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Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

The selective catalytic reduction has seen widespread adoption as the best technology to reduce the NOx emissions from internal combustion engines, particularly for Diesels. This technology uses ammonia as a reducing agent, which is obtained injecting an ammonia carrier into the exhaust gas stream. The dosing of the ammonia carrier, usually AdBlue, is the major concern during the design and engine calibration phases, since the interaction between the injected liquid and the components of the exhaust system can lead to the undesired formation of solid deposits. To avoid this, the thermal and kinematic interaction between the spray and the components of the after treatment system (ATS) must be modeled accurately. In this work, the authors developed a Conjugate Heat Transfer (CHT) framework to model the kinetic and thermal interaction among the spray, the eventual liquid layer and the pipe walls.

In recent years, the increase of gasoline fuel injection pressure is a way to improve thermal efficiency and lower engine-out emissions in GDI homogenous combustion concept. The challenge of controlling particulate formation as well in mass and number concentrations imposed by emissions regulations can be pursued improving the mixture preparation process and avoiding mixture inhomogeneity with ultra-high injection pressure values up to 100 MPa. The increase of the fuel injection pressure in GDI homogeneous systems meets the demand for increased injector static flow, while simultaneously improves the spray atomization and mixing characteristics with consequent better combustion performance. Few studies quantify the effects of high injection pressure on transient gasoline spray evolution. The aim of this work was to simulate with OpenFOAM the spray morphology of a commercial gasoline injected in a constant volume vessel by a prototypal GDI injector.

The injection process of urea-water solution (AdBlue) determines initial conditions for reactions and catalysis and is fundamentally responsible for optimal operation of selective catalytic reduction (SCR) systems. The spray characteristics of four, commercially available, injectors (one air-assisted and three pressure-driven with different nozzle-hole configurations) are investigated with non-intrusive measuring techniques. Injection occurred in the crossflow of a channel blowing preheated air in an exhaust duct similar configuration. The effect of several gas temperatures and flows on the spray propagation and entrainment has been extensively studied by shadow imaging. Shadow images, in addition, show that the spray of the pressure-driven injectors is only marginally affected by the gas crossflow. In contrast, the air assisted spray is strongly deflected by the gas, the effect increasing with increasing gas flow.

The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.

The modeling of fuel sprays under well-characterized conditions relevant for heavy-duty Diesel engine applications, allows for detailed analyses of individual phenomena aimed at improving emission formation and fuel consumption. However, the complexity of a reacting fuel spray under heavy-duty conditions currently prohibits direct simulation. Using a systematic approach, we extrapolate available spray models to the desired conditions without inclusion of chemical reactions. For validation, experimental techniques are utilized to characterize inert sprays of n-dodecane in a high-pressure, high-temperature (900 K) constant volume vessel with full optical access. The liquid fuel spray is studied using high-speed diffused back-illumination for conditions with different densities (22.8 and 40 kg/m3) and injection pressures (150, 80 and 160 MPa), using a 0.205-mm orifice diameter nozzle.

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.

The thorough understanding of the effects due to the fuel direct injection process in modern gasoline direct injection engines has become a mandatory task to meet the most demanding regulations in terms of pollutant emissions. Within this context, computational fluid dynamics proves to be a powerful tool to investigate how the in-cylinder spray evolution influences the mixture distribution, the soot formation and the wall impingement. In this work, the authors proposed a comprehensive methodology to simulate the air-fuel mixture formation into a gasoline direct injection engine under multiple operating conditions. At first, a suitable set of spray sub-models, implemented into an open-source code, was tested on the Engine Combustion Network Spray G injector operating into a static vessel chamber. Such configuration was chosen as it represents a typical gasoline multi-hole injector, extensively used in modern gasoline direct injection engines.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

Today, Direct-Injection systems are widely used on Spark-Ignition engines in combination with turbo-charging to reduce the fuel-consumption and the knock risks. In particular, the spread of Gasoline Direct Injection (GDI) systems is mainly related to the use of new generations of multi-hole, high-pressure injectors whose characteristics are quite different with respect to the hollow-cone, low-pressure injectors adopted in the last decade. This paper presents the results of an experimental campaign conducted on the spray produced by a GDI six-holes injector into a constant volume vessel with optical access. The vessel was filled with air at atmospheric pressure. Different operating conditions were considered for an injection pressure ranging from 3 to 20 MPa. For each operating condition, spray images were acquired by a CCD camera and then post processed to evaluate the spray penetration and cone angles.

Modeling plume interaction and collapse for direct-injection gasoline sprays is important because of its impact on fuel-air mixing and engine performance. Nevertheless, the aerodynamic interaction between plumes and the complicated two-phase coupling of the evaporating spray has shown to be notoriously difficult to predict. With the availability of high-speed (100 kHz) Particle Image Velocimetry (PIV) experimental data, we compare velocity field predictions between plumes to observe the full temporal evolution leading up to plume merging and complete spray collapse. The target “Spray G” operating conditions of the Engine Combustion Network (ECN) is the focus of the work, including parametric variations in ambient gas temperature. We apply both LES and RANS spray models in different CFD platforms, outlining features of the spray that are most critical to model in order to predict the correct aerodynamics and fuel-air mixing.

This paper is focused on the development and application of a CFD methodology that can be applied to predict the fuel-air mixing process in stratified charge, sparkignition engines. The Eulerian-Lagrangian approach was used to model the spray evolution together with a liquid film model that properly takes into account its effects on the fuel-air mixing process into account. However, numerical simulation of stratified combustion in SI engines is a very challenging task for CFD modeling, due to the complex interaction of different physical phenomena involving turbulent, reacting and multiphase flows evolving inside a moving geometry. Hence, for a proper assessment of the different sub-models involved a detailed set of experimental optical data is required. To this end, a large experimental database was built by the authors.

Future human exploration roadmaps involve the development of temporary or permanent outposts on Moon and Mars. The capability of providing astronauts with proper conditions for living and working in extraterrestrial environments is therefore a key issue for the sustainability of those roadmaps, and closed-loop Environment Control and Life Support Systems (ECLSSs) and bio-regenerative plants represent the necessary evolution of current technologies for complying with the challenging requirements imposed. This paper presents the architectural design of a terrestrial plant to be exploited to test and validate air and water management technologies for a biological life support system in a closed environment. The plant includes a crew area and a plant growth area. These two spaces can be considered as either a unique volume or two separated environments with reduced contact, e.g. for plant harvesting or other up-keeping activities.

A swirl injector for GDI application was used to inject an iso-octane spray in a quiescent chamber, to study the effect of the air density on the spray behavior. Stroboscopic images are recorded at different delays from the injection trigger to study the spray shape and structure. The temporal evolution of different spray parameters, length, width, angle, volume, instantaneous global air-fuel ratio, is calculated from the images. The effect of the increasing air density is to shorten the time and length scale of the spray evolution.

In this work an integration between a 1D code (Gasdyn) with a CFD code (OpenFOAM®) has been applied to improve the performance of a Moto3 engine. The four-stroke, single cylinder S.I. engine was modeled, in order to predict the wave motion in the intake and exhaust systems and to study how it affects the cylinder gas exchange process. The engine considered was characterized by having an air induction system with integrated filter cartridge, air-box and intake runner, including two fuel injectors, resulting in a complex air-path from the intake mouth to the intake valves, which presents critical aspects when a 1D modeling is addressed. The exhaust and intake systems have been optimized form the point of view of the wave action. However, due to the high revolution speed reached by this type of engine, the interaction between the gas stream and the fuel spray becomes a key aspect to be addressed in order to achieve the best performance at the desired operating condition.

Partially premixed combustion (PPC) can be applied to decrease emissions and increase fuel efficiency in direct injection, compression ignition (DICI) combustion engines. PPC is strongly influenced by the mixing of fuel and oxidizer, which for a given fuel is controlled mainly by (a) the fuel injection, (b) the in-cylinder flow, and (c) the geometry and dynamics of the engine. As the injection timings can vary over a wide range in PPC combustion, detailed knowledge of the in-cylinder flow over the whole intake and compression strokes can improve our understanding of PPC combustion. In computational fluid dynamics (CFD) the in-cylinder flow is sometimes simplified and modeled as a solid-body rotation profile at some time prior to injection to produce a realistic flow field at the moment of injection. In real engines, the in-cylinder flow motion is governed by the intake manifold, the valve motion, and the engine geometry.

The application of liquid aqueous Urea Solution (AUS) as reductant in SCR exhaust after-treatment systems is now a commonly accepted industry standard. Unfortunately, less acceptable are the associated difficulties caused by incomplete decomposition of the liquid, resulting in solid deposits which accumulate in the exhaust pipe downstream of the dosing components. The correct prediction of the spray pattern and, therefore, the spray impact on the walls is a key feature for the system optimization. A mechanical patternator, designed on the basis of CFD performance assessment, involving a Lagrangian representation of the dispersed liquid fully coupled with a 3D Eulerian description of the carrier phase, has been built and used to measure the spray mass distribution.

The ride comfort of three Alfa Romeo cars, namely Giulietta (1955), Alfetta (1972) and 159 (2005) has been assessed both objectively and subjectively. The three cars belong to the same market segment. The aim is to let young engineers or graduate students understand how technology has evolved and eventually learn a lesson from the assessed trend. A number of cleats have been fixed at the ground and the three cars have traversed such uneven surface. The objective assessment of the ride comfort has been performed by means of accelerometers fixed at the seat rails, additionally a special dummy developed at Politecnico di Milano has been employed. The subjective assessment has been performed by a panel of passengers. The match between objective and subjective ratings is very good. Simple mathematical models have been employed to establish a (successful) comparison between experimental and computational results. The ride comfort differs substantially among the cars.

The OpenFOAM® CFD methodology is nowadays employed for simulation in internal combustion engines and a lot of work has been done for an appropriate description of all complex phenomena. At the moment in the RANS turbulence models available in the OpenFOAM® toolbox the turbulence modulation is not yet included, and the present work analyzes the predictive capabilities of the code in simulating high injection pressure fuel sprays after modeling the influence of the dispersed phase on the turbulence structure. Different experiments were employed for the validation. At first, non-evaporating diesel spray was considered in a constant volume and quiescent vessel. The validation was performed via the available experimental spray evolution in terms of penetrations and spatial/temporal fuel distributions. Then the Sandia combustion chamber was chosen for diesel spray simulation in non-reacting conditions.

The paper presents results of an experimental investigation of the fluid dynamic processes during the air/fuel mixture formation period between an evaporating diesel spray and swirl air flow under realistic engine conditions. Particle Image Velocimetry (PIV) experiments have been carried out using an optically accessible prototype 2-stroke diesel engine equipped with a swirled combustion chamber. The flow within the chamber assumes a well structured swirl motion, similar to that developing in a real diesel engine, operating at high swirl ratio. The engine has been equipped with a common rail injection system and a solenoid-controlled injector, in use on automotive engines for the European market, able to manage multiple injection strategies. Two injector nozzles have been tested: a micro-sac 5-hole nozzle, 0.13 mm diameter, 150° spray angle and a 7-hole, 0.141 mm diameter, 148° spray angle.