engine out NOx levels of 250 - 600 ppm. The effects of hydrocarbon level, catalyst temperature, and space velocity are discussed where propene and in one case ultra-low sulfur diesel fuel (late cycle injection) were the reducing agents used for NOx reduction. Results showed NOx reduction in the range of 25 - 97% depending on engine operating conditions and management of the catalyst and slipstream conditions.

The effect of piston ring pack crevice flow and lubricant oil vaporization on heavy-duty diesel engine deposits is investigated numerically using a multidimensional CFD code, KIVA3V, coupled with Chemkin II, and computational grids that resolve part of the crevice region appropriately. Improvements have been made to the code to be able to deal with the complex geometry of the ring pack, and sub-models for the crevice flow dynamics, lubricating oil vaporization and combustion, soot formation and deposition were also added to the code. Eight parametric cases were simulated under reacting conditions using detailed chemical kinetics to determine the effects of variations of lube-oil film thickness, distribution of the oil film thickness, number of injection pulses, and the main injection timing on engine soot deposition. The results show that crevice-borne hydrocarbon species play an important role in deposit formation on crevice surfaces.

Direct injection has been considered the most effective approach to overcome the inherent short-circuiting of fuel in a two-stroke engine. A practical application of this technology on an 1100cc personal watercraft (PWC) engine is described. The experimental results show a drastic improvement in the engine emissions and fuel economy while maintaining good output performance and drive-ability of the PWC tested. The all-electronic, direct fuel injection engine has demonstrated a 76.3% reduction in hydrocarbon (HC) emissions and 43.03 g/kW-h HC plus oxides of nitrogen (NOx) emissions. This HC + NOx level meets the emission standards applicable to the 2006 model year set by the Environmental Protection Agency (EPA) for new gasoline spark-ignition marine engines. Finally some considerations on extending the technology to include combustion control in the areas of both air and spark management, are recommended.

Studies of the physical and combustion properties of saturated hydrocarbon gaseous fuels have shown that there is a remarkable correlation between these properties and the hydrogen to carbon ratio of the fuel molecules. If the correlation is limited to the four most prevalent constituents of natural gas fuels, i.e., methane (CH4), ethane (C2 H6), propane (C3H8) and butane (C4H10), it appears that the flow and combustion characteristics of the pure gases and mixtures of these same gases can be predicted from the H/C ratio alone, independent of the various proportions of the gases. It was concluded that if the H/C ratio of a mixture of gases could be determined by means of an on-line dynamic sensor, important engine and fuel management parameters, such as octane no., methane no., density, stoichiometric air/fuel ratio, etc. could be determined and compensated for by an electronic control unit.

The need for a natural gas conversion kit for heavy-duty engines which provides equivalent gasoline performance as well as acceptable exhaust emissions has prompted the use of turbocharged lean-burn engine technology. Turbocharged lean-burn strategy allows operation which meets current heavy-duty emission requirements without the need for a catalytic converter. To insure proper fuel distribution during lean-burn operation, the system includes multi-point sequential fuel injection, fully mapped lambda control, deceleration fuel cut-off, part load cylinder deactivation, and fuel charge stratification. This paper documents the design and development of a General Motors turbocharged, sequential fuel injected, leanburn natural gas engine based on the 4.3L truck engine.

The paper discusses objectives, approaches and results of the development of a pilot fuel injection system (FIS) for a dedicated, compression ignition, high-speed, heavy duty natural gas/diesel engine. The performance of the pilot FIS is crucial for the success of a dual fuel concept. The Servojet electro-hydraulic, accumulator type fuel system was chosen for the pilot fuel injection. An alternative pilot FIS based on the “water hammer” (WH) effect was also considered. The modifications to a stock 17 min injector is described. Three different types of pilot injector nozzle were investigated: standard Valve Covered Orifice (VCO), modified minisac and new designed, unthrottled pintle. Preliminary results from engine tests proved that the optimum pilot fuel quantity is the minimum quantity. Based on that finding, the pilot FIS design was further optimized.

NOx reduction efficiency in simulated lean exhaust conditions has been examined for three proprietary catalyst materials using a non-thermal plasma discharge as a pretreatment stage to the catalyst. Using propene as the reducing agent for selective catalytic reduction, 74% reduction of NOx has been observed in the presence of 20 ppm SO2. For sulfur-free simulated exhaust, 84% NOx reduction has been obtained. Results show that the impact of sulfur on the samples examined can vary widely from virtually no effect (< 5%) to more than 20% loss in activity depending on the catalyst. Any loss due to sulfur poisoning appears to be irreversible according to limited measurements on poisoned catalysts exposed to sulfur-free exhaust streams. Catalysts were tested over a temperature range of 473-773K, with the highest activity observed at 773K. Examination of this large temperature window has shown that the optimum C1:NOx ratio changes with temperature.

The benefits of direct cylinder fuel injection to the fuel economy and exhaust emissions of small spark ignited two-stroke engines is well known. The selection of a commercially viable fuel injection solution continues to receive evaluation and scrutiny by the engine manufacturers. This paper describes the development and demonstration of an EDFI solution which is applicable to low cost and high production volume engines in several industries. The system is based on the “accumulator” fuel injection operating principle, which involves pressurizing fuel within an injection nozzle and subsequently releasing the pressurized fuel into the combustion chamber on command. This concept provides very short injection duration throughout the dynamic operating range of the engine as well as high injection frequency capability.