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Brief Investigation of SCR High Temperature N2O Production

2012-06-18
Nitrous Oxide (N2O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 [1,2] (298-310 times more potent than carbon dioxide (CO2)). As a result, any aftertreatment system that generates N2O must be well understood to be used effectively. Under low temperature conditions, N2O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N2O formed by the thermal decomposition of ammonium nitrate [3]. Ammonium nitrate and N2O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO2)[4]. This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO2 ratio above 1. However, N2O has also been observed at relatively high temperatures, in the region of 500°C.
Journal Article

Diesel Cold-Start Emission Control Research for 2015-2025 LEV III Emissions - Part 2

2014-04-01
2014-01-1552
The diesel engine can be an effective solution to meet future greenhouse gas and fuel economy standards, especially for larger segment vehicles. However, a key challenge facing the diesel is the upcoming LEV III and Tier 3 emission standards which will require significant reductions in hydrocarbon (HC) and oxides of nitrogen (NOx) emissions. The challenge stems from the fact that diesel exhaust temperatures are much lower than gasoline engines, so the time required to achieve effective emissions control after a cold-start with typical aftertreatment devices is considerably longer. To address this challenge, a novel diesel cold-start emission control strategy was investigated on a 2L class diesel engine. This strategy combines several technologies to reduce tailpipe HC and NOx emissions before the start of the second hill of the FTP75. The technologies include both engine tuning and aftertreatment changes.
Journal Article

Analysis Process for Truck Fuel Efficiency Study

2015-09-29
2015-01-2778
Medium- and Heavy Duty Truck fuel consumption and the resulting greenhouse gas (GHG) emissions are significant contributors to overall U.S. GHG emissions. Forecasts of medium- and heavy-duty vehicle activity and fuel use predict increased use of freight transport will result in greatly increased GHG emissions in the coming decades. As a result, the National Highway Traffic Administration (NHTSA) and the United States Environmental Protection Agency (EPA) finalized a regulation requiring reductions in medium and heavy truck fuel consumption and GHGs beginning in 2014. The agencies are now proposing new regulations that will extend into the next decade, requiring additional fuel consumption and GHG emissions reductions. To support the development of future regulations, a research project was sponsored by NHTSA to look at technologies that could be used for compliance with future regulations.
Journal Article

An Efficient, Durable Vocational Truck Gasoline Engine

2016-04-05
2016-01-0660
This paper describes the potential for the use of Dedicated EGR® (D-EGR®) in a gasoline powered medium truck engine. The project goal was to determine if it is possible to match the thermal efficiency of a medium-duty diesel engine in Class 4 to Class 7 truck operations. The project evaluated a range of parameters for a D-EGR engine, including displacement, operating speed range, boosting systems, and BMEP levels. The engine simulation was done in GT-POWER, guided by experimental experience with smaller size D-EGR engines. The resulting engine fuel consumption maps were applied to two vehicle models, which ran over a range of 8 duty cycles at 3 payloads. This allowed a thorough evaluation of how D-EGR and conventional gasoline engines compare in fuel consumption and thermal efficiency to a diesel. The project results show that D-EGR gasoline engines can compete with medium duty diesel engines in terms of both thermal efficiency and GHG emissions.
Journal Article

Brief Investigation of SCR High Temperature N2O Production

2012-04-16
2012-01-1082
Nitrous Oxide (N₂O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 (298-310 times more potent than carbon dioxide (CO₂)). As a result, any aftertreatment system that generates N₂O must be well understood to be used effectively. Under low temperature conditions, N₂O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N₂O formed by the thermal decomposition of ammonium nitrate. Ammonium nitrate and N₂O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO₂). This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO₂ ratio above 1. However, N₂O has also been observed at relatively high temperatures, in the region of 500°C.
Journal Article

Diesel Cold-Start Emission Control Research for 2015-2025 LEV III Emissions

2013-04-08
2013-01-1301
The diesel engine can be an effective solution to meet future greenhouse gas and fuel economy standards, especially for larger segment vehicles. However, a key challenge facing the diesel is the upcoming LEV III emissions standard which will require significant reductions of hydrocarbon (HC) and oxides of nitrogen (NOx) from current levels. The challenge stems from the fact that diesel exhaust temperatures are much lower than gasoline engines so the time required to achieve effective emissions control with current aftertreatment devices is considerably longer. The objective of this study was to determine the potential of a novel diesel cold-start emissions control strategy for achieving LEV III emissions. The strategy combines several technologies to reduce HC and NOx emissions before the start of the second hill of the FTP75.
Technical Paper

Impact of EGR on Combustion Processes in a Hydrogen Fuelled SI Engine

2008-04-14
2008-01-1039
With concerns continuing to grow with respect to global warming from greenhouse gases, further regulations are being examined, developed and are expected for the emission of CO2 as an automobile exhaust. Renewable alternate fuels offer the potential to significantly reduce the CO2 impact of transportation. Hydrogen as a spark - ignition (SI) engine fuel provides this potential for significant CO2 reduction when generated from renewable resources. In addition, hydrogen has advantageous combustion properties including a wide flammable mixture range which facilitates lean burning and high dilution, fast combustion energy release and zero CO2 emissions. However, the high burning rates and fast energy release can lead to excessive in-cylinder pressures and temperatures resulting in combustion knock and high NOx emissions at stoichiometric operation.
Technical Paper

Comparison of Emission Characteristics of Conventional, Hydrotreated, and Fischer-Tropsch Diesel Fuels in a Heavy-Duty Diesel Engine

2001-09-24
2001-01-3519
This study compared diesel exhaust emission from four different diesel fuels: a conventional low sulfur D2 diesel (0.03% sulfur, 28% aromatics), California Air Resources Board (CARB) diesel (0.015% sulfur, 8% aromatics), “Swedish” diesel (<0.001% sulfur, 4% aromatics), and a Fischer-Tropsch (F-T) diesel (<0.0001% sulfur, <0.1% aromatics) fuel. The comparison included regulated emissions, hydrocarbon speciation, air toxics, aldehydes and ketones, particle size distribution, and greenhouse gas emissions. Testing was conducted using a Cummins B-Series engine installed both in a heavy light-duty truck operating on a chassis dynamometer and on an engine dynamometer. The chassis driving cycles included city, highway, and aggressive driving operation. Engine dynamometer tests included the U.S. transient cycle.
Technical Paper

A Dual-Use Hybrid Electric Command and Control Vehicle

2001-11-12
2001-01-2775
Until recently, U.S. government efforts to dramatically reduce emissions, greenhouse gases and vehicle fuel consumption have primarily focused on passenger car applications. Similar aggressive reductions need to be extended to heavy vehicles such as delivery trucks, buses, and motorhomes. However, the wide range of torques, speeds, and powers that such vehicles must operate under makes it difficult for any current powertrain system to provide the desired improvements in emissions and fuel economy. Hybrid electric powertrains provide the most promising, near-term technology that can satisfy these requirements. This paper highlights the configuration and benefits of a hybrid electric powertrain capable of operating in either a parallel or series mode. It describes the hybrid electric components in the system, including the electric motors, power electronics and batteries.
Technical Paper

Impact of Ultra-Clean Fischer-Tropsch Diesel Fuel on Emissions in a Light Duty Passenger Car Diesel Engine

2002-10-21
2002-01-2725
Sulfur and aromatic compounds in diesel fuel impact the emissions profile of current diesel engines. Fuels that do not contain these components can be made from natural gas using Fischer-Tropsch chemistry. Very little data has been presented comparing the emissions characteristics of current low sulfur diesel to fuels with ultra low levels of sulfur and aromatics in passenger car diesel engines. This study reports on an exhaust emission comparison of currently available conventional diesel fuel to Fischer Tropsch diesel fuel free of aromatics and sulfur comparisons included regulated emissions, air toxics, aldehydes and ketones, particle size distribution, and greenhouse gas emissions. Testing was conducted on a current model diesel passenger car using a chassis dynamometer. Regulated emissions were analyzed according to the Code of Federal Regulations (CFR) Title 40 specifications and requirements of the Environmental Protection Agency (EPA) Federal Test Procedure (FTP).
Technical Paper

Design and Development of the 2002 Michigan Tech FutureTruck, a Parallel Hybrid Electric Vehicle

2003-03-03
2003-01-1257
In this paper, the conversion of a production sport utility vehicle (SUV) to a hybrid electric vehicle utilizing a through-the-road parallel hybrid configuration is presented. The uniqueness of this design comes from its ability to decouple the front and rear drivetrain to simplify the packaging of underbody components. The Hybrid Theory utilizes a 2.0L, 4-cylinder engine that supplies 101kW (135hp) to the front wheels and a DC motor that supplies an additional 53kW (70hp) to the rear wheels to achieve the competition goals of a 25% improvement in fuel economy, a reduction in Green House Gas (GHG) emissions, as well as maintaining stock performance. The effects on drivability, manufacturing, fuel economy, emissions, and performance are presented along with the design, selection, and implementation of all of the vehicle conversion components.
Technical Paper

Development of Greenhouse Gas Emissions Model for 2014-2017 Heavy- and Medium-Duty Vehicle Compliance

2011-09-13
2011-01-2188
Of all existing modes of transportation, onroad motor vehicles are the largest contributor to greenhouse gas emissions and fuel usage. The Environmental Protection Agency and the National Highway Traffic Safety Administration finalized regulations in April 2010 to reduce greenhouse gas emissions and improve fuel economy for 2012-2016 model year light-duty vehicles. In November 2010, both agencies jointly proposed the first ever greenhouse gas standards for medium- and heavy-duty trucks which are expected to take effect for model years starting in 2014. Vehicles of light-duty families are subject to mandatory testing for certification and compliance. Unlike the light-duty sector where a vast majority of vehicles are mass produced for generally similar purposes, medium- and heavy-duty vehicles are commonly custom-made.
Technical Paper

Efficiency and Emissions Characteristics of Partially Premixed Dual-Fuel Combustion by Co-Direct Injection of NG and Diesel Fuel (DI2) - Part 2

2017-03-28
2017-01-0766
The CO2 advantage coupled with the low NOX and PM potential of natural gas (NG) makes it well-suited for meeting future greenhouse gas (GHG) and NOX regulations for on-road medium and heavy-duty engines. However, because NG is mostly methane, reduced combustion efficiency associated with traditional NG fueling strategies can result in significant levels of methane emissions which offset the CO2 advantage due to reduced efficiency and the high global warming potential of methane. To address this issue, the unique co-direct injection capability of the Westport HPDI fuel system was leveraged to obtain a partially-premixed fuel charge by injecting NG during the compression stroke followed by diesel injection for ignition timing control. This combustion strategy, referred to as DI2, was found to improve thermal and combustion efficiencies over fumigated dual-fuel combustion modes.
Technical Paper

Light Duty Vehicle Life Cycle Analysis

2021-04-06
2021-01-0789
The short-term future direction of the automotive transportation sector is uncertain. Many governments and environmental localities around the world are proposing internal combustion engine (ICE) bans and enacting large subsidy programs for zero-tailpipe emissions vehicles powered by batteries or fuel-cells. Such policies can be effective in driving the consumer towards specific powertrains. The reason for such aggressive change is to reduce the sector’s carbon footprint. However, it is not clear if these proposals will reduce greenhouse gas (GHG) emissions. Emissions from raw material extraction, manufacturing, and power generation are shadowed by the focus on reducing the reliance on fossil fuel use. Emissions from non-tailpipe sources should also be considered before pushing for a rapid change to powertrains. Life-cycle analysis (LCA) can assess the GHG emissions produced before, during and after the life of a vehicle in a cradle-to-grave analysis.
Technical Paper

Fuel Economy Improvements and NOx Reduction by Reduction of Parasitic Losses: Effect of Engine Design

2006-10-31
2006-01-3474
Reducing aerodynamic drag and tire rolling resistance in trucks using cooled EGR engines meeting EPA 2004 emissions standards has been observed to result in increases in fuel economy and decreases in NOx emissions. We report here on tests conducted using vehicles equipped a non-EGR engine meeting EPA 2004 emission standards and an electronically-controlled engine meeting EPA 1998 emissions standards. The effects of trailer fairings and single-wide tires on fuel economy and NOx emissions were tested using SAE test procedure J1321. NOx emissions were measured using a portable emissions monitoring system (PEMS). Fuel consumption was estimated by a carbon balance on PEMS output and by the gravimetric method specified by test procedure J1321. Fuel consumption decreased and fuel economy increased by a maximum of about 10 percent, and NOx emissions decreased by a maximum of 20 percent relative to baseline.
Technical Paper

Predictive GT-Power Simulation for VNT Matching on a 1.6 L Turbocharged GDI Engine

2018-04-03
2018-01-0161
The thermal efficiency benefits of low-pressure (LP) exhaust gas recirculation (EGR) in spark-ignition engine combustion are well known. One of the greatest barriers facing adoption of LP-EGR for high power-density applications is the challenge of boosting. Variable nozzle turbines (VNTs) have recently been developed for gasoline applications operating at high exhaust gas temperatures (EGTs). The use of a single VNT as a boost device may provide a lower-cost option compared to two-stage boosting systems or 48 V electronic boost devices for some LP-EGR applications. A predictive model was created based on engine testing results from a 1.6 L turbocharged gasoline direct injection (GDI) engine [1]. The model was tuned so that it predicted burn-rates and end-gas knock over an engine operating map with varying speeds, loads, EGR rates and fuel types.
Technical Paper

Greenhouse Gas Reduction from EnviroKool Piston in Lean Burn Natural Gas and Diesel Dual Fuel Heavy Duty Engine

2022-06-14
2022-37-0004
Heavy-duty (HD) internal combustion engines (ICE) have achieved quite high brake thermal efficiencies (BTE) in recent years. However, worldwide GHG regulations have increased the pace towards zero CO2 emissions. This, in conjunction with the ICE reaching near theoretical efficiencies means there is a fundamental lower limit to the GHG emissions from a conventional diesel engine. A large factor in achieving lower GHG emissions for a given BTE is the fuel, in particular its hydrogen to carbon ratio. Substituting a fuel like diesel with compressed natural gas (CNG) can provide up to 25% lower GHG at the same BTE with a sufficiently high substitution rate. However, any CNG slip through the combustion system is penalized heavily due to its large global warming potential compared to CO2. Therefore, new technologies are needed to reduce combustion losses in CNG-diesel dual fuel engines.
Technical Paper

CARB Low NOx Stage 3 Program - Modified Engine Calibration and Hardware Evaluations

2020-04-14
2020-01-0318
With the conclusion of the California Air Resources Board (CARB) Stage 1 Ultra-Low NOX (ULN) program, there continues to be a commitment for identifying potential pathways to demonstrate 0.02 g/bhp-hr NOX emissions. The Stage 1 program focused on achieving the ULN levels on the heavy-duty regulatory cycles utilizing a turbo-compound engine which required the integration of novel catalyst technologies and a supplemental heat source. While the aftertreatment configuration provided a potential solution to meet the ULN target, a complicated approach with a greenhouse gas (GHG) penalty was required to overcome challenges from low temperature exhaust. A subsequent Stage 2 program was concerned with the development of a new low load test cycle and evaluating the trade-off between GHG and tailpipe NOX on the Stage 1 ULN solution.
Technical Paper

CARB Low NOX Stage 3 Program - Aftertreatment Evaluation and Down Selection

2020-04-14
2020-01-1402
With the conclusion of the California Air Resources Board (CARB) Stage 1 Ultra-Low NOX program, there continues to be a commitment for identifying potential pathways to demonstrate 0.02 g/hp-hr NOX emissions. The Stage 1 program focused on achieving the Ultra-Low NOX (ULN) levels utilizing a turbo-compound (TC) engine, which required the integration of novel catalyst technologies and a supplemental heat source. While the aftertreatment configuration provided a potential solution to meet the ULN target, a complicated approach was required to overcome challenges from low temperature exhaust. The Stage 3 program leverages a different engine architecture more representative of the broader heavy-duty industry to meet the Phase 2 Greenhouse Gas (GHG) targets and to simplify the ULN aftertreatment solution. The following work will discuss the aftertreatment technology evaluation, down selection criteria, and the emission results for the candidate ULN systems
Journal Article

CARB Low NOX Stage 3 Program - Final Results and Summary

2021-04-06
2021-01-0589
Despite considerable progress over the last several decades, California continues to face some of the most significant air quality problems in the United States. These continued issues highlight the need for further mobile source NOX reductions to help California and other areas meet ambient air quality targets mandated by the U.S. EPA. Beginning in 2014, the California Air Resources Board (CARB) launched a program aimed at demonstrating technologies that could enable heavy-duty on-highway engines to reach tailpipe NOX levels up to 90% below the current standards, which were implemented in 2010. At the same time, mandated improvements to greenhouse gas emissions (GHG) require that these NOX reductions be achieved without sacrificing fuel consumption and increasing GHG emissions.
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