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Journal Article

Impact of Biodiesel Impurities on the Performance and Durability of DOC, DPF and SCR Technologies

2011-04-12
2011-01-1136
It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil-derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter.
Technical Paper

Advanced Development of the Direct Osmotic Concentration System

2008-06-29
2008-01-2145
Direct osmotic concentration (DOC) is an integrated membrane treatment process designed for the reclamation of spacecraft wastewater. The system includes forward osmosis (FO), membrane evaporation, reverse osmosis (RO) and an aqueous phase catalytic oxidation (APCO) post-treatment unit. This document describes progress in the third year of a four year project to advance hardware maturity of this technology to a level appropriate for human rated testing. The current status of construction and testing of the final deliverable is covered and preliminary calculations of equivalent system mass are funished.
Technical Paper

Membranes on Mars for In-Situ Resource Utilization Processes

2004-07-19
2004-01-2316
The goal of this project is the development and characterization of synthetic membranes for the separation and purification of CO2 from the Martian atmosphere for in-situ resource utilization (ISRU) applications such as in-situ propellant production. Candidate materials should have high selectivity for carbon dioxide over nitrogen and argon, and a glass transition temperature of -40 °C or less to remain in rubbery state at low temperature for high permeance (flux/driving force). Membrane materials we identified include the rubbery polymers poly(dimethyl siloxane) (PDMS) and the copolymer poly(dimethyl, methylphenyl siloxane) (PMPS). Pure and mixed gas permeation experiments with CO2, N2 and Ar were performed with these membrane materials in the temperature range -25 to 21 °C. In experiments with the commercially available PDMS membranes, the pure gas CO2 permeability increases from 1932 Barrers to 2755 Barrers as the temperature decreases from 22 to -30 °C.
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