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The effect of ammoniac deoxidizing agent (Urea) on the reduction of NOx produced in the Diesel engine was investigated numerically. Urea desolved in water was directly injected into the engine cylinder during the expansion stroke. The NOx deoxidizing process was described using a simplified chemical kinetic model coupled with the comprehensive kinetics of Diesel oil surrogate combustion. If the technology of DWI (Direct Water Injection) with the later injection timing is supposed to be used, the deoxidizing reactants could be delivered in a controlled amount directly into the flame plume zones, where NOx are forming. Numerical simulations for the Isotta Fraschini DI Diesel engine are carried out using the KIVA-3V code, modified to account for the “co-fuel” injection and reaction with combustion products. The results showed that the amount of NOx could be substantially reduced up to 80% with the injection timing and the fraction of Urea in the solution optimized.

Both spray-wall and spray-spray interactions in direct injection diesel engines have been found to influence the rate of heat release and the formation of emissions. Simulations of these phenomena for diesel sprays need to be validated, and an issue is investigating what kind of fuels can be used in both experiments and spray calculations. The objective of this work is to compare numerical simulations with experimental data of sprays impinging on a temperature controlled wall with respect to spray characteristics and heat transfer. The numerical simulations were made using the STAR-CD and KIVA-3V codes. The CFD simulations accounted for the actual spray chamber geometry and operating conditions used in the experiments. Particular attention was paid to the fuel used for the simulations.