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Work was performed to determine the feasibility of operating heavy-duty natural gas engines over a wide range of fuel compositions by evaluating engine performance and emission levels. Heavy-duty compressed natural gas engines from various engine manufacturers, spanning a range of model years and technologies, were evaluated using a diversity of fuel blends. Performance and regulated emission levels from these engines were evaluated using natural gas fuel blends with varying methane number (MN) and Wobbe Index in a dynamometer test cell. Eight natural gas blends were tested with each engine, and ranged from MN 75 to MN 100. Test engines included a 2007 model year Cummins ISL G, a 2006 model year Cummins C Gas Plus, a 2005 model year John Deere 6081H, a 1998 model year Cummins C Gas, and a 1999 model year Detroit Diesel Series 50G TK. All engines used lean-burn technology, except for the ISL G, which was a stoichiometric engine.

The addition of exhaust gas recirculation (EGR) has demonstrated the potential to significantly improve engine efficiency by allowing high CR operation due to a reduction in knock tendency, heat transfer, and pumping losses. In addition, EGR also reduces the engine-out emission of nitrogen oxides, particulates, and carbon monoxide while further improving efficiency at stoichiometric air/fuel ratios. However, improvements in efficiency through enhanced combustion phasing at high compression ratios can result in a significant increase in cylinder pressure. As cylinder pressure and temperature are both important parameters for estimating the durability requirements of the engine - in effect specifying the material and engineering required for the head and block - the impact of EGR on surface temperatures, when combined with the cylinder pressure data, will provide an important understanding of the design requirements for future cylinder heads.

In light of the increasingly stringent efficiency and emissions requirements, several new engine technologies are currently under investigation. One of these new concepts is the Dedicated EGR (D-EGR®) engine. The concept utilizes fuel reforming and high levels of recirculated exhaust gas (EGR) to achieve very high levels of thermal efficiency. While the positive impact of reformate, in particular hydrogen, on gasoline engine performance has been widely documented, the on-board reforming process and / or storage of H2 remains challenging. The Water-Gas-Shift (WGS) reaction is well known and has been used successfully for many years in the industry to produce hydrogen from the reactants water vapor and carbon monoxide. For this study, prototype WGS catalysts were installed in the exhaust tract of the dedicated cylinder of a turbocharged 2.0 L in-line four cylinder MPI engine. The potential of increased H2 production in a D-EGR engine was evaluated through the use of these catalysts.

Past experimental studies conducted by the current authors on a 13 liter 16.7:1 compression ratio heavy-duty diesel engine have shown that diesel-Compressed Natural Gas (CNG) Reactivity Controlled Compression Ignition (RCCI) combustion targeting low NOx emissions becomes progressively difficult to control as the engine load is increased. This is mainly due to difficulty in controlling reactivity levels at higher loads. For the current study, CFD investigations were conducted in CONVERGE using the SAGE combustion solver with the application of the Rahimi mechanism. Studies were conducted at a load of 5 bar BMEP to validate the simulation results against RCCI experimental data. In the low load study, it was found that the Rahimi mechanism was not able to predict the RCCI combustion behavior for diesel injection timings advanced beyond 30 degCA bTDC. This poor prediction was found at multiple engine speed and load points.

An investigation was performed to identify the benefits of cooled exhaust gas recirculation (EGR) when applied to a potential ethanol flexible fuelled vehicle (eFFV) engine. The fuels investigated in this study represented the range a flex-fuel engine may be exposed to in the United States; from 85% ethanol/gasoline blend (E85) to regular gasoline. The test engine was a 2.0-L in-line 4 cylinder that was turbocharged and port fuel injected (PFI). Ethanol blended fuels, including E85, have a higher octane rating and produce lower exhaust temperatures compared to gasoline. EGR has also been shown to decrease engine knock tendency and decrease exhaust temperatures. A natural progression was to take advantage of the superior combustion characteristics of E85 (i.e. increase compression ratio), and then employ EGR to maintain performance with gasoline. When EGR alone could not provide the necessary knock margin, hydrogen (H2) was added to simulate an onboard fuel reformer.

On-road comparisons were made between a federal reference method mobile emissions laboratory (MEL) and a portable emissions measurement system (PEMS) to support validation of the engine “Not To Exceed” (NTE) emissions design and to evaluate the accuracy of PEMS. Three different brake specific emissions calculation equations (methods) were used as part of this research, with method one directly using engine speed and torque, and methods two and three including ECM fuel consumption and carbon balance fuel consumption. The brake specific NOx emissions for the particular PEMS unit utilized in this program were consistently higher than those for the MEL. The brake specific (bs) NOx NTE deltas were +0.63±0.31 g/kW-h (0.47±0.23 g/hp-h), +0.55±0.17 g/kW-h (0.41±0.13 g/hp-h), and +0.54±0.17g/kW-h (0.40±0.13g/hp-h) for methods one, two, and three respectively.

Impending emissions regulations for diesel engines, specifically exhaust particulate emissions have caused engine manufacturers to once again examine the potential of alternative fuels. Much interest has centered around compressed natural gas (CNG) due to its potential for low particulate and NOx emissions. Natural gas engine development projects have tended toward the use of current gasoline engine technology (stoichiometric mixtures, closed-loop fuel control, exhaust catalysts) or have applied the results of previous research in lean-burn gasoline engines (high-turbulence combustion chambers). These technologies may be inappropriate for foreseeable emissions targets in heavy-duty natural gas engines.

Interest in natural gas as a fuel for light-duty transportation has increased due to its domestic availability and lower cost relative to gasoline. Natural gas, comprised mainly of methane, has a higher knock resistance than gasoline making it advantageous for high load operation. However, the lower flame speeds of natural gas can cause ignitability issues at part-load operation leading to an increase in the initial flame development process. While port-fuel injection of natural gas can lead to a loss in power density due to the displacement of intake air, injecting natural gas directly into the cylinder can reduce such losses. A study was designed and performed to evaluate the potential of natural gas for use as a light-duty fuel. Steady-state baseline tests were performed on a single-cylinder research engine equipped for port-fuel injection of gasoline and natural gas, as well as centrally mounted direct injection of natural gas.

An experimental program to develop a practical natural gas-fueled locomotive engine was conducted. Six natural gas-fueled combustion systems for an EMD 710-type locomotive engine were developed and tested. The six systems were evaluated in terms of NOx and CO emissions, thermal efficiency, knock tolerance, and other practical considerations. Each combustion system was tested at Notch 5, 100-percent load, Notch 8, 80-percent load, and Notch 8, 100-percent load conditions. In general, all of the technologies produced significantly lower NOx emissions than the baseline diesel engine. Based on the results of the tests and other analyses, a late cycle, high-injection pressure (LaCHIP) combustion system, using a diesel pilot-ignited, late cycle injection of natural gas with a Diesel-type combustion process, was determined to provide the most practical combustion system for a natural gas-fueled, EMD 710-powered locomotive.

The goal of this project was to demonstrate a low emissions, high efficiency heavy-duty on-highway natural gas engine. The emissions targets for this project are to demonstrate US 2010 emissions standards on the 13-mode steady state test. To meet this goal, a chemically correct combustion (stoichiometric) natural gas engine with exhaust gas recirculation (EGR) and a three way catalyst (TWC) was developed. In addition, a Sturman Industries, Inc. camless Hydraulic Valve Actuation (HVA) system was used to improve efficiency. A Volvo 11 liter diesel engine was converted to operate as a stoichiometric natural gas engine. Operating a natural gas engine with stoichiometric combustion allows for the effective use of a TWC, which can simultaneously oxidize hydrocarbons and carbon monoxide and reduce NOx. High conversion efficiencies are possible through proper control of air-fuel ratio.

A zero-dimensional cycle simulation model coupled with a chemical equilibrium model and a two-zone combustion model has been extended to predict nitric oxide formation and emissions from spark-ignited, lean-burn natural gas engines. It is demonstrated that using the extended Zeldovich mechanism alone, the NOx emissions from an 8.1-liter, 6-cylinder, natural gas engine were significantly under predicted. However, by combining the predicted NOx formation from both the extended Zeldovich thermal NO and the Fenimore prompt NO mechanisms, the NOx emissions were predicted with fair accuracy over a range of engine powers and lean-burn equivalence ratios. The effect of injection timing on NOx emissions was under predicted. Humidity effects on NOx formation were slightly under predicted in another engine, a 6.8-liter, 6-cylinder, natural gas engine. Engine power was well predicted in both engines, which is a prerequisite to accurate NOx predictions.

A vehicle's gasoline fuel tank was removed and replaced with a 5,000-psig, Type-III, aluminum-lined hydrogen cylinder. High-pressure cylinders are typically installed with a thermally-activated pressure relief device (PRD) designed to safely vent the contents of the cylinder in the event of accidental exposure to fire. The objective of this research was to assess the results of a catastrophic failure in the event that a PRD were ineffective. Therefore, no PRD was installed on the vehicle to ensure cylinder failure would occur. The cylinder was pressurized and exposed to a propane bonfire in order to simulate the occurrence of a gasoline pool fire on the underside of the vehicle. Measurements included temperature and carbon monoxide concentration inside the passenger compartment of the vehicle to evaluate tenability. Measurements on the exterior of the vehicle included blast wave pressures. Documentation included standard, infrared, and high-speed video.

Small (up to 1% by volume) amounts of hydrogen (H2) were added to the intake charge of a single-cylinder, stoichiometric spark ignited engine to determine the effect of H2 addition on EGR tolerance. Two types of tests were performed at 1500 rpm, two loads (3.1 bar and 5.5 bar IMEP), two compression ratios (11:1 and 14:1) and with two fuels (gasoline and natural gas). The first test involved holding EGR level constant and increasing the H2 concentration. The EGR level of the engine was increased until the CoV of IMEP was > 5% and then small amounts of hydrogen were added until the total was 1% by volume. The effect of increasing the amount of H2 on engine stability was measured along with combustion parameters and engine emissions. The results showed that only a very small amount of H2 was necessary to stabilize the engine. At amounts past that level, increasing the level of H2 had no or only a very small effect.

An electromagnetic valve actuation (EVA) system was developed and applied to a Kohler Command Series engine. Engine development and testing was conducted for the purpose of evaluating the performance of the EVA-equipped engine, running on natural gas, in an engine-test laboratory environment. As part of this effort, a personal computer-based engine control system, which managed the fueling, ignition, throttling, and intake/exhaust valve control functions, was developed. The evaluation included an investigation into increasing engine power output and full load efficiency, as well as increased part load efficiency. Techniques including optimized valve events as a function of operating condition, and throttleless operation using early and late intake valve closing are presented. Engine simulation results are compared with actual engine data and presented in this paper.

Various gold catalysts were prepared using commercial and in-house fabricated advanced catalyst supports that included mesoporous silica, mesoporous alumina, sol-gel alumina, and transition metal oxides. Gold nanoparticles were loaded on the supports by co-precipitation, deposition-precipitation, ion exchange and surface functionalization techniques. The average gold particle size was ∼20nm or less. The oxidation activity of the prepared catalysts was studied using carbon monoxide and light hydrocarbons (ethylene, propylene and propane) in presence of water and CO2 and the results are presented.

Dual fuel (CI) engines provide an excellent means of maintaining high thermal efficiency and power while reducing emissions, particularly in situations where the primary fuel does not exhibit good auto-ignition characteristics. This is especially true of diesel engines operating on natural gas; usually in stationary applications such as distributed power generation. However, because two fuels are needed, the reliability of the engine is compromised. Therefore, this paper describes the first phase of a project that is to eventually manufacture dimethyl ether (DME) from natural gas and supply it to the pilot injector of a dual fuel engine. A chemical pilot plant has been built and operated, demonstrating an intermediate step in the production of DME from natural gas. DME is manufactured from methanol for pilot injection into a dual fuel engine operating with natural gas as the main fuel.

The effect of low temperature intake air on the knock limited brake mean effective pressure (BMEP) in a spark ignited natural gas engine is described in this paper. This work was conducted to demonstrate the feasibility of using the vaporization of liquefied natural gas (LNG) to reduce the intake air temperature of engines operating on LNG fuel. The effect on steady-state emissions and transient response are also reported. Three different intake air temperatures were tested and evaluated as to their impact upon engine performance and gaseous emissions output. The results of these tests are as follows. The reduced intake air temperature allowed for a 30.7% (501 kPa) increase in the knock-limited BMEP (comparing the 10°C (50°F) intake air results with the 54.4°C (130°F) results). Exhaust emissions were recorded at constant BMEP for varying intake air temperatures.

Development of a natural gas-fueled engine capable of throttleless operation is discussed in this paper. This development was conducted under a program funded by the National Renewable Energy Laboratory to investigate methods to increase the efficiency of natural gas engines. In-cylinder fuel-air charge stratification was pursued as the mechanism for throttleless operation. Various methods of charge stratification were investigated, including direct injection, stratified charge (DISC) and a fuel injected prechamber (FIPC). The FIPC combustion system was found to be a more practical solution to the problem of charge stratification. Performance and emissions results from this engine configuration are presented and comparisons are made between current natural gas engines and the prototype FIPC engine.

This study compared four different candidate fuels which were prepared by blending different components with a typical No. 2 diesel. Two fuels were blended with a synthetic diesel prepared from natural gas condensate, and all candidate fuels were splash blended with a proprietary additive package from International Fuel Technology Inc. (IFT). These fuels were then compared to the No. 2 diesel and to a California Air Resources Board (CARB) equivalent diesel fuel. The comparisons included fuel properties such as sulfur content, aromatics, cetane, lubricity, distillation; emissions; and fuel consumption. Emission testing was conducted on a 1991 Detroit Diesel Series 60. The Environmental Protection Agency (EPA) transient cycle was utilized for emissions, fuel characterization was performed according to ASTM standards, and fuel consumption was calculated by the carbon balance method.

Natural gas quality, in terms of the volume fraction of higher hydrocarbons, strongly affects the auto-ignition characteristics of the air-fuel mixture, the engine performance and its controllability. The influence of natural gas composition on engine operation has been investigated both experimentally and through chemical kinetic based cycle simulation. A range of two component gas mixtures has been tested with methane as the base fuel. The equivalence ratio (0.3), the compression ratio (19.8), and the engine speed (1000 rpm) were held constant in order to isolate the impact of fuel autoignition chemistry. For each fuel mixture, the start of combustion was phased near top dead center (TDC) and then the inlet mixture temperature was reduced. These experimental results have been utilized as a source of data for the validation of a chemical kinetic based full-cycle simulation.