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Biofuel usage is increasingly expanding thanks to its significant contribution to a well-to-wheel (WTW) reduction of greenhouse gas (GHG) emissions. In addition, stringent emission standards make mandatory the use of Diesel Particulate Filter (DPF) for the particulate emissions control. The different physical properties and chemical composition of biofuels impact the overall engine behaviour. In particular, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value (LHV). More specifically, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value, respectively. The particle emissions, in fact, are lower mainly because of the higher oxygen content. Subsequently less frequent regenerations are required.

This paper reports results of an experimental investigation performed on a commercial diesel engine supplied with fuel blends having low cetane number to attain a simultaneous reduction in NOx and smoke emissions. Blends of 20% and 40% of n-butanol in conventional diesel fuel have been tested, comparing engine performance and emissions to diesel ones. Taking advantage of the fuel blend higher resistance to auto ignition, it was possible to extend the range in which a premixed combustion is achieved. This allowed to match the goal of a significant reduction in emissions without important penalties in fuel consumption. The experimental activity was carried on a turbocharged, water cooled, 4 cylinder common rail DI diesel engine. The engine equipment included an exhaust gas recirculation system controlled by an external driver, a piezo-quartz pressure transducer to detect the in-cylinder pressure signal and a current probe to acquire the energizing current to the injector.

In this work a detailed model to simulate the transient behavior of catalytic converters is presented. The model is able to predict the unsteady and reacting flows in the exhaust ducts, by solving the system of conservation equations of mass, momentum, energy and transport of reacting chemical species. The en-gine and the intake system have not been included in the simulation, imposing the measured values of mass flow, gas temperature and chemical composition as a boundary condition at the inlet of the exhaust system. A detailed analysis of the diffusion stage triggering is proposed along with simplifications of the physics, finalized to the reduction of the calculation time. Submodels for water condensation and its following evaporation on the monolith surface have been taken into account as well as oxygen storage promoted by ceria oxides.

A numerical investigation on a series of Diesel spray experiments in constant-volume vessels is proposed. Non reacting conditions were used to assess the spray models and to determine the grid size required to correctly predict the fuel-air mixture formation process. To this end, not only computed liquid and vapor penetrations were compared with experimental data, but also a detailed comparison between computed and experimental mixture fraction distributions was performed at different distances from the injector. Grid dependency was reduced by introducing an Adaptive Local Mesh Refinement technique (ALMR) with an arbitrary level of refinement. Once the capabilities of the current implemented spray models have been assessed, reacting conditions at different ambient densities and temperatures were considered. A Perfectly Stirred Reactor (PSR) combustion model, based on a direct integration of complex chemistry mechanisms over a homogenous cell, was adopted.

Mopeds are popular means of transportation, particularly in southern Europe and in eastern and southern Asia. The relative importance of their emissions increases in urban environments which host large fleets of mopeds. In Naples, for example, mopeds make a considerable contribution to HC emissions (about 53%), although the percentage of mopeds (12.4%) in the total circulating fleet is lower than that of other vehicle categories [1]. This study presents a method for analysing the influence of kinematic parameters on the emission factors of mopeds during the “cold-start” and “hot” phases of elementary kinematic sequences (speed-time profiles between two successive stops). These elementary sequences were obtained through appropriate fragmentation of complex urban driving cycles. In a second step, we show how to estimate, for the whole cycle, the duration of the cold phase and the relevant time-dependence function.

Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

The present paper describes some results of a research project aimed at studying the impact of alternative fuels blends on the emissions and fuel consumption of an Euro 5 automotive diesel engine. Two alternative fuels were chosen for the experiments: RME and GTL. The tests were done in the three most important operating conditions for the engine emission calibration. Moreover, the NOx-PM trade-off by means of EGR sweep was performed in the same operating conditions, in order to evaluate the engine EGR tolerability when burning low sooting fuels as the RME. The investigations put in evidence that the impact of the alternative fuels on modern diesel engines remains significant. This also depends on the interaction between the alternative fuel characteristics and the engine-management strategies, as described in detail in the paper.

The evaluation of vehicles real emissions circulating in urban areas is a basic activity for planning and management of implemented traffic measures aiming at emission control and air quality improvement. National, region, and city emission inventories require overall average emission estimation based on modeling technique with a few input parameters such as fleet composition and mission profile, represented by average speed. But in the field of emission modeling an important open issue is the very expensive costs of experimental campaigns needed to obtain driving cycle statistically representative of driving behavior, also if only in a specific link of a network. A possible approach to deal with this problem is represented by the use of traffic microscopic simulation models which are capable to simulate individual car motion on the basis of traffic conditions, road characteristics and management rules.

Although the application of cylinder pressure sensors to gain insight into the combustion process is not a novel topic itself, the recent availability of inexpensive in-cylinder pressure sensors has again prompted an upcoming interest for the utilization of the cylinder pressure signal within engine control and monitoring. Besides the use of the in-cylinder pressure signal for combustion analysis and control the information can also be used to determine related quantities in the exhaust or intake manifold. Within this work two different methods to estimate the pressure inside the exhaust manifold are proposed and compared. In contrary to first principle based approaches, which may require time extensive parameterization, alternative data driven approaches were pursued. In the first method a Principle Component Analysis (PCA) is applied to extract the cylinder pressure information and combined with a polynomial model approach.

High pressure diesel sprays were visualized under vaporizing and combusting conditions in a constant-volume combustion vessel. Near-simultaneous visualization of vapor and liquid phase fuel distribution were acquired using a hybrid shadowgraph/Mie-scattering imaging setup. This imaging technique used two pulsed LED's operating in an alternative manner to provide proper light sources for both shadowgraph and Mie scattering. In addition, combustion cases under the same ambient conditions were visualized through high-speed combustion luminosity measurement. Two single-hole diesel injectors with same nozzle diameters (100μm) but different k-factors (k0 and k1.5) were tested in this study. Detailed analysis based on spray penetration rate curves, rate of injection measurements, combustion indicators and 1D model comparison have been performed.

In the present paper, two different methodologies are adopted and critically integrated to analyze the knock behavior of a last generation small size spark ignition (SI) turbocharged VVA engine. Particularly, two full load operating points are selected, exhibiting relevant differences in terms of knock proximity. On one side, a knock investigation is carried out by means of an Auto-Regressive technique (AR model) to process experimental in-cylinder pressure signals. This mathematical procedure is used to estimate the statistical distribution of knocking cycles and provide a validation of the following 1D-3D knock investigations. On the other side, an integrated numerical approach is set up, based on the synergic use of 1D and 3D simulation tools. The 1D engine model is developed within the commercial software GT-Power™. It is used to provide time-varying boundary conditions (BCs) for the 3D code, Star-CD™.

Detailed chemistry and turbulence-chemistry interaction need to be properly taken into account for a realistic combustion simulation of IC engines where advanced combustion modes, multiple injections and stratified combustion involve a wide range of combustion regimes and require a proper description of several phenomena such as auto-ignition, flame stabilization, diffusive combustion and lean premixed flame propagation. To this end, different approaches are applied and the most used ones rely on the well-stirred reactor or flamelet assumption. However, well-mixed models do not describe correctly flame structure, while unsteady flamelet models cannot easily predict premixed flame propagation and triple flames. A possible alternative for them is represented by transported probability density functions (PDF) methods, which have been applied widely and effectively for modeling turbulent reacting flows under a wide range of combustion regimes.

The present paper reassumes the results of an experimental study focused on the effects of the nozzle injector's coking varying the flow number (FN); the performance and emissions of an automotive Euro5 diesel engine have been analyzed using diesel fuel. As the improvement of the diesel engine performance requires a continuous development of the injection system and in particular of the nozzle design, in the last years the general trend among OEMs is lowering nozzle flow number and, as a consequence, nozzle holes size. The study carried out moves from the consideration that a reduction of the nozzle holes diameter could increase the impact of their coking process. For this purpose, an experimental campaign has been realized, testing the engine in steady state in three partial load operating points, representative of the European homologation driving cycle, and in full load conditions.

In this work a multilevel CFD analysis have been applied for the design of an intake air-box with improved characteristics of noise reduction and fluid dynamic response. The approaches developed and applied for the optimization process range from the 1D to fully 3D CFD simulation, exploring hybrid approaches based on the integration of a 1D model with quasi-3D and 3D tools. In particular, the quasi-3D strategy is exploited to investigate several configurations, tailoring the best trade-off between noise abatement at frequencies below 1000 Hz and optimization of engine performances. Once the best configuration has been defined, the 1D-3D approach has been adopted to confirm the prediction carried out by means of the simplified approach, studying also the impact of the new configuration on the engine performances.

In this study, experiments were carried out in an optical single-cylinder Direct Injection Spark Ignition engine fuelled with n-butanol and gasoline, alternatively. The engine is equipped with the head of a commercial turbocharged engine with similar geometrical specifications (bore, stroke, compression ratio). The head has four valves and a centrally located spark device with surface charge ignition. A conventional elongated hollow Bowditch piston is used and an optical crown, accommodating fused-silica window, is screwed onto it. The injector is side mounted and features 6 holes oriented to guide the jets towards the piston crown. During the experimental activity, the injection pressure was maintained at 100 bar for all conditions; the injection timing and the number of injections were adjusted to investigate their influence on combustion and emissions.

In the next years, the upcoming emission legislations are expected to introduce further restrictions on the admittable level of pollutants from vehicles measured on homologation cycles and real drive tests. In this context, the strict control of pollutant emissions at the cold start will become a crucial point to comply with the new regulation standards. This will necessarily require the implementation of novel strategies to speed-up the light-off of the reactions occurring in the after-treatment system, since the cold start conditions are the most critical one for cumulative emissions. Among the different possible technological solutions, this paper focuses on the evaluation of the potential of a burner system, which is activated before the engine start. The hypothetical burner exploits the lean combustion of an air-gasoline mixture to generate a high temperature gas stream which is directed to the catalyst section promoting a fast heating of the substrate.

Methane abatement in the exhaust gas of natural gas engines is much more challenging in respect to the oxidation of other higher order hydrocarbons. Under steady state λ sweep, the methane conversion efficiency is high at exact stoichiometric, and decreases steeply under both slightly rich and slightly lean conditions. Transient lean to rich transitions can improve methane conversion at the rich side. Previous experimental work has attributed the enhanced methane conversion to activation of methane steam reforming. The steam reforming rate, however, attenuates over time and the methane conversion rate gradually converges to the low steady state values. In this work, a reactor model is established to predict steady state and transient transition characteristics of a three-way catalyst (TWC) mounted in the exhaust of a natural gas heavy-duty engine.

Modeling combustion of transportation fuels remains a difficult task due to the extremely large number of species constituting commercial gasoline and diesel. However, for this purpose, multi-component surrogate fuel models with a reduced number of key species and dedicated reaction subsets can be used to reproduce the physical and chemical traits of diesel and gasoline, also allowing to perform CFD calculations. Recently, a detailed surrogate fuel kinetic model, named C3 mechanism, was developed by merging high-fidelity sub-mechanisms from different research groups, i.e. C0-C4 chemistry (NUI Galway), linear C6-C7 and iso-octane chemistry (Lawrence Livermore National Laboratory), and monocyclic aromatic hydrocarbons (MAHs) and polycyclic aromatic hydrocarbons (PAHs) (ITV-RWTH Aachen and CRECK modelling Lab-Politecnico di Milano).

A growing number of electric vehicles (EV) and hybrid electric vehicles (HEV) in the present market depicts the rapid growing demand for energy storage systems. The battery’s main peculiarities must be the power density and reliability over time. The temperature strongly affects battery performance for low and high intensity. In particular, the management of the heat generated by the battery itself is one of the main aspects to handle to preserve the performance over time. The objective of this paper is to compare the surface temperature of the lithium-ion polymer battery at different discharging rates by infrared thermography. Thermal imaging is performed to detect the battery surface temperature distribution, focusing on its variation over time and the local inhomogeneity. Temperature measurements are then used to estimate the contributions of the different heat transfer mechanisms for the dissipation of the heat generated by the battery.

In recent years, the increase of gasoline fuel injection pressure is a way to improve thermal efficiency and lower engine-out emissions in GDI homogenous combustion concept. The challenge of controlling particulate formation as well in mass and number concentrations imposed by emissions regulations can be pursued improving the mixture preparation process and avoiding mixture inhomogeneity with ultra-high injection pressure values up to 100 MPa. The increase of the fuel injection pressure in GDI homogeneous systems meets the demand for increased injector static flow, while simultaneously improves the spray atomization and mixing characteristics with consequent better combustion performance. Few studies quantify the effects of high injection pressure on transient gasoline spray evolution. The aim of this work was to simulate with OpenFOAM the spray morphology of a commercial gasoline injected in a constant volume vessel by a prototypal GDI injector.