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Fuel cell electric vehicles are a promising technology to create CO2- neutral mobility. Model-based development approaches are key to reduce costs and to raise efficiencies. A model on vehicle system level is discussed that balances the need of physical depth and computational performance. The vehicle model comprises the domains of mechanics, electrics, thermodynamics, cooling and controls. Detailed models of the fuel cell and battery are presented as a part of the system model. The models apply electrochemical approaches and spatial resolutions up to 3D. The models of both components are validated via 3D reference simulations showing a seamless parameter transfer between system level and CFD-based simulations. The validity of the vehicle model, including the electrochemical components, is demonstrated by simulating the Toyota Mirai vehicle. Simulation results of an NEDC are compared to measurements.

This work elaborates the transferability of electrode diffusion coefficients gained from fitting procedures in frequency domain to an electrochemical battery model run in time domain. An electrochemical battery model of an NMC622 half-cell electrode is simulated with sinusoidal current excitations at different frequencies. The current and voltage signals are analyzed in frequency domain via Nyquist and Bode plots. The frequency domain analysis of time domain simulations is applied to assess the numerical convergence of the simulation and the sensitivity on particle diameter, electrode and electrolyte diffusion coefficients. The simulated frequency spectra are used to fit the electrode diffusion coefficient by means of different electrical equivalent circuit models and the electrochemical battery model itself. The fitted diffusion coefficients from the different electrical equivalent circuit models deviate by one order of magnitude from the a priori known reference data.