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In this work, two blends of isopropanol, n-butanol, and ethanol (IBE) that can be produced by metabolically engineered clostridium acetobutylicum are studied experimentally in advanced compression ignition (ACI). This is done to determine whether these fuel blends have the right fuel properties to enable thermally stratified compression ignition, a stratified ACI strategy that using the cooling potential of single stage ignition fuels to control the heat release process. The first microorganism, ATCC824, produces a blend of 34.5% isopropanol, 60.1% n-butanol, and 5.4% ethanol, by mass. The second microorganism, BKM19, produces a blend of 12.3% isopropanol, 54.0% n-butanol, and 33.7% ethanol, by mass. The sensitivity of both IBE blends to intake pressure, intake temperature, and cylinder energy content (fueling rate) is characterized and compared to that of its neat constituents. Both IBE blends behaved similarly with a reactivity level between that of ethanol and n-butanol.

Solid Oxide Electrolysis (SOE) with an embedded Sabatier reactor is an innovative and efficient concept for regenerative air revitalization. The concept safely eliminates handling of hydrogen, and works regardless of gravity and pressure environments with no moving parts and no multi-phase flows. It also is efficient because it requires no expendables from Earth while being compact with minimal impact on mass. The consequence is significant because SOE is an inherently suitable technology (and possibly the only technology) for enabling 100% oxygen regeneration from carbon dioxide and water vapor, two byproducts of crew activity that must be managed. To investigate the feasibility of this concept, a Sabatier reactor was successfully embedded into a single SOE cell.

Solid oxide electrolysis with embedded Sabatier reactors is being developed to regenerate all the oxygen required by a crew, eliminating any resupply needs. Metabolically produced carbon dioxide and water are electrolyzed at high temperature to produce pure dry oxygen. Carbon monoxide and hydrogen byproducts are converted to methane and water in the embedded Sabatier reactor. As it is embedded in the electrolyzer, the water is further electrolyzed to produce additional oxygen. A demonstration unit has been designed at full scale with a design production rate equivalent to that required to support one third of one person's oxygen requirements. Stack design was configured to enable the electrolyzer and Sabatier stacks to operate at their respective temperatures. Thermal modeling was performed to support internal heater sizing, insulation design, and evaluate touch temperatures. The unit was built and tested. Modeling and initial testing results are presented.

The Major Constituent Analyzer (MCA) was activated on-orbit on 2/13/01 and provided essentially continuous readings of partial pressures for oxygen, nitrogen, carbon dioxide, methane, hydrogen and water in the ISS atmosphere. The MCA plays a crucial role in the operation of the Laboratory ECLSS and EVA operations from the airlock. This paper discusses the performance of the MCA as compared to specified accuracy requirements. The MCA has an on-board self-calibration capability and the frequency of this calibration could be relaxed with the level of instrument stability observed on-orbit. This paper also discusses anomalies the MCA experienced during the first year of on-orbit operation. Extensive Built In Test (BIT) and fault isolation capabilities proved to be invaluable in isolating the causes of anomalies. The process of fault isolation is discussed along with development of workaround solutions and implementation of permanent on-orbit corrections.

On the International Space Station (ISS), humidity condensate will be collected from the atmosphere and treated by multifiltration to produce potable water for use by the crews. Ground-based development tests have demonstrated that multifiltration beds filled with a series of ion-exchange resins and activated carbons can remove many inorganic and organic contaminants effectively from wastewaters. As a precursor to the use of this technology on the ISS, a demonstration of multifiltration treatment under microgravity conditions was undertaken. On the Space Shuttle, humidity condensate from cabin air is recovered in the atmosphere revitalization system, then stored and periodically vented to space vacuum. A Shuttle Condensate Adsorption Device (SCAD) containing sorbent materials similar to those planned for use on the ISS was developed and flown on STS-68 as a continuation of DSO 317, which was flown initially on STS-45 and STS-47.

Regenerative-type subsystems are being tested at JSC to provide atmosphere revitalization functions of oxygen supply and carbon dioxide (CO2) removal for a future Space Station. Oxygen is supplied by an electrolysis subsystem, developed by General Electric, Wilmington, Mass., which uses the product water from either the CO2 reduction subsystem or a water reclamation process. CO2 is removed and concentrated by an electrochemical process, developed by Life Systems, Inc., Cleveland, Ohio. The concentrated CO2 is reduced in a Sabatier process with the hydrogen from the electrolysis process to water and methane. This subsystem is developed by Hamilton Standard, Windsor Locks, Conn. These subsystems are being integrated into an atmosphere revitalization group. This paper describes the integrated test configuration and the initial checkout test. The feasibility and design compatibility of these subsystems integrated into an air revitalization system is discussed.

Reduction of metabolic carbon dioxide is one of the essential steps in physiochemical air revitalization for long-duration manned space missions. Under contract with NASA Johnson Space Center, Hamilton Standard is developing an Advanced Carbon Reactor Subsystem (ACRS) to produce water and dense solid carbon from carbon dioxide and hydrogen. The ACRS essentially consists of a Sabatier Methanation Reactor (SMR) to reduce carbon dioxide with hydrogen to methane and water, a gas-liquid separator to remove product water from the methane, and a Carbon Formation Reactor (CFR) to pyrolyze methane to carbon and hydrogen. The hydrogen is recycled to the SMR, while the produce carbon is periodically removed from the CFR. The SMR is well-developed, while the CFR is under development. In this paper, the fundamentals of the SMR and CFR processes are presented and results of Breadboard CFR testing are reported.

An experimental study was conducted on a Ricardo Hydra single-cylinder light-duty diesel research engine. Start of Injection (SOI) timing sweeps from -350 deg aTDC to -210 deg aTDC were performed on a total number of five pistons including two baseline metal pistons and three coated pistons to investigate the effects of thick thermal barrier coatings (TBCs) on the efficiency and emissions of low-temperature combustion (LTC). A fuel with a high latent heat of vaporization, wet ethanol, was chosen to eliminate the undesired effects of thick TBCs on volumetric efficiency. Additionally, the higher surface temperatures of the TBCs can be used to help vaporize the high heat of vaporization fuel and avoid excessive wall wetting. A specialized injector with a 60° included angle was used to target the fuel spray at the surface of the coated piston.

Spark ignition engines have low tailpipe criteria pollutants due to their stoichiometric operation and three-way catalysis and are highly controllable. However, one of their main drawbacks is that the compression ratio is low due to knock, which incurs an efficiency penalty. With a global push towards low-lifecycle-carbon renewable fuels, high-octane alternatives to gasoline such as ethanol are attractive options as fuels for spark ignition engines. Under premixed spark ignition operating conditions, ethanol can enable higher compression ratios than regular-grade gasoline due to its high octane number. The high cooling potential of high-ethanol content gasolines, like E85, or of ethanol-water blends, like hydrous ethanol, can be leveraged to further reduce knock and enable higher compression ratios as well as further downsizing and boosting to reduce frictional and throttling losses.

Renewable fuels, such as the alcohols, ammonia, and hydrogen, have a high autoignition resistance. Therefore, to enable these fuels in compression ignition, some modifications to existing engine architectures is required, including increasing compression ratio, adding insulation, and/or using hot internal residuals. The opposed-piston two-stroke (OP2S) engine architecture is unique in that, unlike conventional four-stroke engines, the OP2S can control the amount of trapped residuals over a wide range through its scavenging process. As such, the OP2S engine architecture is well suited to achieve compression ignition of high autoignition resistance fuels. In this work, compression ignition with wet ethanol 80 (80% ethanol, 20% water by mass) on a 3-cylinder OP2S engine is experimentally demonstrated. A load sweep is performed from idle to nearly full load of the engine, with comparisons made to diesel at each operating condition.

High compression ratios are critical to increasing the efficiency of spark ignition engines, but the trend in downsized and down sped configurations has brought attention to the nominally low compression ratios used to avoid knock. Knock is an abnormal combustion event defined by the acoustic sound caused by end-gas auto-ignition ahead of the flame front. In order to avoid engine-damaging levels of knock, low compression ratios and retarded combustion phasing at high loads are used, both of which lower efficiency. Low carbon alternative fuels such as ethanol or water-based alcohol fuels combine strong chemical auto-ignition resistance with large charge cooling characteristics that can suppress knock and enable optimal combustion phasing, thus allowing an increase in the compression ratio.

Solid Oxide Electrolysis with an embedded Sabatier reactor is being developed for regenerative air revitalization. In a previous effort, an embedded Sabatier reactor was demonstrated using a nickel-based electrode in a SOE cell. To explore the performance potential, new experiments were performed at various operating temperatures and inlet gas compositions. Successful methane and oxygen regeneration was achieved. The gas compositions fed to the cell were a mixture of carbon dioxide, water, carbon monoxide, and hydrogen in ratios indicative of a previously electrolyzed stream of metabolically produced by-products (carbon dioxide and water vapor) of nominal crew activity. The composition was varied by simulating various degrees of oxygen regeneration by upstream electrolysis cells. All results are presented and compared to previous testing where applicable. Carbon deposition was observed in the inlet tube to the cell.