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Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

2012-06-18
The development of PM and NOx reduction system with the combination of DOC included DPF and SCR catalyst in addition to the AOC sub-assembly for NH3 slip protection is described. DPF regeneration strategy and manual regeneration functionality are introduced with using ITH, HCI device on the EUI based EGR, VGT 12.3L diesel engine at the CVS full dilution tunnel test bench. With this system, PM and NOx emission regulation for JPNL was satisfied and DPF regeneration process under steady state condition and transient condition (JE05 mode) were successfully fulfilled. Manual regeneration process was also confirmed and HCI control strategy was validated against the heat loss during transient regeneration mode. Presenter Seung-il Moon
Journal Article

Eulerian CFD Modeling of Coupled Nozzle Flow and Spray with Validation Against X-Ray Radiography Data

2014-04-01
2014-01-1425
This paper implements a coupled approach to integrate the internal nozzle flow and the ensuing fuel spray using a Volume-of-Fluid (VOF) method in the CONVERGE CFD software. A VOF method was used to model the internal nozzle two-phase flow with a cavitation description closed by the homogeneous relaxation model of Bilicki and Kestin [1]. An Eulerian single velocity field approach by Vallet et al. [2] was implemented for near-nozzle spray modeling. This Eulerian approach considers the liquid and gas phases as a complex mixture with a highly variable density to describe near nozzle dense sprays. The mean density is obtained from the Favreaveraged liquid mass fraction. The liquid mass fraction is transported with a model for the turbulent liquid diffusion flux into the gas.
Journal Article

Simulation of Organic Rankine Cycle Power Generation with Exhaust Heat Recovery from a 15 liter Diesel Engine

2015-04-14
2015-01-0339
The performance of an organic Rankine cycle (ORC) that recovers heat from the exhaust of a heavy-duty diesel engine was simulated. The work was an extension of a prior study that simulated the performance of an experimental ORC system developed and tested at Oak Ridge National laboratory (ORNL). The experimental data were used to set model parameters and validate the results of that simulation. For the current study the model was adapted to consider a 15 liter turbocharged engine versus the original 1.9 liter light-duty automotive turbodiesel studied by ORNL. Exhaust flow rate and temperature data for the heavy-duty engine were obtained from Southwest Research Institute (SwRI) for a range of steady-state engine speeds and loads without EGR. Because of the considerably higher exhaust gas flow rates of the heavy-duty engine, relative to the engine tested by ORNL, a different heat exchanger type was considered in order to keep exhaust pressure drop within practical bounds.
Journal Article

Very High Cycle Fatigue of Cast Aluminum Alloys under Variable Humidity Levels

2015-04-14
2015-01-0556
Ultrasonic fatigue tests (testing frequency around 20 kHz) have been conducted on four different cast aluminum alloys each with a distinct composition, heat treatment, and microstructure. Tests were performed in dry air, laboratory air and submerged in water. For some alloys, the ultrasonic fatigue lives were dramatically affected by the environment humidity. The effects of different factors like material composition, yield strength, secondary dendrite arm spacing and porosity were investigated; it was concluded that the material strength may be the key factor influencing the environmental humidity effect in ultrasonic fatigue testing. Further investigation on the effect of chemical composition, especially copper content, is needed.
Journal Article

Modeling Approach to Estimate EGR Cooler Thermal Fatigue Life

2015-04-14
2015-01-1654
Cooled EGR continues to be a key technology to meet emission regulations, with EGR coolers performing a critical role in the EGR system. Designing EGR coolers that reliably manage thermal loads is a challenge with thermal fatigue being a top concern. The ability to estimate EGR cooler thermal fatigue life early in the product design and validation cycle allows for robust designs that meet engine component reliability requirements and customer expectations. This paper describes a process to create an EGR cooler thermal fatigue life model. Components which make up the EGR cooler have differing thermal responses, consequently conjugate transient CFD must be used to accurately model metal temperatures during heating and cooling cycles. Those metal temperatures are then imported into FEA software for structural analysis. Results from both the CFD and FEA are then used in a simplified numerical model to estimate the virtual strain of the EGR cooler.
Journal Article

Impact of Carbonaceous Compounds Present in Real-World Diesel Exhaust on NOx Conversion over Vanadia-SCR Catalyst

2016-04-05
2016-01-0921
Exposure of hydrocarbons (HCs) and particulate matter (PM) under certain real-world operating conditions leads to carbonaceous deposit formation on V-SCR catalysts and causes reversible degradation of its NOx conversion. In addition, uncontrolled oxidation of such carbonaceous deposits can also cause the exotherm that can irreversibly degrade V-SCR catalyst performance. Therefore carbonaceous deposit mitigation strategies, based on their characterization, are needed to minimize their impact on performance. The nature and the amount of the deposits, formed upon exposure to real-world conditions, were primarily carried out by the controlled oxidation of the deposits to classify these carbonaceous deposits into three major classes of species: i) HCs, ii) coke, and iii) soot. The reversible NOx conversion degradation can be largely correlated to coke, a major constituent of the deposit, and to soot which causes face-plugging that leads to decreased catalyst accessibility.
Journal Article

Effect of Transition Metal Ion Properties on the Catalytic Functions and Sulfation Behavior of Zeolite-Based SCR Catalysts

2017-03-28
2017-01-0939
Copper- and Iron- based metal-zeolite SCR catalysts are widely used in US and European diesel aftertreatment systems to achieve drastic reduction in NOx emission. These catalysts are highly selective to N2 under wide range of operating conditions. Nevertheless, the type of transition metal has a significant impact on the key performance and durability parameters such as NOx conversion, selectivity towards N2O, hydrothermal stability, and sensitivity to fuel sulfur content. In this study, we explained the differences in the performance characteristics of these catalysts based on their relative acidic-basic nature of transition metal present in these catalysts using practically relevant gas species present in diesel exhaust such as NO2, SOx, and NH3. These experiments show that Fe-zeolite has relatively acidic nature as compared to Cu-zeolite that causes NH3 inhibition and hence explains low NOx conversion on Fe-zeolite at low temperature under standard SCR conditions.
Technical Paper

Alleviating the Magnetic Effects on Magnetometers Using Vehicle Kinematics for Yaw Estimation for Autonomous Ground Vehicles

2020-04-14
2020-01-1025
Autonomous vehicle operation is dependent upon accurate position estimation and thus a major concern of implementing the autonomous navigation is obtaining robust and accurate data from sensors. This is especially true, in case of Inertial Measurement Unit (IMU) sensor data. The IMU consists of a 3-axis gyro, 3-axis accelerometer, and 3-axis magnetometer. The IMU provides vehicle orientation in 3D space in terms of yaw, roll and pitch. Out of which, yaw is a major parameter to control the ground vehicle’s lateral position during navigation. The accelerometer is responsible for attitude (roll-pitch) estimates and magnetometer is responsible for yaw estimates. However, the magnetometer is prone to environmental magnetic disturbances which induce errors in the measurement.
Journal Article

The Effect of Welding Dimensional Variability on the Fatigue Life of Gas Metal Arc Welded Joints

2011-04-12
2011-01-0196
Gas Metal Arc Welding (GMAW) is widely employed for joining relatively thick sheet steels in automotive body-in-white structures and frames. The GMAW process is very flexible for various joint geometries and has relatively high welding speed. However, fatigue failures can occur at welded joints subjected to various types of loads. Thus, vehicle design engineers need to understand the fatigue characteristics of welded joints produced by GMAW. Currently, automotive structures employ various advanced high strength steels (AHSS) such as dual-phase (DP) and transformation-induced plasticity (TRIP) steels to produce lighter vehicle structures with improved safety performance and fuel economy, and reduced harmful emissions. Relatively thick gages of AHSS are commonly joined to conventional high strength steels and/or mild steels using GMAW in current body-in-white structures and frames.
Journal Article

Correlation between Scatter in Fatigue Life and Fatigue Crack Initiation Sites in Cast Aluminum Alloys

2012-04-16
2012-01-0920
High cycle fatigue tests at a constant positive mean stress have been performed on a Al-Si-Cu cast aluminum alloy. The Random Fatigue Limit (RFL) model was employed to fit the probabilistic S-N curves based on Maximum Likelihood Estimate (MLE). Fractographic studies indicated that fatigue cracks in most specimens initiate from oxide films located at or very close to specimen surface. The RFL model was proved to be able to accurately capture the scatter in fatigue life. The cumulative density function (CDF) of fatigue life determined by RFL fit is found to be approximately equal to the complementary value of the CDF of the near-surface fatigue initiator size.
Journal Article

Investigation of the Impact of Real-World Aging on Diesel Oxidation Catalysts

2012-04-16
2012-01-1094
Real-world operation of diesel oxidation catalysts (DOCs), used in a variety of aftertreatment systems, subjects these catalysts to a large number of permanent and temporary deactivation mechanisms. These include thermal damage, induced by generating exotherm on the catalyst; exposure to various inorganic species contained in engine fluids; and the effects of soot and hydrocarbons, which can mask the catalyst in certain operating modes. While some of these deactivation mechanisms can be accurately simulated in the lab, others are specific to particular engine operation regimes. In this work, a set of DOCs, removed from prolonged service in the field, has been subjected to a detailed laboratory study. Samples obtained from various locations in these catalysts were used to characterize the extent and distribution of deactivation.
Journal Article

Optimized AHSS Structures for Vehicle Side Impact

2012-04-16
2012-01-0044
Advanced high strength steels (AHSS) have been widely accepted as a material of choice in the automotive industry to balance overall vehicle weight and stringent vehicle crash test performance targets. Combined with efficient use of geometry and load paths through shape and topology optimization, AHSS has enabled vehicle manufacturers to obtain the highest possible ratings in safety evaluations by the Insurance Institute for Highway Safety (IIHS) and the National Highway Traffic Safety Administration (NHTSA). In this study, vehicle CAE side impact models were used to evaluate three side impact crash test conditions (IIHS side impact, NHTSA LINCAP and FMVSS 214 side pole) and the IIHS roof strength test condition and to identify several key components affecting the side impact test performance. HyperStudy® optimization software and LS-DYNA® nonlinear finite element software were utilized for shape and gauge optimization.
Journal Article

Development of Corrosion Testing Protocols for Magnesium Alloys and Magnesium-Intensive Subassemblies

2013-04-08
2013-01-0978
Corrosion tendency is one of the major inhibitors for increased use of magnesium alloys in automotive structural applications. Moreover, systematic or standardized methods for evaluation of both general and galvanic corrosion of magnesium alloys, either as individual components or eventually as entire subassemblies, remains elusive, and receives little attention from professional and standardization bodies. This work reports outcomes from an effort underway within the U.S. Automotive Materials Partnership - ‘USAMP’ (Chrysler, Ford and GM) directed toward enabling technologies and knowledge base for the design and fabrication of magnesium-intensive subassemblies intended for automotive “front end” applications. In particular, subassemblies consisting of three different grades of magnesium (die cast, sheet and extrusion) and receiving a typical corrosion protective coating were subjected to cyclic corrosion tests as employed by each OEM in the consortium.
Journal Article

New Insights into Reaction Mechanism of Selective Catalytic Ammonia Oxidation Technology for Diesel Aftertreatment Applications

2011-04-12
2011-01-1314
Mitigation of ammonia slip from SCR system is critical to meeting the evolving NH₃ emission standards, while achieving maximum NOx conversion efficiency. Ammonia slip catalysts (ASC) are expected to balance high activity, required to oxidize ammonia across a broad range of operating conditions, with high selectivity of converting NH₃ to N₂, thus avoiding such undesirable byproducts as NOx or N₂O. In this work, new insights into the behavior of an advanced ammonia slip catalyst have been developed by using accelerated progressive catalyst aging as a tool for catalyst property interrogation. The overall behavior was deconstructed to several underlying functions, and referenced to an active but non-selective NH₃ oxidation function of a diesel oxidation catalyst (DOC) and to the highly selective but minimally active NH₃ oxidation function of an SCR catalyst.
Journal Article

The Impact of Ammonium Nitrate Species on Low Temperature NOx Conversion Over Cu/CHA SCR Catalyst

2017-03-28
2017-01-0953
Cu/CHA catalysts have been widely used in the industry, due to their desirable performance characteristics including the unmatched hydrothermal stability. While broadly recognized for their outstanding activity at or above 200°C, these catalysts may not show desired levels of NOx conversion at lower temperatures. To achieve high NOx conversions it is desirable to have NO2/NOx close to 0.5 for fast SCR. However even under such optimal gas feed conditions, sustained use of Cu/CHA below 200°C leads to ammonium nitrate formation and accumulation, resulting in the inhibition of NOx conversion. In this contribution, the formation and decomposition of NH4NO3 on a commercial Cu/CHA catalyst have been investigated systematically. First, the impact of NH4NO3 self-inhibition on SCR activity as a function of temperature and NO2/NOx ratios was investigated through reactor testing.
Journal Article

Internal Diesel Injector Deposits: Theory and Investigations into Organic and Inorganic Based Deposits

2013-10-14
2013-01-2670
Over the last two decades, global emission regulations have become more stringent and have required the use of more advanced fuel injection systems. This includes the use of tighter tolerances, more rapid injections and internal components actuated by weaker injection forces. Unfortunately, these design features make the entire system more susceptible to fuel contaminants. Over the last six years, the composition of these contaminants has evolved from hard insoluble debris, such as dust and rocks, to soluble chemical contaminants. Recent research by the diesel engine manufacturers, fuel injection equipment suppliers and the fuel and fuel additive industry has discovered a major source of the soluble chemical contaminant that leads to injector deposits to be derived from cost effective and commonly used additives used to protect against pipeline corrosion.
Technical Paper

A 2-D Computational Model Describing the Heat Transfer, Reaction Kinetics and Regeneration Characteristics of a Ceramic Diesel Particulate Trap

1998-02-23
980546
A 2-D CFD model was developed to describe the heat transfer, and reaction kinetics in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state as well as the transient behavior of the flow and heat transfer during the trap regeneration processes. The trap temperature profile was determined by numerically solving the 2-D unsteady energy equation including the convective, heat conduction and viscous dissipation terms. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations (Opris, 1997). The reaction kinetics were described using a discretized first order Arrhenius function. The 2-D term describing the reaction kinetics and particulate matter conservation of mass was added to the energy equation as a source term in order to represent the particulate matter oxidation. The filtration model describes the particulate matter accumulation in the trap.
Technical Paper

A Study of the Filtration and Oxidation Characteristics of a Diesel Oxidation Catalyst and a Catalyzed Particulate Filter

2007-04-16
2007-01-1123
An experimental and modeling study was conducted to study the passive regeneration of a catalyzed particulate filter (CPF) by the oxidation of particulate matter (PM) via thermal and Nitrogen dioxide/temperature-assisted means. Emissions data in the exhaust of a John Deere 6.8 liter, turbocharged and after-cooled engine with a low-pressure loop EGR and a diesel oxidation catalyst (DOC) - catalyzed particulate filter (CPF) in the exhaust system was measured and used for this study. A series of experiments was conducted to evaluate the performance of the DOC, CPF and DOC+CPF configurations at various engine speeds and loads.
Technical Paper

Experimental and Modeling Results Comparing Two Diesel Oxidation Catalyst - Catalyzed Particulate Filter Systems

2008-04-14
2008-01-0484
Steady-state particulate loading experiments were conducted on an advanced production catalyzed particulate filter (CPF), both with and without a diesel oxidation catalyst (DOC). A heavy-duty diesel engine was used for this study with the experiments conducted at 20, 40, 60 and 75 % of full load (1120 Nm) at rated speed (2100 rpm). The data obtained from these experiments were used and are necessary for calibrating the MTU 1-D 2-Layer CPF model. These experimental and modeling results were compared to previous research conducted at MTU that used the same engine but an earlier development version of the combination of DOC and CPF. The motivation for the comparison of the two systems was to determine whether the reformulated production catalysts performed as good or better than the early development catalysts. The results were compared to understand the filtration and oxidation differences between the two DOC+CPF and the CPF-only aftertreatment systems.
Technical Paper

Experimental Studies of an Advanced Ceramic Diesel Particulate Filter

2008-04-14
2008-01-0622
A Cummins ISB 5.9 liter medium-duty engine with cooled EGR has been used to study an early extrusion of an advanced ceramic uncatalyzed diesel particulate filter (DPF). Data for the advanced ceramic material (ACM) and an uncatalyzed cordierite filter of similar dimensions are presented. Pressure drop data as a function of mass loadings (0, 4, and 6 grams of particulate matter (PM) per liter of filter volume) for various flow rate/temperature combinations (0.115 - 0.187 kg/sec and 240 - 375 °C) based upon loads of 15, 25, 40 and 60% of full engine load (684 N-m) at 2300 rpm are presented. The data obtained from these experiments were used to calibrate the MTU 1-D 2-Layer computer model developed previously at MTU. Clean wall permeability determined from the model calibration for the ACM was 5.0e-13 m2 as compared to 3.0e-13 m2 for cordierite.
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