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Journal Article

Potential and Challenges for a Water-Gas-Shift Catalyst as a Combustion Promoter on a D-EGR® Engine

2015-04-14
2015-01-0784
In light of the increasingly stringent efficiency and emissions requirements, several new engine technologies are currently under investigation. One of these new concepts is the Dedicated EGR (D-EGR®) engine. The concept utilizes fuel reforming and high levels of recirculated exhaust gas (EGR) to achieve very high levels of thermal efficiency. While the positive impact of reformate, in particular hydrogen, on gasoline engine performance has been widely documented, the on-board reforming process and / or storage of H2 remains challenging. The Water-Gas-Shift (WGS) reaction is well known and has been used successfully for many years in the industry to produce hydrogen from the reactants water vapor and carbon monoxide. For this study, prototype WGS catalysts were installed in the exhaust tract of the dedicated cylinder of a turbocharged 2.0 L in-line four cylinder MPI engine. The potential of increased H2 production in a D-EGR engine was evaluated through the use of these catalysts.
Technical Paper

Comparison of Partial and Total Dilution Systems for the Measurement of Polycyclic Aromatic Hydrocarbons and Hydrocarbon Speciation in Diesel Exhaust

2020-09-15
2020-01-2190
Two methods of sampling exhaust emissions are typically used for characterizing emissions from diesel engines: total dilution which uses a constant volume sampling (CVS) system and partial flow dilution which relies on proportionally diluting a small part from the main exhaust stream. The CVS dilutes the entire exhaust flow to a constant volumetric flowrate which allows for proportional sampling of the exhaust species during transient engine operation. For partial dilution sampling during transient engine operation, obtaining a proportional sample is more rigorous and dilution of the extracted sample must be continuously changed throughout the cycle in order for the extracted sample flowrate to be proportional to the continuously changing exhaust flow. Typically, regulated emissions measured using both methods for an engine platform have shown good correlation. The focus for this work was on the experimental investigation of the two methods for the measurement of unregulated species.
Technical Paper

Machinability of As-Compacted P/M Parts: Effect of Material Chemistry

1998-02-23
980635
Since the advent of P/M technology as a near net shape production process, millions of mechanical components of various shapes and sizes have been produced. Although P/M continues to be one of the fast growing shaping processes, it suffers from the inability to produce intricate geometry's such as internal tapers, threads or recesses perpendicular to pressing direction. In such cases application of machining as a secondary forming operation becomes the preferred alternative. However, machining of P/M parts due to their inherent porosity is known to decrease tool life and increase tool chatter and vibration. Consequently, several attempts have been made to improve the machinability of P/M materials by either addition of machinability enhancing elements such as sulfur, calcium, tellurium, selenium, etc., or by resin impregnation of P/M parts.
Technical Paper

Aging of Zeolite Based Automotive Hydrocarbon Traps

2007-04-16
2007-01-1058
This paper analyzes the aging of zeolite based hydrocarbon traps to guide development of diagnostic algorithms. Previous research has shown the water adsorption ability of zeolite ages along with the hydrocarbon adsorption ability, and this leads to a possible diagnostic algorithm: the water concentration in the exhaust can be measured and related to aging. In the present research, engine experiments demonstrate that temperature measurements are also related to aging. To examine the relationship between temperature-based and moisture-based diagnostic algorithms, a transient, nonlinear heat and mass transfer model of the exhaust during cold-start is developed. Despite some idealizations, the model replicates the qualitative behavior of the exhaust system. A series of parametric studies reveals the sensitivity of the system response to aging and various noise factors.
Technical Paper

Effect of Diesel and Water Co-injection with Real-Time Control on Diesel Engine Performance and Emissions

2008-04-14
2008-01-1190
A system for injection of diesel fuel and water with real-time control, or real-time water injection (RTWI), was developed and applied to a heavy-duty diesel engine. The RTWI system featured electronic unit pumps that delivered metered volumes of water to electronic unit injectors (EUI) modified to incorporate the water addition passages. The water and diesel mixed in the injector tip such that the initial portion of the injection contained mostly diesel fuel, while the balance of the injection was a water and diesel mixture. With this hardware, real-time cycle-by-cycle control of water mass was used to mitigate soot formation during diesel combustion. Using RTWI alone, NOx emissions were reduced by 42%. Using high-pressure-loop exhaust gas recirculation (EGR) and conventional diesel combustion with RTWI, the NOx was reduced by 82%.
Technical Paper

Effects of Water on Distillate Fuel Lubricity

1998-10-19
982568
The continuing trend toward “cleaner” distillate fuels has prompted concerns about the lubricity characteristics of current and future distillates. Since many U.S. Navy ships utilize seawater-compensated fuel tanks to maintain the ship's trim, the Navy performed a detailed study in order to better understand the relationship between fuel water content and lubricity characteristics. The lubricity test methods, modified for this study, were ASTM D 6078 (SLBOCLE), D 6079 (HFRR), and D 5001 (BOCLE). The results indicated that, with few exceptions, there was generally no evidence of a correlation between the water content of the fuels and the corresponding lubricity measurements as determined by the laboratory tests.
Technical Paper

The Port Fuel Injector Deposit Test - A Statistical Review

1998-10-19
982713
The Port Fuel Injector (PFI) Deposit Test is a performance-based test procedure developed by the Coordinating Research Council and adopted by state and federal regulatory agencies for fuel qualification in the United States. To date, Southwest Research Institute (SwRI) has performed over 375 PFI tests between 1991 and 1998 for various clients. This paper details the analyses of these tests. Of the 375 tests, 199 were performed as keep-clean tests and 176 were performed as clean-up tests. The following areas of interest are discussed in this paper: Keep-clean versus clean-up test procedures Linearity of deposit formation Injector position effects as related to fouling Dirtyup / cleanup phenomena Seasonal effects This paper draws the conclusion that it is easier to keep new injectors from forming deposits than it is to clean up previously formed deposits. It was found that injector deposit formation is generally non-linear.
Technical Paper

Calibrating and Protecting Microphones to Allow Acoustic Measurements in Hazardous Environments

2009-05-19
2009-01-2163
Performing acoustic measurements on or near engines, transmissions, as well as in other circumstances where the environment is hazardous and harsh for microphones requires special precautions. Fluids inevitably leak, and the possibility of transducer damage can be very high without proper protection. Properly protecting microphones during testing allows for consistent data quality in these hazardous and difficult environments. While this paper will present the use of a 5 mil Nitrile cover which protects against many fluids within the scope of automotive testing, including water, hydrocarbons, and alcohols, as well as having good heat resistance and high strength, the concepts developed are applicable to other types of microphone protective mechanisms. Acoustic sensitivity was measured and used to calculate the change of the microphone's response after the treatment is applied, as well as after being exposed to various contaminants.
Technical Paper

Preparation and Characterization of Nanophase Gold Catalysts for Emissions Control

2008-10-07
2008-01-2639
Various gold catalysts were prepared using commercial and in-house fabricated advanced catalyst supports that included mesoporous silica, mesoporous alumina, sol-gel alumina, and transition metal oxides. Gold nanoparticles were loaded on the supports by co-precipitation, deposition-precipitation, ion exchange and surface functionalization techniques. The average gold particle size was ∼20nm or less. The oxidation activity of the prepared catalysts was studied using carbon monoxide and light hydrocarbons (ethylene, propylene and propane) in presence of water and CO2 and the results are presented.
Technical Paper

An Investigation of Sample Bag Hydrocarbon Emissions and Carbon Dioxide Permeation Properties

2004-03-08
2004-01-0593
The equipment for collecting dilute exhaust samples involves the use of bag materials (i.e., Tedlar®) that emit hydrocarbons that contaminate samples. This study identifies a list of materials and treatments to produce bags that reduce contamination. Based on the average emission rates, baked Tedlar®, Capran® treated with alumina deposition, supercritical CO2 extracted Kynar® and supercritical CO2 extracted Teflon NXT are capable of achieving the target hydrocarbon emission rate of less than 15 ppbC per 30 minutes. CO2 permeation tests were also performed. Tedlar, Capran, Kynar and Teflon NXT showed comparable average permeation rates. Based on the criteria of HC emission performance, changes in measured CO2 concentration, ease of sealing, and ease of surface treatment, none of the four materials could be distinguished from one another.
Technical Paper

CO2 Pump for the Space Station Advanced Atmosphere Revitalization Subsystem

2001-07-09
2001-01-2418
The current operation of the International Space Station (ISS) calls for the oxygen used by the occupants to be vented overboard in the form of CO2, after the CO2 is scrubbed from the cabin air. Likewise, H2 produced via electrolysis in the oxygen generator is also vented. NASA is investigating the use of the Sabatier process to combine these two product streams to form water and methane. The water is then used in the oxygen generator, thereby conserving this valuable resource. One of the technical challenges to developing the Sabatier reactor is transferring CO2 from the Carbon Dioxide Removal Assembly (CDRA) to the Sabatier reactor at the required rate, even though the CDRA and the Sabatier reactor operate on different schedules. One possible way to transfer and store CO2 is to use a mechanical compressor and a storage tank.
Technical Paper

Induction Hardening Simulation of Steel and Cast Iron Components

2002-03-19
2002-01-1557
The induction hardening process involves a complex interaction of electromagnetic heating, rapid cooling, metallurgical phase transformations, and mechanical behavior. Many factors including induction coil design, power, frequency, scanning velocity, workpiece geometry, material chemistry, and quench severity determine a process outcome. This paper demonstrates an effective application of a numerical analysis tool for understanding of induction hardening. First, an overview of the Caterpillar induction simulation tool is briefly discussed. Then, several important features of the model development are examined. Finally, two examples illustrating the use of the computer simulation tool for solving induction-hardening problems related to cracking and distortion are presented. These examples demonstrate the tool's ability to simulate changes in process parameters and latitude of modeling steel or cast iron.
Technical Paper

Effects of Water-Fuel Emulsions on Spray and Combustion Processes in a Heavy-Duty DI Diesel Engine

2002-10-21
2002-01-2892
Significant reductions of particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines have been realized through fueling with water-fuel emulsions. However, the physical and chemical in-cylinder mechanisms that affect these pollutant reductions are not well understood. To address this issue, laser-based and chemiluminescence imaging experiments were performed in an optically-accessible, heavy-duty diesel engine using both a standard diesel fuel (D2) and an emulsion of 20% water, by mass (W20). A laser-based Mie-scatter diagnostic was used to measure the liquid-phase fuel penetration and showed 40-70% greater maximum liquid lengths with W20 at the operating conditions tested. At some conditions with low charge temperature or density, the liquid phase fuel may impinge directly on in-cylinder surfaces, leading to increased PM, HC, and CO emissions because of poor mixing.
Technical Paper

Caterpillar’s Autonomous Journey - The Argument for Autonomy

2016-09-27
2016-01-8005
Today’s business climate and economy demand new, innovative strategies from the initial kickoff of research and development - to the mining of ore from the earth - to the final inspection of a finished product in a mid-western factory. From startup companies with two employees to the largest companies, the world faces new and challenging requirements every day. The demands from companies, customers, executives, and shareholders continue to drive for higher outputs with more efficient use of personnel and investments. Fortunately, the rate of technology continues to exponentially accelerate, which allows those at the cutting edge of technology to capitalize. Caterpillar has been a pioneer in advanced technology since its inception and has been developing the foundation for autonomy over the past four decades.
Technical Paper

Splashing Criterion and Topological Features of a Single Droplet Impinging on the Flat Plate

2018-04-03
2018-01-0289
This paper aims to provide the experimental and numerical investigation of a single fuel droplet impingement on the different wall conditions to understand the detailed impinging dynamic process. The experimental work was carried out at the room temperature and pressure except for the variation of the impinged wall temperature. A high-speed camera was employed to capture the silhouette of the droplet impinging on wall process against a collimated light. Water, diesel, n-dodecane, and n-heptane were considered as four different droplets and injected from a precision syringe pump with the volume flow rate of 0.2 mL/min at various impact Weber numbers. The impingement outcomes after droplet impacting on the wall include stick, spread, rebound and splash, which depend on the controlling parameters of Weber number, Reynolds number, liquid and surface properties, etc.
Technical Paper

Blend Ratio Optimization of Fuels Containing Gasoline Blendstock, Ethanol, and Higher Alcohols (C3-C6): Part I - Methodology and Scenario Definition

2013-04-08
2013-01-1144
The U.S. Renewable Fuel Standard (RFS2) requires an increase in the use of advanced biofuels up to 36 billion gallons by 2022. Longer chain alcohols, in addition to cellulosic ethanol and synthetic biofuels, could be used to meet this demand while adhering to the RFS2 corn-based ethanol limitation. Higher carbon number alcohols can be utilized to improve the energy content, knock resistance, and/or petroleum displacement of gasoline-alcohol blends compared to traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part I of this paper focuses on the development of scenarios by which to compare higher alcohol fuel blends to traditional ethanol blends. It also details the implementation of fuel property prediction methods adapted from literature. Possible combinations of eight alcohols mixed with a gasoline blendstock were calculated and the properties of the theoretical fuel blends were predicted.
Technical Paper

A New Multi-point Active Drawbead Forming Die: Model Development for Process Optimization

1998-02-01
980076
A new press/die system for restraining force control has been developed in order to facilitate an increased level of process control in sheet metal forming. The press features a built-in system for controlling drawbead penetration in real time. The die has local force transducers built into the draw radius of the lower tooling. These sensors are designed to give process information useful for the drawbead control. This paper focuses on developing models of the drawbead actuators and the die shoulder sensors. The actuator model is useful for developing optimal control methods. The sensor characterization is necessary in order to develop a relationship between the raw sensor outputs and a definitive process characteristic such as drawbead restraining force (DBRF). Closed loop control of local specific punch force is demonstrated using the die shoulder sensor and a PID controller developed off-line with the actuator model.
Technical Paper

Life Assessment of PM, Gaseous Emissions, and Oil Usage in Modern Marine Outboard Engines

2004-09-27
2004-32-0092
Recently, outboard engine technology has advanced significantly. With these new technologies comes a substantial improvement in emissions compared to traditional carbureted two-stroke engines. Some two-stroke gasoline direct injection (GDI) marine outboard engines are now capable of meeting California Air Resources Board 2008 Ultra-Low emissions standards. With improvement of gaseous emissions, studies are now being conducted to assess particulate matter (PM) emissions from all new technology marine outboard engines which include both four-stroke and two-stroke designs. Methods are currently being developed to determine the best way to measure PM from outboard engines. This study assesses gaseous and PM emissions, mutagenic activity of PM and oil consumption of two different technologies over the useful life of the engines.
Technical Paper

Reduced Energy and Power Consumption for Electrically Heated Extruded Metal Converters

1993-03-01
930383
Improved designs of extruded metal electrically heated catalysts (EHC) in combination with a traditional converter achieved the California ultra-low emission vehicle (ULEV) standard utilizing 50% less electrical energy than previous prototypes. This energy reduction is largely achieved by reducing the mass of the EHC. In addition to energy reduction, the battery voltage is reduced from 24 volts to 12 volts, and the power is reduced from 12 kilowatts to 3 kilowatts. Also discussed is the impact EHC mass, EHC catalytic activity, and no EHC preheating has on non-methane hydrocarbon emissions, energy requirements, and power requirements.
Technical Paper

Assessment of Technology Readiness Level of a Carbon Dioxide Reduction Assembly (CRA) for Use on International Space Station

2004-07-19
2004-01-2446
When technologies are traded for incorporation into vehicle systems to support a specific mission scenario, they are often assessed in terms of “Technology Readiness Level” (TRL). TRL is based on three major categories of Core Technology Components, Ancillary Hardware and System Maturity, and Control and Control Integration. This paper describes the Technology Readiness Level assessment of the Carbon Dioxide Reduction Assembly (CRA) for use on the International Space Station. A team comprising of the NASA Johnson Space Center, Marshall Space Flight Center, Southwest Research Institute and Hamilton Sundstrand Space Systems International have been working on various aspects of the CRA to bring its TRL from 4/5 up to 6. This paper describes the work currently being done in the three major categories. Specific details are given on technology development of the Core Technology Components including the reactor, phase separator and CO2 compressor.
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