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Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

2012-06-18
The development of PM and NOx reduction system with the combination of DOC included DPF and SCR catalyst in addition to the AOC sub-assembly for NH3 slip protection is described. DPF regeneration strategy and manual regeneration functionality are introduced with using ITH, HCI device on the EUI based EGR, VGT 12.3L diesel engine at the CVS full dilution tunnel test bench. With this system, PM and NOx emission regulation for JPNL was satisfied and DPF regeneration process under steady state condition and transient condition (JE05 mode) were successfully fulfilled. Manual regeneration process was also confirmed and HCI control strategy was validated against the heat loss during transient regeneration mode. Presenter Seung-il Moon
Journal Article

A Semi-Detailed Chemical Kinetic Mechanism of Acetone-Butanol-Ethanol (ABE) and Diesel Blends for Combustion Simulations

2016-04-05
2016-01-0583
With the development of advanced ABE fermentation technology, the volumetric percentage of acetone, butanol and ethanol in the bio-solvents can be precisely controlled. To seek for an optimized volumetric ratio for ABE-diesel blends, the previous work in our team has experimentally investigated and analyzed the combustion features of ABE-diesel blends with different volumetric ratio (A: B: E: 6:3:1; 3:6:1; 0:10:0, vol. %) in a constant volume chamber. It was found that an increased amount of acetone would lead to a significant advancement of combustion phasing whereas butanol would compensate the advancing effect. Both spray dynamic and chemistry reaction dynamic are of great importance in explaining the unique combustion characteristic of ABE-diesel blend. In this study, a semi-detailed chemical mechanism is constructed and used to model ABE-diesel spray combustion in a constant volume chamber.
Technical Paper

Investigation of Diesel-CNG RCCI Combustion at Multiple Engine Operating Conditions

2020-04-14
2020-01-0801
Past experimental studies conducted by the current authors on a 13 liter 16.7:1 compression ratio heavy-duty diesel engine have shown that diesel-Compressed Natural Gas (CNG) Reactivity Controlled Compression Ignition (RCCI) combustion targeting low NOx emissions becomes progressively difficult to control as the engine load is increased. This is mainly due to difficulty in controlling reactivity levels at higher loads. For the current study, CFD investigations were conducted in CONVERGE using the SAGE combustion solver with the application of the Rahimi mechanism. Studies were conducted at a load of 5 bar BMEP to validate the simulation results against RCCI experimental data. In the low load study, it was found that the Rahimi mechanism was not able to predict the RCCI combustion behavior for diesel injection timings advanced beyond 30 degCA bTDC. This poor prediction was found at multiple engine speed and load points.
Technical Paper

Experimental Investigation of the Compression Ignition Process of High Reactivity Gasoline Fuels and E10 Certification Gasoline using a High-Pressure Direct Injection Gasoline Injector

2020-04-14
2020-01-0323
Gasoline compression ignition (GCI) technology shows the potential to obtain high thermal efficiencies while maintaining low soot and NOx emissions in light-duty engine applications. Recent experimental studies and numerical simulations have indicated that high reactivity gasoline-like fuels can further enable the benefits of GCI combustion. However, there is limited empirical data in the literature studying the gasoline compression ignition process at relevant in-cylinder conditions, which are required for further optimizing combustion system designs. This study investigates the temporal and spatial evolution of the compression ignition process of various high reactivity gasoline fuels with research octane numbers (RON) of 71, 74 and 82, as well as a conventional RON 97 E10 gasoline fuel. A ten-hole prototype gasoline injector specifically designed for GCI applications capable of injection pressures up to 450 bar was used.
Journal Article

Impact of Biodiesel Impurities on the Performance and Durability of DOC, DPF and SCR Technologies

2011-04-12
2011-01-1136
It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil-derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter.
Journal Article

Performance, Efficiency and Emissions Assessment of Natural Gas Direct Injection compared to Gasoline and Natural Gas Port-Fuel Injection in an Automotive Engine

2016-04-05
2016-01-0806
Interest in natural gas as a fuel for light-duty transportation has increased due to its domestic availability and lower cost relative to gasoline. Natural gas, comprised mainly of methane, has a higher knock resistance than gasoline making it advantageous for high load operation. However, the lower flame speeds of natural gas can cause ignitability issues at part-load operation leading to an increase in the initial flame development process. While port-fuel injection of natural gas can lead to a loss in power density due to the displacement of intake air, injecting natural gas directly into the cylinder can reduce such losses. A study was designed and performed to evaluate the potential of natural gas for use as a light-duty fuel. Steady-state baseline tests were performed on a single-cylinder research engine equipped for port-fuel injection of gasoline and natural gas, as well as centrally mounted direct injection of natural gas.
Technical Paper

The Calculation of Mass Fraction Burn of Ethanol-Gasoline Blended Fuels Using Single and Two-Zone Models

2008-04-14
2008-01-0320
One-dimensional single-zone and two-zone analyses have been exercised to calculate the mass fraction burned in an engine operating on ethanol/gasoline-blended fuels using the cylinder pressure and volume data. The analyses include heat transfer and crevice volume effects on the calculated mass fraction burned. A comparison between the two methods is performed starting from the derivation of conservation of energy and the method to solve the mass fraction burned rates through the results including detailed explanation of the observed differences and trends. The apparent heat release method is used as a point of reference in the comparison process. Both models are solved using the LU matrix factorization and first-order Euler integration.
Technical Paper

On-Site DME Generation from Methanol for Pilot Injection in CI Engines

2003-10-27
2003-01-3198
Dual fuel (CI) engines provide an excellent means of maintaining high thermal efficiency and power while reducing emissions, particularly in situations where the primary fuel does not exhibit good auto-ignition characteristics. This is especially true of diesel engines operating on natural gas; usually in stationary applications such as distributed power generation. However, because two fuels are needed, the reliability of the engine is compromised. Therefore, this paper describes the first phase of a project that is to eventually manufacture dimethyl ether (DME) from natural gas and supply it to the pilot injector of a dual fuel engine. A chemical pilot plant has been built and operated, demonstrating an intermediate step in the production of DME from natural gas. DME is manufactured from methanol for pilot injection into a dual fuel engine operating with natural gas as the main fuel.
Technical Paper

Plasma-Facilitated SCR of NOx in Heavy-Duty Diesel Exhaust

2001-09-24
2001-01-3570
This paper describes two independent studies on γ-alumina as a plasma-activated catalyst. γ-alumina (2.5 - 4.3 wt%) was coated onto the surface of mesoporous silica to determine the importance of aluminum surface coordination on NOx conversion in conjunction with nonthermal plasma. Results indicate that the presence of 5- and 6- fold aluminum coordination sites in γ-alumina could be a significant factor in the NOx reduction process. A second study examined the effect of changing the reducing agent on NOx conversion. Several hydrocarbons were examined including propene, propane, isooctane, methanol, and acetaldehyde. It is demonstrated that methanol was the most effective reducing agent of those tested for a plasma-facilitated reaction over γ-alumina.
Technical Paper

Experimental and Simulated Results Detailing the Sensitivity of Natural Gas HCCI Engines to Fuel Composition

2001-09-24
2001-01-3609
Natural gas quality, in terms of the volume fraction of higher hydrocarbons, strongly affects the auto-ignition characteristics of the air-fuel mixture, the engine performance and its controllability. The influence of natural gas composition on engine operation has been investigated both experimentally and through chemical kinetic based cycle simulation. A range of two component gas mixtures has been tested with methane as the base fuel. The equivalence ratio (0.3), the compression ratio (19.8), and the engine speed (1000 rpm) were held constant in order to isolate the impact of fuel autoignition chemistry. For each fuel mixture, the start of combustion was phased near top dead center (TDC) and then the inlet mixture temperature was reduced. These experimental results have been utilized as a source of data for the validation of a chemical kinetic based full-cycle simulation.
Technical Paper

Compression Ratio Influence on Maximum Load of a Natural Gas Fueled HCCI Engine

2002-03-04
2002-01-0111
This paper discusses the compression ratio influence on maximum load of a Natural Gas HCCI engine. A modified Volvo TD100 truck engine is controlled in a closed-loop fashion by enriching the Natural Gas mixture with Hydrogen. The first section of the paper illustrates and discusses the potential of using hydrogen enrichment of natural gas to control combustion timing. Cylinder pressure is used as the feedback and the 50 percent burn angle is the controlled parameter. Full-cycle simulation is compared to some of the experimental data and then used to enhance some of the experimental observations dealing with ignition timing, thermal boundary conditions, emissions and how they affect engine stability and performance. High load issues common to HCCI are discussed in light of the inherent performance and emissions tradeoff and the disappearance of feasible operating space at high engine loads.
Technical Paper

System Efficiency Issues for Natural Gas Fueled HCCI Engines in Heavy-Duty Stationary Applications

2002-03-04
2002-01-0417
Homogeneous Charge Compression Ignition (HCCI) has been proposed for natural gas engines in heavy duty stationary power generation applications. A number of researchers have demonstrated, through simulation and experiment, the feasibility of obtaining high gross indicated thermal efficiencies and very low NOx emissions at reasonable load levels. With a goal of eventual commercialization of these engines, this paper sets forth some of the primary challenges in obtaining high brake thermal efficiency from production feasible engines. Experimental results, in conjunction with simulation and analysis, are used to compare HCCI operation with traditional lean burn spark ignition performance. Current HCCI technology is characterized by low power density, very dilute mixtures, and low combustion efficiency. The quantitative adverse effect of each of these traits is demonstrated with respect to the brake thermal efficiency that can be expected in real world applications.
Technical Paper

Using Pilot Diesel Injection in a Natural Gas Fueled HCCI Engine

2002-10-21
2002-01-2866
Previous research has shown that the homogeneous charge compression ignition (HCCI) combustion concept holds promise for reducing pollutants (i.e. NOx, soot) while maintaining high thermal efficiency. However, it can be difficult to control the operation of the HCCI engines even under steady state running conditions. Power density may also be limited if high inlet air temperatures are used for achieving ignition. A methodology using a small pilot quantity of diesel fuel injected during the compression stroke to improve the power density and operation control is considered in this paper. Multidimensional computations were carried out for an HCCI engine based on a CAT3401 engine. The computations show that the required initial temperature for ignition is reduced by about 70 K for the cases of the diesel pilot charge and a 25∼35% percent increase in power density was found for those cases without adversely impacting the NOx emissions.
Technical Paper

Modeling and Simulation of a Dual Fuel (Diesel/Natural Gas) Engine With Multidimensional CFD

2003-03-03
2003-01-0755
A dual fuel engine simulation model was formulated and the combustion process of a diesel/natural gas dual fuel engine was studied using an updated KIVA-3V Computational Fluid Dynamic (CFD) code. The dual fuel engine ignition and combustion process is complicated since it includes diesel injection, atomization and ignition, superimposed with premixed natural gas combustion. However, understanding of the combustion process is critical for engine performance optimization. Starting from a previously validated Characteristic-Timescale diesel combustion model, a natural gas combustion model was implemented and added to simulate the ignition and combustion process in a dual fuel bus engine. Available engine test data were used for validation of both the diesel-only and the premixed spark-ignition operation regimes. A new formulation of the Characteristic-Timescale combustion model was then introduced to allow smooth transition between the combustion regimes.
Technical Paper

HEUI Injector Modeling and ROI Experiments for High Injection Pressure of Diesel and Dimethyl Ether (DME)

2016-04-05
2016-01-0855
Dimethyl Ether (DME) is considered a clean alternative fuel to diesel due to its soot-free combustion characteristics and its capability to be produced from renewable energy sources rather than fossil fuels such as coal or petroleum. To mitigate the effect of strong wave dynamics on fuel supply lines caused due to the high compressibility of DME and to overcome its low lubricity, a hydraulically actuated electronic unit injector (HEUI) with pressure intensification was used. The study focuses on high pressure operation, up to 2000 bar, significantly higher than pressure ranges reported previously with DME. A one-dimensional HEUI injector model is built in MATLAB/SIMULINK graphical software environment, to predict the rate of injection (ROI) profile critical to spray and combustion characterization.
Technical Paper

Estimating Ozone Potential of Pipe-out Emissions from Euro-3 to Euro-5 Passenger Cars Fueled with Gasoline, Alcohol-Gasoline, Methanol and Compressed Natural Gas

2016-04-05
2016-01-1009
Along with the booming expansion of private car preservation, many Chinese cities are now struggling with hazy weather and ground-level ozone contamination. Although central government has stepped up efforts to purify skies above China, counter-strategies to curb ground-level ozone is comparatively weak. By using maximum incremental reactivity (MIR) method, this paper estimated the ozone forming potential for twenty-five Euro-3 to Euro-5 passenger cars burning conventional gasoline, methanol-gasoline, ethanol-gasoline, neat methanol and compressed natural gas (CNG). The results showed that, for all the fuel tested, VOC/NOx ratios and SR values decreased with the upgrading of emission standard. Except for Euro-3 M100 and Euro-4 M85, SR values for alternative fuel were to different degrees smaller than those for gasoline. When the emission standard was shifted from Euro-4 to Euro-5, OFP values estimated for gasoline vehicle decreased.
Technical Paper

An Optical Investigation of Multiple Diesel Injections in CNG/Diesel Dual-Fuel Combustion in a Light Duty Optical Diesel Engine

2017-03-28
2017-01-0755
Dual-fuel combustion combining a premixed charge of compressed natural gas (CNG) and a pilot injection of diesel fuel offer the potential to reduce diesel fuel consumption and drastically reduce soot emissions. In this study, dual-fuel combustion using methane ignited with a pilot injection of No. 2 diesel fuel, was studied in a single cylinder diesel engine with optical access. Experiments were performed at a CNG substitution rate of 70% CNG (based on energy) over a wide range of equivalence ratios of the premixed charge, as well as different diesel injection strategies (single and double injection). A color high-speed camera was used in order to identify and distinguish between lean-premixed methane combustion and diffusion combustion in dual-fuel combustion. The effect of multiple diesel injections is also investigated optically as a means to enhance flame propagation towards the center of the combustion chamber.
Technical Paper

Effect of Hydrogen Volume Ratio on the Combustion Characteristics of CNG-Diesel Dual-Fuel Engine

2017-10-08
2017-01-2270
CNG-diesel dual fuel combustion mode has been regarded as a practical operation strategy because it not only can remain high thermal efficiency but also make full use of an alternative fuel, natural gas. However, it is suffering from misfire and high HC emissions under cold start and low load conditions. As known, hydrogen has high flammability. Thus, a certain proportion of hydrogen can be added in the natural gas (named HCNG) to improve combustion performance. In this work, the effect of hydrogen volume ratio on combustion characteristics was investigated on an optically accessible single-cylinder CNG-diesel engine using a Phantom v7.3 color camera. HCNG was compressed into the tank under different hydrogen volume ratios varied from 0% to 30%, while the energy substitution rate of` HCNG remained at 70%.
Technical Paper

Effect of Ethanol Addition on Soot Formation of Gasoline in Laminar Diffusion Flames

2017-10-08
2017-01-2396
Soot emission, known as PM (particulate matter), is becoming a big issue for GDI engines as the emission regulations being increasingly stricter. It is found that ethanol, as an oxygenated bio-fuel, can reduce the soot emission when added to gasoline. In order to fully understand the effect of ethanol on soot reducing, the soot characteristics of ethanol/gasoline blends were studied on laminar diffusion flames. In this experiment, the blending ratio of ethanol/gasoline was set as E0/20/40/60/80. Considering the carbon content decreasing due to ethanol addition, carbon mass flow rate was remained constant. The two-dimensional distributions of soot volume fraction were measured quantitatively by using two-color laser induced incandescence technique. The results showed that ethanol is able to decrease the soot significantly, but the effect of ethanol on soot reduction is weakened with the increasing ethanol ratio.
Technical Paper

Numerical Investigation of Spark Ignition Events in Lean and Dilute Methane/Air Mixtures Using a Detailed Energy Deposition Model

2016-04-05
2016-01-0609
It is beneficial but challenging to operate spark-ignition engines under highly lean and dilute conditions. The unstable ignition behavior can result in downgraded combustion performance in engine cylinders. Numerical approach is serving as a promising tool to identify the ignition requirements by providing insight into the complex physical/chemical phenomena. An effort to simulate the early stage of flame kernel initiation in lean and dilute fuel/air mixture has been made and discussed in this paper. The simulations are set to validate against laboratory results of spark ignition behavior in a constant volume combustion vessel. In order to present a practical as well as comprehensive ignition model, the simulations are performed by taking into consideration the discharge circuit analysis, the detailed reaction mechanism, and local heat transfer between the flame kernel and spark plug.
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