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In this work, two blends of isopropanol, n-butanol, and ethanol (IBE) that can be produced by metabolically engineered clostridium acetobutylicum are studied experimentally in advanced compression ignition (ACI). This is done to determine whether these fuel blends have the right fuel properties to enable thermally stratified compression ignition, a stratified ACI strategy that using the cooling potential of single stage ignition fuels to control the heat release process. The first microorganism, ATCC824, produces a blend of 34.5% isopropanol, 60.1% n-butanol, and 5.4% ethanol, by mass. The second microorganism, BKM19, produces a blend of 12.3% isopropanol, 54.0% n-butanol, and 33.7% ethanol, by mass. The sensitivity of both IBE blends to intake pressure, intake temperature, and cylinder energy content (fueling rate) is characterized and compared to that of its neat constituents. Both IBE blends behaved similarly with a reactivity level between that of ethanol and n-butanol.

A novel advanced combustion strategy that employs the kinetically controlled compression ignition of gasoline whose autoignition is sensitive to fuel concentration is termed Low Temperature Gasoline Combustion. The LTGC method can achieve high thermal efficiency with a commercially available fuel while generating ultra-low soot and NOx emissions relative to the conventional combustion modes. At high loads, a double direct injection (D-DI) strategy is used where the first injection generates a background premixed charge while a second compression stroke injection controls the level of fuel stratification on a cycle-to-cycle basis to manage the heat release rates. With lower loads, this combustion performance of this D-DI strategy decreases as the background charge becomes increasingly lean. Instead, a single direct injection (S-DI) is used at lower loads to maintain an adequate combustion efficiency.

An experimental study was conducted on a Ricardo Hydra single-cylinder light-duty diesel research engine. Start of Injection (SOI) timing sweeps from -350 deg aTDC to -210 deg aTDC were performed on a total number of five pistons including two baseline metal pistons and three coated pistons to investigate the effects of thick thermal barrier coatings (TBCs) on the efficiency and emissions of low-temperature combustion (LTC). A fuel with a high latent heat of vaporization, wet ethanol, was chosen to eliminate the undesired effects of thick TBCs on volumetric efficiency. Additionally, the higher surface temperatures of the TBCs can be used to help vaporize the high heat of vaporization fuel and avoid excessive wall wetting. A specialized injector with a 60° included angle was used to target the fuel spray at the surface of the coated piston.

Thermal barrier coatings (TBCs) have long been studied as a potential pathway to achieve higher thermal efficiency in spark ignition engines. Researchers have studied coatings with different thicknesses and thermophysical properties to counteract the volumetric efficiency penalty associated with TBCs in spark ignition. To achieve an efficiency benefit with minimal charge heating during the intake stroke, low thermal inertia coatings characterized by their larger temperature swings are required. To study the impact of low thermal inertia coatings in spark ignition, coatings were applied to the cylinder head, piston crown, intake and exhaust valve faces, and intake and exhaust valve backsides. Tier III EEE E10 certification gasoline was used to keep the experiments relevant to the present on-road vehicles. This study is aimed at analyzing durability of the coatings as well as efficiency and emissions improvements.

Catalytic converters, which are commonly used for after-treatment in SI engines, exhibit poor performance at lower temperatures. This is one of the main reasons that tailpipe emissions drastically increase during cold-start periods. Thermal inertia of turbocharger casing prolongs the catalyst warm-up time. Exhaust enthalpy management becomes crucial for a turbocharged direct injection spark ignition (DISI) engine during cold-start periods to quickly heat the catalyst and minimize cold-start emissions. Thermal barrier coatings (TBCs), because of their low thermal inertia, reach higher surface temperatures faster than metal walls, thereby blocking heat transfer and saving enthalpy for the catalyst. The TBCs applied on surfaces that exchange heat with exhaust gases can increase the enthalpy available for the catalyst warm-up.