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Lean NOx trap (LNT) is a great potential NOx abatement method for lean-burn gasoline engines in consideration of exhaust aftertreatment cost and installation space. NOx firstly is adsorbed on storage sites during the lean-burn period, then reduced to N2 under catalysis of the catalyst sites in the rich-burn phase. There must be a spillover of NOx species between both types of sites. For a better understanding of this spillover process of NOx species between Pt (as the catalytic center) and BaO sites (as storage components in commercial catalyst), this work focused on the vital first step of spillover, the adsorption of NOx on clean substrate surface (γ-Al2O3 (110) surface) and Ba\Pt cluster supported by the surface. Based on first principles software VASP (Vienna Ab-initio Simulation Package), the most stable adsorption structures of NO with Pt3 clusters and (BaO)3 clusters on carrier γ- Al2O3 (110) surface were confirmed and the adsorption energy of these structures were compared.

Transparent materials such as Plexiglas and glass are applied in airplane and boat widely as the windows and hatches. There are three type stresses in the structure made of Plexiglas or glass, which are residual stresses from the casting, residual stresses due to manufacturing process involving sheet forming structure and the stresses from serving period. In the paper the stresses are studied by laser scattered Photoelasticy method. Phase shift method is presented to recognize scattered light patterns automatically. The residual stresses in Plexiglas plate and shell were analyzed by thin plate-shell theory. Stresses in the Plexiglas and shell were tested by laser scattered Photoelastic method.

Recent toxicological and epidemiologic studies have shown that diesel emissions have been a significant toxic air contaminant. Catalyzed DPF (CDPF) not only significantly reduces the PM mass emissions (>90%), but also further promotes carrier self-regeneration and oxidize more harmful gaseous pollutants by the catalyst coated on the carrier. However, some ultrafine particles and potentially harmful gaseous pollutants, such as VOCs species, originally emitted in the vapor-phase at high plume temperature, may penetrate through the CDPF filter. Furthermore, the components and content of catalyst coated on the CDPF could influence the physicochemical properties and toxicity intensity of those escaping ultrafine particles and gaseous pollutants. In this work, (1) we investigated the influence of precious metal content as a variable parameter on the physicochemical properties and catalytic activities of the small CDPF samples.

The evolution of surface functional groups (SFGs) and the graphitization degree of soot generated in premixed methane flames are studied and the correlation between them is discussed. Test soot samples were obtained from an optimized thermophoretic sampling system and probe sampling system. The SFGs of soot were determined by Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS) after removing the soluble impurities from the soot samples, while the graphitization degree of soot was characterized by Raman spectrum and electron energy loss spectroscopy (EELS). The results reveal that the number of aliphatic C-H groups and C=O groups shows an initial increase and then decrease in the sooting history. The large amount of aliphatic C-H groups and small amount of aromatic C-H groups in the early stage of the soot mass growth process indicate that aliphatic C-H groups make a major contribution to the early stage of soot mass growth.

Rubber bushing is an important connection component in vehicle suspensions. It plays an important role in vehicle performance. In the past years, the theories of rubber have been studied, and several forms of the strain energy potential, incompressible or almost incompressible, have been developed. But not all of these models are suitable for all kinds of applications. Therefore, when investigating the rubber bushing, it is necessary to find the effective constitutive equations. Two bushings with different shapes are studied. One is an ax-symmetric uniform bushing. The other one has additional two longitudinal holes. A process of parameter identification is conducted. The axial stiffness and radial stiffness of the bushing are tested and used as objectives. The parameters of constitutive equations are defined as design variables. The nonlinear analysis software ABAQUS and a multi-disciplinary optimization software OPTIMUS are used.

Stiffness is one of the key points for research and development of vehicle body in white (BIW). Fast and effective evaluation of stiffness is very important for reducing the time and cost of research and development. How to realize weight reduction with proper stiffness is also a focus point of automobile design. In general, commercial software is used to optimize the BIW design. But the optimization process is time consuming. Therefore a simple but effective tool for fast evaluation is desired. A method to evaluate stiffness with sensitivity coefficients of sheet metal thickness of body structure is proposed in this paper. The simple mathematical relation of the sensitivity coefficients, the thickness variation of sheet metals, and the stiffness of body structure is established. The stiffness can be evaluated quickly for various combination of sheet metal thickness without running large-scale simulation using commercial software.

During the aero-engine operation, the compressor blades are subjected to periodic inertial force and aerodynamic excitation caused by blade rotation and airflow disturbance, respectively. Under the coupling alternating loads, the blade is prone to high cycle fatigue failure. In this paper, a time domain calculation model of fluid-structure interaction (FSI) is established to study the vibration characteristics of the blade and its failure modes are analyzed. Then, the fatigue damage of the blade under multi-level loading is evaluated by the nonlinear damage accumulation model. Considering the coupling effect of the airflow and the blade, computational fluid dynamics (CFD) is applied to calculate the aerodynamic parameters on the blade surface under different working conditions, which is imported to the finite element (FE) model to analyze the dynamic characteristics.

Proton exchange membrane (PEM) fuel cell is widely recognized as an outstanding portable power plant and expected to be possibly commercialization in the near future. As is well known, mechanical stresses implemented on the bipolar plates during the assembly procedure should have prominent influences on mass and heat transfer behavior inside the cell, as well as the resultant performance. In this study, an analytical model is proposed to comprehensively investigate the influence of clamping force on the mass transport, electrochemical properties and overall cell output capability of a PEM fuel cell. The results indicate that proper clamping force not only benefits the gas leakage prevention but also increases the contact area between the neighboring components to decrease the contact ohmic resistance.

In order to improve the combustion and emissions for high-speed marine diesel engines, numerical investigations on effects of different combustion chamber structures combined with oxygen enriched air have to be conducted. The study uses AVL Fire code to establish three-dimensional combustion model and simulate the in-cylinder flow, air-fuel mixing and combustion process with the flow dynamics metrics such as swirl number and uniformity index, analyze the interactional effects of combustion chamber structures and oxygen enriched air against the experimental data for a part load operation at 1350 r/min, find the optimized way to improve engine performance as well as decrease the NOx and soot emissions. The novelty is that this study is to combine different oxygen concentration with different combustion chamber structures including the re-entrant chamber, the straight chamber and the open chamber.

In order to achieve high-efficiency and clean combustion in HCCI engines, combustion must be controlled reasonably. A great variety of species with various reactivities can be produced through low temperature oxidation of fuels, which offers possible solutions to the problem of controlling in-cylinder mixture reactivity to accommodate changes in the operating conditions. In this work, in-cylinder combustion characteristics with low temperature reforming (LTR) were investigated in an optical engine fueled with low octane number fuel. LTR was achieved through low temperature oxidation of fuels in a reformer (flow reactor), and then LTR products (oxidation products) were fed into the engine to alter the charge reactivity. Primary Reference Fuels (blended fuel of n-heptane and iso-octane, PRFs) are often used to investigate the effects of octane number on combustion characteristics in engines.

Although turbulence plays a critical role in engines operated within low temperature combustion (LTC) regime, its interaction with chemistry on auto-ignition at low-ambient-temperature and lean-oxygen conditions remains inadequately understood. Therefore, it is worthwhile taking turbulence-chemistry interaction (TCI) into consideration in LTC engine simulation by employing advanced combustion models. In the present study, large eddy simulation (LES) coupled with linear eddy model (LEM) is performed to simulate the ignition process in n-heptane spray under engine-relevant conditions, known as Spray H. With LES, more details about unsteady spray flame could be captured compared to Reynolds-averaged Navier-Stokes equations (RANS). With LEM approach, both scalar fluctuation and turbulent mixing on sub-grid level are captured, accounting for the TCI. A skeletal mechanism is adopted in this numerical simulation, including 41 species and 124 reactions.

The previous study indicates that the detonation waves generated by acetylene/oxygen mixture can converge in the combustion chamber. In order to verify the destructive effect of detonation wave convergence on piston materials, the detonation bomb device was modified to fundamentally investigate the material failures of aluminum alloy for pistons. The results show that the specimens are destroyed in the middle and edge region after dozens of detonations, which is consistent with the typical characteristics of the piston failures in engines. Therefore, the hypothesis that failures of piston material is caused by the detonation wave convergence is verified.

Compared with conventional flow field, metal foam has been increasingly used for gas distributor in the PEM (proton exchange membrane) fuel cell due to its high porosity and conductivity, which significantly enhances the species transport under high current density condition. In this study, the cell performances with metal foam and graphite parallel flow field are compared under normal and subzero temperature conditions. Besides, electrochemical impedance spectroscopy (EIS) is recorded to characterize the Ohmic, polarization and polarization resistance. Under normal condition, the cell with metal foam exhibits three times better performance than the one with parallel flow field. Meanwhile, the effects of inlet gas humidity and flow rates on cell performance are also studied, indicating that the cathode flooding easily occurs due to its difficult water removal. However, the high flow rate can greatly ease the cathode water flooding.