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The modeling of transient phenomena occurring inside an automotive 3-way catalytic converter poses a significant challenge to the emissions control engineer. Since the significant progress that has been observed with steady-state models cannot be directly exploited in this direction, it is necessary to develop a fully transient model and computer code incorporating dynamic behaviour of the three way catalytic converter in a relatively simple and effective way. The Laboratory of Applied Thermodynamics (LAT), Aristotle University Thessaloniki, is cooperating with the Engine Direction of FIAT Research Center, in the development of a computer code fulfilling these objectives, within the framework of an EEC Brite EuRam cost shared project. The CRF and LAT modeling approaches, along with the underlying philosophy and experimental work, are presented in this paper.

The purpose of this paper is to investigate a new, universally applicable technique to protect the filter from overheating that could overcome the need for trap bypassing; namely, the trap protection by limiting A/F ratio during regeneration. The technique is supported by control of A/F ratio, leading to an indirect control of exhaust oxygen content and consequently trap regeneration rate. Realisation of the above-mentioned, very simple idea, so as to work effectively in the multitude of possible trap failure scenarios occuring during vehicle driving, is shown to be a fairly complicated task. The new method of trap protection, now being at the stage of initial investigations, is expected to lead to a safe and reliable system with wide applicability, without the need to bypass the trap at any circumstances. As such, it will also be attractive for passenger car applications, supported by the recent advances in wide application of electronic fuel control.

In view of recent and future US and european regulations the design optimization of 3-way catalytic converters (3WCC) should also account for catalyst durability. The purpose of this paper is to extend the authors' approach for 3WCC modeling and evaluation in the direction of covering some aspects of ageing behavior. After a brief examination of the commonly accepted ageing mechanisms, a new methodology for the assessment of catalyst durability is formulated. This methodology takes into account the effect of thermal loading, high-temperature oxidation and poisoning of the catalyst. Based on the approach presented, along with the 3WCC and other related models and computer codes already in-use by the authors, a comparative assesment of engine bench ageing cycles may be computationally supported. Correlation of vehicle ageing cycles with engine bench cycles may also be accomplished as illustrated by a case study.

The design of a diesel particulate trap system to fit a specific vehicular application requires significant expenditure, due to the high degree of interaction between the vehicle operation and trap behavior. The assistance of modeling in the design process is already well established. This paper presents the basic principles of a Computer Aided Engineering methodology aimed to assist the selection of the basic parameters of a Diesel Particulate Trap System by reducing the number of the necessary experimental tests. The computational modules currently supporting the CAE methodology are based on fundamental mathematical models, incorporating a small number of semi-empirical relations derived by experimental data on trap loading and catalytic regeneration, exhaust system heat transfer and trap backpressure effect on fuel consumption.