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Significant reductions of particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines have been realized through fueling with water-fuel emulsions. However, the physical and chemical in-cylinder mechanisms that affect these pollutant reductions are not well understood. To address this issue, laser-based and chemiluminescence imaging experiments were performed in an optically-accessible, heavy-duty diesel engine using both a standard diesel fuel (D2) and an emulsion of 20% water, by mass (W20). A laser-based Mie-scatter diagnostic was used to measure the liquid-phase fuel penetration and showed 40-70% greater maximum liquid lengths with W20 at the operating conditions tested. At some conditions with low charge temperature or density, the liquid phase fuel may impinge directly on in-cylinder surfaces, leading to increased PM, HC, and CO emissions because of poor mixing.

In-cylinder control of particulate emissions in a diesel engine depends on careful control and understanding of the fuel injection and air/fuel mixing process. It is extremely difficult to measure physical parameters of the injection and mixing process in an operating engine, but it is possible to simulate some diesel combustion chamber conditions in a steady flow configuration whose characteristics can be more easily probed. This program created a steady flow environment in which air-flow and injection sprays were characterized under non-combusting conditions, and emissions measurements were made under combusting conditions. A limited test matrix was completed in which the following observations were made. Grid-generated air turbulence decreased particulates, CO, and unburned hydrocarbons, while CO2 and NOx levels were increased. The turbulence accelerated combustion, resulting in more complete combustion and higher temperatures at the measurement location.

The increased use of diesel-powered equipment in underground mines has prompted interest in reducing their exhaust pollutants. Control of particulate emissions without substantial penalties in other emissions or fuel consumption is necessary. This paper describes test results on a prechaaber, naturally-aspirated, four-cycle diesel engine in which two different concentrations of water-in-fuel emulsions were run. The independent variables comprising the test matrix were fuel, speed, load, injection timing, injection rate, and compression ratio. The dependent variables of the experiment included particulate and gaseous emissions and engine thermal efficiency. Regression analysis was performed on the data to determine how particulate emissions were affected by fuel and engine parameters. Results of this analysis indicated that substantial reductions in particulate emissions could be obtained by utilizing water-in-fuel emulsions.

This paper is the fourth in a series describing work sponsored by the Bureau of Mines to reduce diesel particulate and gaseous emissions through fuel modification. A stabilized water microemulsion fuel developed in previous work was tested in a Caterpillar 3304 NA four-cylinder engine with compression ratio and injection timing and rate optimized for this fuel to demonstrate the emissions reductions achieved. It was tested in both standard and optimum configurations with both baseline DF-2 and optimized microemulsion fuels. Gaseous and particulate data are presented from steady-state tests using a computer-operated mini-dilution tunnel and from transient tests using a total exhaust dilution tunnel. The optimized engine-fuel combination was effective in reducing particulates and oxides of nitrogen in steady-state tests. However, the standard engine-fuel combination provided the lowest particulate and NOx emissions in transient tests.