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Traditional smoke opacity measurement, performed on diesel engines during regular emissions inspections, sensitive primarily to larger particles of elemental carbon, is very little sensitive to nanoparticles and to semi-volatile “organic carbon” particles. For this reason, it no longer suffices as a high emitter detection tool for modern vehicles with a particle filter or for advanced low-emissions technology where semi-volatile organic particles are the dominant fraction of particulate matter. This paper investigates the potential of common low-cost ionization type smoke detectors, produced in mass quantities for fire detection in buildings, as a tool to measure particle emissions in vehicular exhaust. Two ionization chambers were used to measure both raw and diluted exhaust of various engines powered by diesel fuel and biofuels under laboratory conditions as well as on the road.

An ordinary, unmodified port fuel injection spark ignition automobile engine with closed-loop air-fuel ratio control and a three-way catalyst was operated on two butanol isomers, n-butanol and iso-butanol, and their blends with gasoline at steady-state operating points covering both common and potentially problematic regimes. The engine control unit was able to maintain the air-fuel ratio while running on both butanol isomers and their blends with gasoline. Only small changes in the heat release rates, small and insignificant decrease in exhaust gas temperatures, and no excessive increase in emissions were observed. Under commanded enrichment operation, the maximum torque, air-fuel ratio and exhaust emissions were comparable among nearly all fuels tested. The exhaust gas temperatures were comparable among fuels, with a moderate increase observed in some regimes during operation with high share of n-butanol in fuel.