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The development of PM and NOx reduction system with the combination of DOC included DPF and SCR catalyst in addition to the AOC sub-assembly for NH3 slip protection is described. DPF regeneration strategy and manual regeneration functionality are introduced with using ITH, HCI device on the EUI based EGR, VGT 12.3L diesel engine at the CVS full dilution tunnel test bench. With this system, PM and NOx emission regulation for JPNL was satisfied and DPF regeneration process under steady state condition and transient condition (JE05 mode) were successfully fulfilled. Manual regeneration process was also confirmed and HCI control strategy was validated against the heat loss during transient regeneration mode. Presenter Seung-il Moon

Hydrogen is widely considered a promising fuel for future transportation applications for both, internal combustion engines and fuel cells. Due to their advanced stage of development and immediate availability hydrogen combustion engines could act as a bridging technology towards a wide-spread hydrogen infrastructure. Although fuel cell vehicles are expected to surpass hydrogen combustion engine vehicles in terms of efficiency, the difference in efficiency might not be as significant as widely anticipated [1]. Hydrogen combustion engines have been shown capable of achieving efficiencies of up to 45 % [2]. One of the remaining challenges is the reduction of nitric oxide emissions while achieving peak engine efficiencies. This paper summarizes research work performed on a single-cylinder hydrogen direct injection engine at Argonne National Laboratory.

Past experimental studies conducted by the current authors on a 13 liter 16.7:1 compression ratio heavy-duty diesel engine have shown that diesel-Compressed Natural Gas (CNG) Reactivity Controlled Compression Ignition (RCCI) combustion targeting low NOx emissions becomes progressively difficult to control as the engine load is increased. This is mainly due to difficulty in controlling reactivity levels at higher loads. For the current study, CFD investigations were conducted in CONVERGE using the SAGE combustion solver with the application of the Rahimi mechanism. Studies were conducted at a load of 5 bar BMEP to validate the simulation results against RCCI experimental data. In the low load study, it was found that the Rahimi mechanism was not able to predict the RCCI combustion behavior for diesel injection timings advanced beyond 30 degCA bTDC. This poor prediction was found at multiple engine speed and load points.

Gasoline compression ignition (GCI) technology shows the potential to obtain high thermal efficiencies while maintaining low soot and NOx emissions in light-duty engine applications. Recent experimental studies and numerical simulations have indicated that high reactivity gasoline-like fuels can further enable the benefits of GCI combustion. However, there is limited empirical data in the literature studying the gasoline compression ignition process at relevant in-cylinder conditions, which are required for further optimizing combustion system designs. This study investigates the temporal and spatial evolution of the compression ignition process of various high reactivity gasoline fuels with research octane numbers (RON) of 71, 74 and 82, as well as a conventional RON 97 E10 gasoline fuel. A ten-hole prototype gasoline injector specifically designed for GCI applications capable of injection pressures up to 450 bar was used.

Because of domestic production from renewable sources and their clean burning nature, alcohols, especially ethanol, have seen growing use as a blending agent and replacement for basic hydrocarbons in gasoline. The increasing use of alcohol in fuels raises questions on the safety of these fuels under certain non-operational situations. Modern vehicles use evaporative emission control systems to minimize environmental emissions of fuel. These systems must be relatively leak-free to function properly and are self-diagnosed by the vehicle On-Board Diagnostic system. When service is required, the service leak testing procedures may involve forcing test gases into the “evap” system and also exposure of the fuel vapors normally contained in the system to atmosphere. Previous work has discussed the hazards involved when performing shop leak testing activities for vehicles fuelled with conventional hydrocarbon gasoline [1, 2].

It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil-derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter.

The application of hydrogen (H2) as an internal combustion (IC) engine fuel has been under investigation for several decades. The favorable physical properties of hydrogen make it an excellent alternative fuel for fuel cells as well as IC engines and hence it is widely regarded as the energy carrier of the future. The potential of hydrogen as an IC engine fuel can be optimized by direct injection (DI) as it provides multiple degrees of freedom to influence the in-cylinder combustion processes and consequently the engine efficiency and exhaust emissions. This paper studies a single-hole nozzle and examines the effects of injection strategy on engine efficiency, combustion behavior and NOx emissions. The experiments for this study are done on a 0.5 liter single-cylinder research engine which is specifically designed for combustion studies and equipped with a cylinder head that allows side as well as central injector location.

Interest in natural gas as a fuel for light-duty transportation has increased due to its domestic availability and lower cost relative to gasoline. Natural gas, comprised mainly of methane, has a higher knock resistance than gasoline making it advantageous for high load operation. However, the lower flame speeds of natural gas can cause ignitability issues at part-load operation leading to an increase in the initial flame development process. While port-fuel injection of natural gas can lead to a loss in power density due to the displacement of intake air, injecting natural gas directly into the cylinder can reduce such losses. A study was designed and performed to evaluate the potential of natural gas for use as a light-duty fuel. Steady-state baseline tests were performed on a single-cylinder research engine equipped for port-fuel injection of gasoline and natural gas, as well as centrally mounted direct injection of natural gas.

Life Cycle Value Assessment (LCVA) is a decision making tool which considers environmental, economic and/or social aspects for the entire life cycle of a product or process from “cradle-to-grave”. LCVA can be used for a wide range of public policy and business decisions with the analysis being performed at various levels of rigour. By its nature, LCVA utilizes data sets of varying qualities drawn from a wide range of sources. The uncertainties in the input data obviously lead to uncertainties in the results of the LCVA analysis. To establish confidence in an LCVA's recommendations, it is important to consider these uncertainties and incorporate an assessment of uncertainty into the LCVA process. However, the diverse nature of the data sets being used makes it difficult to rigorously establish data uncertainty levels. In addition, the complexity of most life cycle models makes it difficult to trace uncertainty through the analysis process.

Fuel choices are being made today by consumers, industry and government. One such choice is whether to use reformulated gasoline to replace regular unleaded gasoline. A second choice involves the source of crude oil, with synthetic crude oil from tar sands currently expanding its share of the Canadian supply. Decision makers usually work with the direct economic consequences of their fuel choice. However, they generally lack the knowledge to measure environmental aspects of different fuel systems. This paper uses Life Cycle Value Assessment (LCVA) to demonstrate how the life cycle environmental aspects can be compared for alternative fuel choices. LCVA is an engineering decision making tool which provides a framework for the decision maker to consider the key economic and environmental impacts for the entire life cycle of alternative products or process systems.

The favorable physical properties of hydrogen (H2) make it an excellent alternative fuel for internal combustion (IC) engines and hence it is widely regarded as the energy carrier of the future. Hydrogen direct injection provides multiple degrees of freedom for engine optimization and influencing the in-cylinder combustion processes. This paper compares the results in the mixture formation and combustion behavior of a hydrogen direct-injected single-cylinder research engine using two different injector locations as well as various injector nozzle designs. For this study the research engine was equipped with a specially designed cylinder head that allows accommodating a hydrogen injector in a side location between the intake valves as well as in the center location adjacent to the spark plug.

One-dimensional single-zone and two-zone analyses have been exercised to calculate the mass fraction burned in an engine operating on ethanol/gasoline-blended fuels using the cylinder pressure and volume data. The analyses include heat transfer and crevice volume effects on the calculated mass fraction burned. A comparison between the two methods is performed starting from the derivation of conservation of energy and the method to solve the mass fraction burned rates through the results including detailed explanation of the observed differences and trends. The apparent heat release method is used as a point of reference in the comparison process. Both models are solved using the LU matrix factorization and first-order Euler integration.

Although HCCI engines promise low NOx emissions with high efficiency, they suffer from a narrow operating range between knock and misfire because they lack a direct means of controlling combustion timing. A series of previous studies showed that reformer gas, (RG, defined as a mixture of light gases dominated by hydrogen and carbon monoxide), can be used to control combustion timing without changing mixture dilution, (λ or EGR) which control engine load. The effect of RG blending on combustion timing was found to be mainly related to the difference in auto-ignition characteristics between the RG and base fuel. The practical effectiveness of RG depends on local production using a fuel processor that consumes the same base fuel as the engine and efficiently produces high-hydrogen RG as a blending additive.

Natural gas is a challenging fuel for HCCI engines because its single-stage ignition and rapid combustion make it difficult to optimize combustion timing over a significant load range. This study investigates direct injection of a pilot quantity of high-cetane fuel near TDC as a range extension and combustion control mechanism for natural gas HCCI engines. The EGR and load range is studied in a supercharged natural gas HCCI engine equipped with external EGR, intake heating and a direct injection system for n-heptane pilot fuel. The operating range and emissions are of primary interest and are compared between both the baseline HCCI engine with variable intake temperature and the direct injected HCCI (DI-HCCI) engine with constant intake temperature. Test results show the EGR and load range at fixed intake temperature can be extended using pilot direct injection.

Life Cycle Analysis (LCA) considers the key environmental impacts for the entire life cycle of alternative products or processes in order to select the best alternative. An ideal LCA would be an expensive and time consuming process because any product or process typically involves many interacting systems and a considerable amount of data must be analysed for each system. Practical LCA methods approximate the results of an ideal analysis by setting limited analysis boundaries and by accepting some uncertainty in the data values for the systems considered. However, there is no consensus in the LCA field on the correct method of selecting boundaries or on the treatment of data set uncertainty. This paper demonstrates a new method of selecting system boundaries for LCA studies and presents a brief discussion on applying Monte Carlo Analysis to treat the uncertainty questions in LCA.

Dual fuel (CI) engines provide an excellent means of maintaining high thermal efficiency and power while reducing emissions, particularly in situations where the primary fuel does not exhibit good auto-ignition characteristics. This is especially true of diesel engines operating on natural gas; usually in stationary applications such as distributed power generation. However, because two fuels are needed, the reliability of the engine is compromised. Therefore, this paper describes the first phase of a project that is to eventually manufacture dimethyl ether (DME) from natural gas and supply it to the pilot injector of a dual fuel engine. A chemical pilot plant has been built and operated, demonstrating an intermediate step in the production of DME from natural gas. DME is manufactured from methanol for pilot injection into a dual fuel engine operating with natural gas as the main fuel.

This paper describes two independent studies on γ-alumina as a plasma-activated catalyst. γ-alumina (2.5 - 4.3 wt%) was coated onto the surface of mesoporous silica to determine the importance of aluminum surface coordination on NOx conversion in conjunction with nonthermal plasma. Results indicate that the presence of 5- and 6- fold aluminum coordination sites in γ-alumina could be a significant factor in the NOx reduction process. A second study examined the effect of changing the reducing agent on NOx conversion. Several hydrocarbons were examined including propene, propane, isooctane, methanol, and acetaldehyde. It is demonstrated that methanol was the most effective reducing agent of those tested for a plasma-facilitated reaction over γ-alumina.

Natural gas quality, in terms of the volume fraction of higher hydrocarbons, strongly affects the auto-ignition characteristics of the air-fuel mixture, the engine performance and its controllability. The influence of natural gas composition on engine operation has been investigated both experimentally and through chemical kinetic based cycle simulation. A range of two component gas mixtures has been tested with methane as the base fuel. The equivalence ratio (0.3), the compression ratio (19.8), and the engine speed (1000 rpm) were held constant in order to isolate the impact of fuel autoignition chemistry. For each fuel mixture, the start of combustion was phased near top dead center (TDC) and then the inlet mixture temperature was reduced. These experimental results have been utilized as a source of data for the validation of a chemical kinetic based full-cycle simulation.

This paper discusses the compression ratio influence on maximum load of a Natural Gas HCCI engine. A modified Volvo TD100 truck engine is controlled in a closed-loop fashion by enriching the Natural Gas mixture with Hydrogen. The first section of the paper illustrates and discusses the potential of using hydrogen enrichment of natural gas to control combustion timing. Cylinder pressure is used as the feedback and the 50 percent burn angle is the controlled parameter. Full-cycle simulation is compared to some of the experimental data and then used to enhance some of the experimental observations dealing with ignition timing, thermal boundary conditions, emissions and how they affect engine stability and performance. High load issues common to HCCI are discussed in light of the inherent performance and emissions tradeoff and the disappearance of feasible operating space at high engine loads.

Homogeneous Charge Compression Ignition (HCCI) has been proposed for natural gas engines in heavy duty stationary power generation applications. A number of researchers have demonstrated, through simulation and experiment, the feasibility of obtaining high gross indicated thermal efficiencies and very low NOx emissions at reasonable load levels. With a goal of eventual commercialization of these engines, this paper sets forth some of the primary challenges in obtaining high brake thermal efficiency from production feasible engines. Experimental results, in conjunction with simulation and analysis, are used to compare HCCI operation with traditional lean burn spark ignition performance. Current HCCI technology is characterized by low power density, very dilute mixtures, and low combustion efficiency. The quantitative adverse effect of each of these traits is demonstrated with respect to the brake thermal efficiency that can be expected in real world applications.