Search Results

Quantitative planar laser-induced fluorescence (PLIF) of gaseous acetone as a fuel-tracer has been used in an optically accessible engine, fueled by direct hydrogen injection. The purpose of this article is to assess the accuracy and precision of the measurement and the associated data reduction procedures. A detailed description of the acetone seeding system is given as well. The key features of the experiment are a high-pressure bubbler saturating the hydrogen fuel with acetone vapor, direct injection into an optical engine, excitation of acetone fluorescence with an Nd:YAG laser at 266 nm, and detection of the resulting fluorescence by an unintensified camera. Key steps in the quantification of the single-shot imaging data are an in-situ calibration and a correction for the effect of local temperature on the fluorescence measurement.

Hydrogen is widely considered a promising fuel for future transportation applications for both, internal combustion engines and fuel cells. Due to their advanced stage of development and immediate availability hydrogen combustion engines could act as a bridging technology towards a wide-spread hydrogen infrastructure. Although fuel cell vehicles are expected to surpass hydrogen combustion engine vehicles in terms of efficiency, the difference in efficiency might not be as significant as widely anticipated [1]. Hydrogen combustion engines have been shown capable of achieving efficiencies of up to 45 % [2]. One of the remaining challenges is the reduction of nitric oxide emissions while achieving peak engine efficiencies. This paper summarizes research work performed on a single-cylinder hydrogen direct injection engine at Argonne National Laboratory.

This paper examines the interaction of bulk flow and jet-induced fuel convection in an optically accessible hydrogen-fueled engine with direct injection. Planar laser-induced fluorescence (PLIF) of gaseous acetone as a fuel tracer was performed to obtain quantitative images of the hydrogen mole-fraction in the operating engine. With the engine motored, fuel was injected into inert bulk gas from a centrally located injector during the compression stroke. The injector had a single-hole nozzle with the jet angled at 50 degrees with respect to the vertical injector axis. Two parameters were varied in the experiments, injector orientation and tumble intensity, and for each of these, the injection timing was varied. Image series of the mean fuel mole-fraction between injection and near-TDC crank angles capture the mixture-formation process for each configuration and injection timing.

Negative Valve Overlap (NVO) is a potential control strategy for enabling Low-Temperature Gasoline Combustion (LTGC) at low loads. While the thermal effects of NVO fueling on main combustion are well-understood, the chemical effects of NVO in-cylinder fuel reforming have not been extensively studied. The objective of this work is to examine the effects of fuel molecular structure on NVO fuel reforming using gas sampling and detailed speciation by gas chromatography. Engine gas samples were collected from a single-cylinder research engine at the end of the NVO period using a custom dump-valve apparatus. Six fuel components were studied at two injection timings: (1) iso-octane, (2) n-heptane, (3) ethanol, (4) 1-hexene, (5) cyclohexane, and (6) toluene. All fuel components were studied neat except for toluene - toluene was blended with 18.9% nheptane by liquid volume to increase the fuel reactivity.

In an optically accessible single-cylinder engine fueled with hydrogen, acetone planar laser-induced fluorescence (PLIF) and particle image velocimetry (PIV) are used to evaluate in-cylinder mixture formation. The experiments include measurements for engine operation with hydrogen injection in-cylinder either prior to or after intake valve closure (IVC). Pre-IVC injection is used to produce a near-homogeneous mixture for PLIF calibration experiments and to establish a baseline comparison for post-IVC injection. Calibration experiments and a temperature correction allow conversion of the acetone fluorescence signal to equivalence ratio. For post-IVC injection with start of injection (SOI) coincident with IVC, PLIF results are similar to pre-IVC injection. With retard of SOI from IVC, mixture inhomogeneities increase monotonically, with high hydrogen concentration spatially located near the injector and within a smaller volume.

The oxidation of 1-butene and n-butane in air at elevated pressure was investigated in a high pressure chemical flow reactor. Results are presented for pressures of 3, 6, and 10 atm, temperatures near 900K, and lean equivalence ratio. Gas samples were analyzed using gas chromatography with aldehydes sampled using a dinitrophenylhydrazine/acetonitrile procedure employing gas chromatography/mass spectrometry analysis. Major common products observed include CO, CH2O, C2H4, C3H6, and CO2. Additional major products included 1,3-C4H6 for 1-butene and 1-C4H8 for n-butane. Fuel conversion was increased with increased pressure, temperature, and equivalence ratio with 1-butene more reactive than n-butane. Large levels of lower molecular weight carbonyls resulted from 1-butene whereas significant amounts of conjugate and lower molecular weight alkenes resulted from n-butane. Trends in product distributions with increasing pressure were successfully accounted for by current autoignition theories.

The application of hydrogen (H2) as an internal combustion (IC) engine fuel has been under investigation for several decades. The favorable physical properties of hydrogen make it an excellent alternative fuel for fuel cells as well as IC engines and hence it is widely regarded as the energy carrier of the future. The potential of hydrogen as an IC engine fuel can be optimized by direct injection (DI) as it provides multiple degrees of freedom to influence the in-cylinder combustion processes and consequently the engine efficiency and exhaust emissions. This paper studies a single-hole nozzle and examines the effects of injection strategy on engine efficiency, combustion behavior and NOx emissions. The experiments for this study are done on a 0.5 liter single-cylinder research engine which is specifically designed for combustion studies and equipped with a cylinder head that allows side as well as central injector location.

Mechanisms responsible for enhanced charge reactivity with intake added ozone (O3) were explored in a single-cylinder, optically accessible, research engine configured for low-load advanced compression ignition (ACI) experiments. The influence of O3 concentration (0-40 ppm) on engine performance metrics was evaluated as a function of intake temperature and start of injection for the engine fueled by iso-octane, 1-hexene, or a 5-component gasoline surrogate. For the engine fueled by either the gasoline surrogate or 1-hexene, 25 ppm of added O3 reduced the intake temperature required for stable combustion by 65 and 80°C, respectively. An ultraviolet (UV) light absorption diagnostic was also used to measure crank angle (CA) resolved in-cylinder O3 concentrations for select motored and fired operating conditions. The O3 measurements were compared to results from complementary 0D chemical kinetic simulations that utilized detailed chemistry mechanisms augmented with O3 oxidation chemistry.

Knowledge of the concentration field and flammability envelope from a small-scale hydrogen leak is an issue of importance for the safe use of hydrogen. A combined experimental and modeling program is being carried out by Sandia National Laboratories to characterize and predict the behavior of small-scale hydrogen releases. In contrast to the previous work performed by Sandia on large, momentum-dominated hydrogen leaks, these studies are focusing on small leaks in the Froude number range where both buoyant and inertial forces are important or, in the limit, where buoyancy dominates leak behavior. In the slow leak regime buoyant forces affect the trajectory and rate of air entrainment of the hydrogen jet leak and significant curvature can occur in the jet trajectory. Slow leaks may occur from leaky fittings or o-ring seals on hydrogen vehicles or other hydrogen-based systems where large amounts of pressure drop occur across the leak path.

The favorable physical properties of hydrogen (H2) make it an excellent alternative fuel for internal combustion (IC) engines and hence it is widely regarded as the energy carrier of the future. Hydrogen direct injection provides multiple degrees of freedom for engine optimization and influencing the in-cylinder combustion processes. This paper compares the results in the mixture formation and combustion behavior of a hydrogen direct-injected single-cylinder research engine using two different injector locations as well as various injector nozzle designs. For this study the research engine was equipped with a specially designed cylinder head that allows accommodating a hydrogen injector in a side location between the intake valves as well as in the center location adjacent to the spark plug.

Sandia National Laboratories has been investigating a new, integrated approach to generating electricity with ultra low emissions and very high efficiency for low power (30 kW) applications such as hybrid vehicles and portable generators. Our approach utilizes a free piston in a double-ended cylinder. Combustion occurs alternately at each cylinder end, with intake/exhaust processes accomplished through a two stroke cycle. A linear alternator is mounted in the center section of the cylinder, serving to both generate useful electrical power and to control the compression ratio by varying the rate of electrical generation. Thus, a mechanically simple geometry results in an electronically controlled variable compression ratio configuration. The capability of the homogeneous charge compression ignition combustion process employed in this engine with regards to reduced emissions and improved thermal efficiency has been investigated using a rapid compression expansion machine.

This paper describes the motivation for developing hydrogen-fueled engines for use in hybrid electric vehicles of the future. The ultimate motivation for using hydrogen as an energy carrier is carbon management. However, air quality concerns also provide motivation for developing hydrogen-fueled vehicles. For this reason, we discuss the position of the hydrogen-powered hybrid vehicle within the California Air Resources Board requirement for Zero Emission Vehicles. We describe the expected performance of an electrical generation system powered by a four-stroke, spark-ignited, internal combustion engine for a hydrogen-powered hybrid vehicle. The data show that the engine-out emissions of NOx will allow the vehicle to operate below the Super Ultra-Low Emission Vehicle standard set by the California Air Resources Board. The engine can run on either hydrogen or blends of hydrogen and natural gas. The engine can be optimized for maximum efficiency with low emissions.

This paper discusses the compression ratio influence on maximum load of a Natural Gas HCCI engine. A modified Volvo TD100 truck engine is controlled in a closed-loop fashion by enriching the Natural Gas mixture with Hydrogen. The first section of the paper illustrates and discusses the potential of using hydrogen enrichment of natural gas to control combustion timing. Cylinder pressure is used as the feedback and the 50 percent burn angle is the controlled parameter. Full-cycle simulation is compared to some of the experimental data and then used to enhance some of the experimental observations dealing with ignition timing, thermal boundary conditions, emissions and how they affect engine stability and performance. High load issues common to HCCI are discussed in light of the inherent performance and emissions tradeoff and the disappearance of feasible operating space at high engine loads.

The in-cylinder charge motion during the compression stroke of an optically accessible engine equipped with direct injection of hydrogen fuel is measured via particle image velocimetry (PIV). The evolution of the mean flow field and the tumble ratio are examined with and without injection, each with the unmodified 4-valve pent-roof engine head and with the intake ports modified to yield higher tumble. The measurements in the vertical symmetry plane of the cylinder show that intake modification produces the desired drastic increase in tumble flow, changing the tumble ratio at BDC from 0.22 to 0.70. Either intake-induced flow is completely disrupted by the high-pressure hydrogen injection from an angled, centrally located single-hole nozzle. The injection event leads to sudden reversal of the tumble. Hence the tumble ratio is negative after injection. However, the two intake configurations still differ in tumble ratio by about the same magnitude as before injection.

This paper performs a parametric analysis of the influence of numerical grid resolution and turbulence model on jet penetration and mixture formation in a DI-H2 ICE. The cylinder geometry is typical of passenger-car sized spark-ignited engines, with a centrally located single-hole injector nozzle. The simulation includes the intake and exhaust port geometry, in order to account for the actual flow field within the cylinder when injection of hydrogen starts. A reduced geometry is then used to focus on the mixture formation process. The numerically predicted hydrogen mole-fraction fields are compared to experimental data from quantitative laser-based imaging in a corresponding optically accessible engine. In general, the results show that with proper mesh and turbulence settings, remarkable agreement between numerical and experimental data in terms of fuel jet evolution and mixture formation can be achieved.

With the introduction of more fuel cell electric vehicles (FCEVs) on U.S. roadways, especially in California, the need for available hydrogen refueling stations is growing. While funding from the California Energy Commission is helping to solve this problem, solutions need to be developed and implemented to help reduce the time to commission a hydrogen station. The current practice of hydrogen station acceptance can take months because each vehicle manufacturer conducts their own testing and evaluation. This process is not practical or sufficient to support the timely development of a hydrogen fueling station network. To address this issue, as part of the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) Project Sandia National Laboratories and the National Renewable Energy Laboratory along with a team of stakeholders and contractor Powertech Labs has developed the Hydrogen Station Equipment Performance (HyStEP) Device.

The influences of laboratory-induced hydrogen on the tensile deformation and fracture behavior of selected sheet steels including conventional DQSK and HSLA steels as well as newer DP and TRIP grades were evaluated. The effects of cold work, simulated paint baking, and natural aging were considered. Hydrogen effects were observable by increased flow stress, decreased ductility, altered neck geometry, and altered fracture mechanisms. Differences among the steels and conditions were observed and interpreted on the basis of microstructure, fracture behavior, and theories of hydrogen embrittlement.

Raw oils generated by low-temperature coal pyrolysis were chemically characterized and subjected to tests in three diesel engines of different configuration. The coal liquids were tested as blends with conventional No. 2 diesel fuels, the coal liquids being 20-25% by volume. These tests were performed in support of a broader set of studies on the feasibility of using low-temperature pyrolysis to obtain liquid fuel materials from coal that do not require extensive, costly upgrading. Determination of physical and chemical properties of the pyrolysis liquids indicated a higher hydrogen/carbon ratio and lower aromaticity than typical SRC II and EDS middle distillates. Combustion tests were performed in both direct- and indirect-injection engines at three sites. The results were highly variable, the addition of the oil showing no effect on emissions and performance in some cases, reduced emissions on one engine, and increased emissions in other cases.

This work establishes the relationship between core hardness, case hardness, and case depth on susceptibility to hydrogen embrittlement of case hardened steel fasteners. Such fasteners have a high surface hardness in order to create their own threads in a mating hole, and are commonly used to attach bracketry and sheet metal in automotive applications. While case hardened fasteners have been studied previously, there are currently no processing guidelines supported by quantitative data for fastener standards. Through sustained load embrittlement testing techniques, the susceptibility of case hardened steel tapping screws to internal and environmental hydrogen embrittlement is examined. Further characterization of the fastener samples through microhardness testing, microstructure review, and fracture surface examination allows the investigation of susceptibility thresholds. It is shown that core hardness is the primary consideration for susceptibility.

The application of hydrogen (H2) as an internal combustion (IC) engine fuel has been under investigation for several decades. The favorable physical properties of hydrogen make it an excellent alternative fuel for IC engines and hence it is widely regarded as the energy carrier of the future. Direct injection of hydrogen allows optimizing this potential as it provides multiple degrees of freedom to influence the in-cylinder combustion processes and consequently engine efficiency and exhaust emissions. At certain operating conditions the stratification associated with hydrogen direct injection (DI) leads to an efficiency improvement. However, it also results in higher emissions levels. This paper examines the effects of combining an advanced direct injection strategy with water injection for efficiency benefits and emissions reduction of a hydrogen fuelled DI spark ignition (SI) engine.