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Trivalent chromium passivation is used after zinc plating for enhancing corrosion resistance of parts. In the passivating process, the amount of dissolved metal ions (for example zinc and iron) in the passivation solution increases the longer the solution is used. This results in a reduced corrosion resistance at elevated temperatures. Adding a top coat after this process improves the corrosion resistance but has an increased cost. To combat this, we strove to clarify the mechanism of decreased corrosion resistance and to develop a trivalent chromium passivation with a higher corrosion resistance at elevated temperatures. At first, we found that in parts produced from an older solution, the passivation layer has cracks which are not seen in parts from a fresh/new solution. These cracks grow when heated at temperatures over 120 degrees Celsius.

In recent years, due to a growing demand for improvement in the performance and reliability of automotive fuel pumps and the advancement of globalization, automotive fuel pumps are being used with inferior gasolines that include more sulfur, organic acids or compounds, compared to gasolines used in general regions. Conventionally, bearings in these fuel pumps have mainly been made of sintered bronze alloy. With this bronze alloy, however, it is difficult to achieve a significant improvement in the tribology characteristics of bearings, in order to meet the demands for performance improvement, etc., and corrosion is severe in inferior gasolines that contain highly-concentrated organic acids or sulfur and the corrosion products that accompany them. Therefore, in order to obtain fine tribology characteristics and superior corrosion resistance in gasolines with highly-concentrated organic acids and sulfur, various copper-based alloys were studied using the powder metallurgy process.

PBT (polybutylene terephthalate) and epoxy adhesive, which both have superior heat resistance and environmental resistance, are a representative combination now being applied to many parts. Generally, PBT is annealed after molding at a temperature above the glass transition temperature to ensure dimensional stability when in use. But in this case, this process decreases the adhesive strength between PBT and epoxy. This study analyzes the adhesion degradation mechanism in this system and a countermeasure technology is proposed. Regarding this PBT-epoxy adhesion degradation mechanism, focus is placed on changes in the fracture surface, which is analyzed before and after annealing. From this analysis it becomes clear that generation of a WBL (weak boundary layer) is caused by non-crystallization and a migration of the PBT functional group on the adhesion surface layer.

Stringent emission regulations call for advanced catalyst substrates with thinner walls and higher cell density. However, substrates with higher cell density increase backpressure, thinner cell wall substrates have lower mechanical characteristics. Therefore we will focus on cell configurations that will show a positive effect on backpressure and emission performance. We found that hexagonal cells have a greater effect on emission and backpressure performance versus square or round cell configurations. This paper will describe in detail the advantage of hexagonal cell configuration versus round or square configurations with respect to the following features: 1 High Oxygen Storage Capacity (OSC) performance due to uniformity of the catalyst coating layer 2 Low backpressure due to the large hydraulic diameter of the catalyst cell 3 Quick light off characteristics due to efficient heat transfer and low thermal mass

The coming Diesel powertrains will remain as key technology in Europe to achieve the stringent 2025 CO2 emission targets. Especially for applications which are unlikely to be powered by pure EV technology like Light Duty vehicles and C/D segment vehicles which require a long driving range this is the case. To cope with these low CO2 targets the amount of electrification e.g. in form of 48V Belt-driven integrated Starter Generator (BSG) systems will increase. On the other hand the efficiency of the Diesel engine will increase which will result in lower exhaust gas temperatures resulting in a challenge to keep the required NOx reduction system efficiencies under Real Drive Emissions (RDE) driving conditions. In order to comply with the RDE legislation down to -7 °C ambient an efficient thermal management is one potential approach. Commonly utilized means to increase exhaust gas temperature are late injection and/or intake throttling, which enable sufficient NOx reduction efficiency.

A methodology for simulating effect of international variations in fuel compositions on spray combustion is proposed. The methodology is validated with spray combustion experiments with real fuels from three different countries. The compositions of those fuels were analyzed through GC×GC and H-NMR. It was found that ignition delay times, flame region and flame luminosity were significantly affected by the compositional variations. For the simulation, an evaporation surrogate consisting of twenty two species, covering basic molecular types and a wide range of carbon numbers, is developed. Each species in the evaporation surrogate is then virtually converted to a reaction surrogate consisting of n-hexadecane, methylcyclohexane and 1,2,4-trimethyl benzene so that combustion reactions can be calculated with a published kinetic model. The virtual species conversion (VSC) is made so as to take over combustion-related properties of each species of evaporation surrogates.

New 2A/F systems different from usual A/F-O2 systems are being developed to cope with strict regulation of exhaust gas. In the 2A/F systems, 2A/F sensors are equipped in front and rear of a three-way catalyst. The A/F-O2 systems are ideas which use a rear O2 to detect exhaust gas leaked from three-way catalyst early and feed back. On the other hand, the 2A/F systems are ideas which use a rear A/F sensor to detect nearly stoichiometric gas discharged from the three-way catalyst accurately, and to prevent leakage of exhaust gas from the three-way catalyst. Therefore, accurate detection of nearly stoichiometric gas by the rear A/F sensor is the most importrant for the 2A/F systems. In general, the A/F sensors can be classified into two types, so called, one-cell type and two-cell type. Because the one-cell type A/F sensors don’t have hysteresis, they have potential for higher accuracy.

For the purpose of improving vehicle fuel efficiency, it is necessary to reduce energy loss in the alternator. We have lowered the resistance of the rectifying device and connecting components, and control the rectifying device with an IC to reduce rectification loss. For the package design, we have changed the structure of the part on which the rectifying device is mounted into a high heat dissipation type. The new structure has enabled optimizing the size of the rectifying device, resulting in the reduction of size of the package. In addition, the rectifying device is mounted using a new soldering material and a new process, which has improved the reliability of the connection. Moreover, since the alternator has introduced a new system, the controller IC has a function for preventing malfunction of the rectifying device and a function for detecting abnormalities, in order to ensure safety.

Exhaust Gas Recirculation (EGR) systems reduce exhaust emissions and improve fuel efficiency. Recently, the number of EGR system installed vehicles has been increasing, especially for gasoline engine systems. One of the major causes of decreasing EGR function is deposit accumulation on a gas passage. The deposit consists mainly of hydrocarbons which are degradation products of fuel, thus the amount of deposit seems to be strongly affected by fuel compositions. Unfortunately there are not as many studies on EGR deposits with gasoline fuel as there are with diesel fuel. In this study, the influence of gasoline fuel compositions, especially aromatics which are major components of EGR gas, on chemical structures of the deposit were investigated. To clarify the accumulation mechanism of EGR deposits, a thermal oxidative degradation test with an autoclave unit and an actual gasoline engine test were employed.

The number of idle-stop vehicles is rapidly increasing in recent years, and air-conditioning technologies that extend engine stopped time while maintaining the cabin comfort are required. When the engine stops during idle- stop mode, the air conditioner also stops functioning. To maintain cabin comfort, the engine is restarted to work the air-conditioning cycle, which reduces the fuel saving effects. As a countermeasure, a cold storage air conditioning system has been proposed. The system extends engine non-operation time by using cold storage for generating cool air while the engine is stopped. We have integrated this technology into an evaporator, which is used in the air-conditioning cycle, and the system has a short cold storage period and a necessary cold release period. This report describes its concept and effects.

As a method of maintaining thermal sensation and comfort inside a passenger compartment, not only a conventional HVAC system but also a combination of a HVAC system and other devices such as seat heaters, a steering wheel heater, ventilation seats are increasing. This research developed a method to evaluate thermal sensation of a human body when using these various thermal control devices. This method can evaluate the heat balance of the human body by calculating the amount of heat exchange between a human body and the external environment, and it takes into consideration the influence of heat exchange by heat conduction with seats or a steering wheel. The human thermal model is made by dividing a human body into various segments, and it is the model that considers heat transport by blood flow for each segment.

In SI engines with port injection system, the injected fuel spray adheres surely on the port wall and the inlet valve, consequently, the spray-wall interaction process leads to the generation of unburned hydrocarbons and uncontrollable mixture formation. This paper deals with the fuel mixture preparation process including basic research on characteristics of the wall-wetted fuel film on a flat wall inside a constant volume vessel. In the experiments, iso-octane mixed with biacetyl as a tracer dopant was injected through a pintle type injector against a flat glass wall under the ambient conditions of atmospheric pressure and room temperature. The thickness of the adhered fuel film on the wall was quantitatively measured by using laser induced fluorescence (LIF) technique, which provides 2-D distribution information with high special resolution as a function of the injection duration, the impingement distance from the injector to the wall, and the impingement angle against the wall.

Fuel atomization is known as an effective means of reducing exhaust emissions from internal combustion engines. In this study, we present a cost-effective atomization method for multiple-hole nozzle gasoline injection systems that requires no auxiliary device or external energy source to carry out atomization. While many studies have been conducted before on the atomization mechanism, most assume that the key to atomization lies in the nozzle configuration or the interaction between the fuel spray and ambient air. We, on the other hand, paid particular attention to the fuel nozzle upstream flow and found how it plays a crucial role in fuel atomization. In case of using multiple-hole nozzle in particular, atomization is greatly influenced by impingement of upstream flow of the fuel nozzle, which leads to rapid directional change in the fuel flow.

Global exhaust emission regulations are becoming stricter, and vehicles equipped with the idle stop system (ISS) are increasing. Recently, starters for vehicles equipped with ISS are required to improve operation feel when speedily restarted. To satisfy this demand, starters must rotate at higher rotational speeds, and heavier wear in their brushes may cause problems. Tribofilm formed on commutators surface by the brush sliding is an important factor in the brush commutator wear, because tribofilm is said to have a property to increase lubricity and decrease mechanical wear in brushes and commutator, as well as to improve commutation and decrease arc wear. Therefore, for reducing brush commutator wear, it is considered effective to promote film formation by improving materials. However, few researches have been conducted to evaluate the relationship between brush materials and tribofilm formation.

With the global adoption of diesel common rail systems and the wide variation in composition of local commercial fuels, modern fuel injection systems must be robust against diverse fuel properties. To bridge the knowledge gap on the effects of compositional variation for real commercial fuels on spray combustion characteristics, the present work quantifies ignition and soot formation/oxidation in three unique, international diesel blends. Schlieren imaging, excited-state hydroxyl radical (OH*) chemiluminescence imaging and diffused back-illumination extinction imaging were employed to quantify vapor penetration, ignition, and soot formation and oxidation for high-pressure sprays in a constant-volume, pre-burn chamber. The three fuels were procured from Finland, Japan and Brazil and have cetane numbers of 64.1, 56.1 and 45.4, respectively.

Continuous improvement of gasoline engine emissions performance is required to further protect the global environment and also the impact of emissions on a local level. During real world driving, transient engine operation and variation in fuel injection, airflow, and wall temperature are key factors to be controlled. Due to the limited opportunity for optimization of engine control, generation of a well-mixed fuel spray is necessary to create a suitable combustion environment to minimize emissions. Optimum spray performance achieves minimum surface wetting as well as promoting evaporation and diffusion if wetting occurs. Improvement in spray homogeneity is an important step to achieve this. Higher fuel pressure is initially considered to achieve improvements, as it is expected to improve mixture formation by reduction of wall wetting due to high atomization and lower penetration, as well as improvement in spray homogeneity.

For the purpose of coping with the strengthening of NOx exhaust gas control and fuel consumption control, it is indispensable to improve the NOx purification capacity. In view of this, vehicle manufacturers are in the course of developing high performance SCR (Selective Catalytic Reduction) systems [1, 2]. For such SCR systems to be realized, high precision NOx sensors for carrying out urea injection quantity control and SCR degradation diagnosis are absolutely indispensable. Detection of NOx concentration by means of a NOx sensor is generally performed as follows: O2 is discharged by means of an O2 detection electrode; remaining NOx is decomposed by a NOx detection electrode; NOx concentration is then detected as electric current that flows when oxygen ions are conduct through solid electrolyte. In order to detect NOx of ppm-order, it is necessary to detect minute current of nA-order with high accuracy.

With the economic development of countries around the world led by BRICs(Brazil, Russia, India, China), the total number of automobiles in the world continues to rise. From the standpoint of preserving limited petroleum resources and reducing CO2 emissions, improved fuel consumption is necessary if we are to continue enjoying the use of automobiles. In Europe, significant development of diesel engine technology as a power source for automobiles has taken place to reduce fuel consumption and to enhance the “Fun to Drive” experience, and market share of diesel engines has increased in this area. However, with increasing environmental awareness worldwide, all areas of the globe are seeing tightened regulations for not only fuel consumption, but also exhaust emissions, including those for PM(Particulate Matter) and NOx. Of these regulations, the requirement for vehicles to satisfy the US Tier 2 Bin 5 rating, regardless of whether they are gasoline or dieselpowered, is the most stringent.

This study investigates if particulates from a GDI engine can be significantly suppressed by use of ultra-high injection pressures under 2 different engine conditions known to be associated with high particulate numbers (PN): warm-up and transients. Experiments were carried out in a single-cylinder GDI engine equipped with an endoscope connected to a high-speed camera to enable combustion visualization. To mimic the warming-up, the coolant temperature was varied between 20 °C and 90 °C. A Diesel injector with modified nozzle was used and the injection pressures were varied between 400 and 1500 bar. The results revealed that increasing the fuel injection pressure decreased engine out HC and PN under warming-up conditions. However, the coolant water temperature was the most dominant factor affecting the emissions. For coolant temperature of 20 °C, the use of 1500 bar fuel injection pressure in comparison to lower fuel pressures resulted in significantly lower PN.

This paper presents an improvement in the accuracy of NOx sensors at high NOx concentration regions by optimizing the manufacturing process, sensor electrode materials and structure, in order to suppress the deterioration mechanism of sensor electrodes. Though NOx sensors generally consist of Pt/Au alloy based oxygen pump electrodes and Pt/Rh alloy based sensor electrodes, detailed experimental analysis of aged NOx sensors showed changes in the surface composition and morphology of the sensor electrode. The surface of the sensor electrode was covered with Au, which is not originally contained in the electrode, resulting in a diminished active site for NOx detection on the sensor electrode and a decrease in sensor output. Theoretical analysis using CAE with molecular dynamics supported that Au tends to be concentrated on the surface of the sensor electrode.