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Journal Article

Removal of NOx from Diesel Exhausts: The New “Enhanced NH3-SCR” Reaction

2010-04-12
2010-01-1181
Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.
Technical Paper

Modeling the Kinetic and Thermal Interaction of UWS Droplets Impinging on a Flat Plate at Different Exhaust Gas Conditions

2021-09-05
2021-24-0079
The selective catalytic reduction has seen widespread adoption as the best technology to reduce the NOx emissions from internal combustion engines, particularly for Diesels. This technology uses ammonia as a reducing agent, which is obtained injecting an ammonia carrier into the exhaust gas stream. The dosing of the ammonia carrier, usually AdBlue, is the major concern during the design and engine calibration phases, since the interaction between the injected liquid and the components of the exhaust system can lead to the undesired formation of solid deposits. To avoid this, the thermal and kinematic interaction between the spray and the components of the after treatment system (ATS) must be modeled accurately. In this work, the authors developed a Conjugate Heat Transfer (CHT) framework to model the kinetic and thermal interaction among the spray, the eventual liquid layer and the pipe walls.
Technical Paper

Numerical Investigation on GDI Spray under High Injection Pressure up to 100 MPa

2020-09-15
2020-01-2108
In recent years, the increase of gasoline fuel injection pressure is a way to improve thermal efficiency and lower engine-out emissions in GDI homogenous combustion concept. The challenge of controlling particulate formation as well in mass and number concentrations imposed by emissions regulations can be pursued improving the mixture preparation process and avoiding mixture inhomogeneity with ultra-high injection pressure values up to 100 MPa. The increase of the fuel injection pressure in GDI homogeneous systems meets the demand for increased injector static flow, while simultaneously improves the spray atomization and mixing characteristics with consequent better combustion performance. Few studies quantify the effects of high injection pressure on transient gasoline spray evolution. The aim of this work was to simulate with OpenFOAM the spray morphology of a commercial gasoline injected in a constant volume vessel by a prototypal GDI injector.
Journal Article

Fluid Dynamic Comparison of AdBlue Injectors for SCR Applications

2015-09-06
2015-24-2502
The injection process of urea-water solution (AdBlue) determines initial conditions for reactions and catalysis and is fundamentally responsible for optimal operation of selective catalytic reduction (SCR) systems. The spray characteristics of four, commercially available, injectors (one air-assisted and three pressure-driven with different nozzle-hole configurations) are investigated with non-intrusive measuring techniques. Injection occurred in the crossflow of a channel blowing preheated air in an exhaust duct similar configuration. The effect of several gas temperatures and flows on the spray propagation and entrainment has been extensively studied by shadow imaging. Shadow images, in addition, show that the spray of the pressure-driven injectors is only marginally affected by the gas crossflow. In contrast, the air assisted spray is strongly deflected by the gas, the effect increasing with increasing gas flow.
Journal Article

A 1D/Quasi-3D Coupled Model for the Simulation of I.C. Engines: Development and Application of an Automatic Cell-Network Generator

2017-03-28
2017-01-0514
Nowadays quasi-3D approaches are included in many commercial and research 1D numerical codes, in order to increase their simulation accuracy in presence of complex shape 3D volumes, e.g. plenums and silencers. In particular, these are regarded as valuable approaches for application during the design phase of an engine, for their capability of predicting non-planar waves motion and, on the other hand, for their low requirements in terms of computational runtime. However, the generation of a high-quality quasi-3D computational grid is not always straightforward, especially in case of complex elements, and can be a time-consuming operation, making the quasi-3D tool a less attractive option. In this work, a quasi-3D module has been implemented on the basis of the open-source CFD code OpenFOAM and coupled with the 1D code GASDYN.
Journal Article

A Progress Review on Soot Experiments and Modeling in the Engine Combustion Network (ECN)

2016-04-05
2016-01-0734
The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.
Technical Paper

Numerical Optimization of a SCR System Based on the Injection of Pure Gaseous Ammonia for the NOx Reduction in Light-Duty Diesel Engines

2020-04-14
2020-01-0356
Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.
Journal Article

The NH3 Inhibition Effect in the Standard SCR Reaction over a Commercial Fe-zeolite Catalyst for Diesel Exhaust Aftertreatment: An Experimental and Modeling Study

2011-04-12
2011-01-1319
Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.
Journal Article

Experimental Characterization of High-Pressure Impinging Sprays for CFD Modeling of GDI Engines

2011-04-12
2011-01-0685
Today, Direct-Injection systems are widely used on Spark-Ignition engines in combination with turbo-charging to reduce the fuel-consumption and the knock risks. In particular, the spread of Gasoline Direct Injection (GDI) systems is mainly related to the use of new generations of multi-hole, high-pressure injectors whose characteristics are quite different with respect to the hollow-cone, low-pressure injectors adopted in the last decade. This paper presents the results of an experimental campaign conducted on the spray produced by a GDI six-holes injector into a constant volume vessel with optical access. The vessel was filled with air at atmospheric pressure. Different operating conditions were considered for an injection pressure ranging from 3 to 20 MPa. For each operating condition, spray images were acquired by a CCD camera and then post processed to evaluate the spray penetration and cone angles.
Journal Article

Improving the Simulation of the Acoustic Performance of Complex Silencers for ICE by a Multi-Dimensional Non-Linear Approach

2012-04-16
2012-01-0828
In this paper a three-dimensional time-domain CFD approach has been employed to predict and analyze the acoustic attenuation performance of complex perforated muffler geometries, where strong 3D effects limit the validity of the use of one-dimensional models. A pressure pulse has been imposed at the inlet to excite the wave motion, while unsteady flow computation have been performed to acquire the time histories of the pressures upstream and downstream of the silencer. Pressures in the time domain have been then transformed to acoustic pressures in the frequency domain, to predict the transmission loss.
Journal Article

A Comparison of Experimental and Modeled Velocity in Gasoline Direct-Injection Sprays with Plume Interaction and Collapse

2017-03-28
2017-01-0837
Modeling plume interaction and collapse for direct-injection gasoline sprays is important because of its impact on fuel-air mixing and engine performance. Nevertheless, the aerodynamic interaction between plumes and the complicated two-phase coupling of the evaporating spray has shown to be notoriously difficult to predict. With the availability of high-speed (100 kHz) Particle Image Velocimetry (PIV) experimental data, we compare velocity field predictions between plumes to observe the full temporal evolution leading up to plume merging and complete spray collapse. The target “Spray G” operating conditions of the Engine Combustion Network (ECN) is the focus of the work, including parametric variations in ambient gas temperature. We apply both LES and RANS spray models in different CFD platforms, outlining features of the spray that are most critical to model in order to predict the correct aerodynamics and fuel-air mixing.
Technical Paper

Test-Model Correlation in Spacecraft Thermal Control by Means of MonteCarlo Techniques

2007-07-09
2007-01-3120
In the paper some methods are presented, with the corresponding practical examples, related to MonteCarlo (MC) techniques for thermal model/test correlation purposes. The MonteCarlo techniques applied to model correlation are intended to be used as an alternative to empirical ‘manual’ correlation techniques, gradients methods, matrix methods based on least square fit minimization. First of all, Design Of Experiments (DoE) tools are used to determine the model response to uncertain parameters and the confidence level of such a response. A sensitivity map is built, allowing the design of the test to maximize the response of the system to the uncertain parameters. Techniques derived from the extreme statistics are used to extrapolate data beyond test limits, with a sufficient confidence in the queue behaviour.
Technical Paper

Preliminary Design of a Bio-Regenerative ECLSS Technological Demo Plant for Air and Water Management

2008-06-29
2008-01-2013
Future human exploration roadmaps involve the development of temporary or permanent outposts on Moon and Mars. The capability of providing astronauts with proper conditions for living and working in extraterrestrial environments is therefore a key issue for the sustainability of those roadmaps, and closed-loop Environment Control and Life Support Systems (ECLSSs) and bio-regenerative plants represent the necessary evolution of current technologies for complying with the challenging requirements imposed. This paper presents the architectural design of a terrestrial plant to be exploited to test and validate air and water management technologies for a biological life support system in a closed environment. The plant includes a crew area and a plant growth area. These two spaces can be considered as either a unique volume or two separated environments with reduced contact, e.g. for plant harvesting or other up-keeping activities.
Technical Paper

Experimental and Numerical Analyses for the Characterization of the Cyclic Dispersion and Knock Occurrence in a Small-Size SI Engine

2010-09-28
2010-32-0069
In this paper, an experimental and numerical analysis of combustion process and knock occurrence in a small displacement spark-ignition engine is presented. A wide experimental campaign is preliminarily carried out in order to fully characterize the engine behavior in different operating conditions. In particular, the acquisition of a large number of consecutive pressure cycle is realized to analyze the Cyclic Variability (CV) effects in terms of Indicated Mean Effective Pressure (IMEP) Coefficient of Variation (CoV). The spark advance is also changed up to incipient knocking conditions, basing on a proper definition of a knock index. The latter is estimated through the decomposition and the FFT analysis of the instantaneous pressure cycles. Contemporary, a quasi-dimensional combustion and knock model, included within a whole engine one-dimensional (1D) modeling framework, are developed. Combustion and knock models are extended to include the CV effects, too.
Technical Paper

Effect of the air density on the evolution and mixing properties of a GDI swirled spray

2001-09-23
2001-24-0048
A swirl injector for GDI application was used to inject an iso-octane spray in a quiescent chamber, to study the effect of the air density on the spray behavior. Stroboscopic images are recorded at different delays from the injection trigger to study the spray shape and structure. The temporal evolution of different spray parameters, length, width, angle, volume, instantaneous global air-fuel ratio, is calculated from the images. The effect of the increasing air density is to shorten the time and length scale of the spray evolution.
Technical Paper

Quantitative Analysis of Low Pressure-Driven Spray Mass Distribution and Liquid Entrainment for SCR Application through a Mechanical Patternator

2017-03-28
2017-01-0965
The application of liquid aqueous Urea Solution (AUS) as reductant in SCR exhaust after-treatment systems is now a commonly accepted industry standard. Unfortunately, less acceptable are the associated difficulties caused by incomplete decomposition of the liquid, resulting in solid deposits which accumulate in the exhaust pipe downstream of the dosing components. The correct prediction of the spray pattern and, therefore, the spray impact on the walls is a key feature for the system optimization. A mechanical patternator, designed on the basis of CFD performance assessment, involving a Lagrangian representation of the dispersed liquid fully coupled with a 3D Eulerian description of the carrier phase, has been built and used to measure the spray mass distribution.
Technical Paper

Evolution of the Ride Comfort of Alfa Romeo Cars since 1955 until 2005

2017-03-28
2017-01-1484
The ride comfort of three Alfa Romeo cars, namely Giulietta (1955), Alfetta (1972) and 159 (2005) has been assessed both objectively and subjectively. The three cars belong to the same market segment. The aim is to let young engineers or graduate students understand how technology has evolved and eventually learn a lesson from the assessed trend. A number of cleats have been fixed at the ground and the three cars have traversed such uneven surface. The objective assessment of the ride comfort has been performed by means of accelerometers fixed at the seat rails, additionally a special dummy developed at Politecnico di Milano has been employed. The subjective assessment has been performed by a panel of passengers. The match between objective and subjective ratings is very good. Simple mathematical models have been employed to establish a (successful) comparison between experimental and computational results. The ride comfort differs substantially among the cars.
Technical Paper

A Review of the State of the Art of Electric Traction Motors Cooling Techniques

2018-04-03
2018-01-0057
This paper provides a review on state-of-art modern cooling systems employed for thermal cooling of electric motors for vehicle applications. In recent years, the pursue of a more sustainable and ecofriendly mobility has pushed the research towards the development of electric vehicle powertrain systems. Besides the evident advantages of the adoption of electric traction systems in terms of pollution and efficiency, the need of an effective cooling system for the electric machine components gained more and more importance in order to maintain high efficiency and ensure high durability. In fact, it is known that high temperatures can be harmful for the electric motor: besides the evident damages for mechanical parts, the influence on the permanent magnet properties is not negligible [1] [2]. In this fast-evolving environment, different solutions for the thermal problem have been researched and adopted, each one with its own pros and cons.
Technical Paper

Reduced Kinetic Mechanisms for Diesel Spray Combustion Simulations

2013-09-08
2013-24-0014
Detailed chemistry represents a fundamental pre-requisite for a realistic simulation of combustion process in Diesel engines to properly reproduce ignition delay and flame structure (lift-off and soot precursors) in a wide range of operating conditions. In this work, the authors developed reduced mechanisms for n-dodecane starting from the comprehensive kinetic mechanism developed at Politecnico di Milano, well validated and tested in a wide range of operating conditions [1]. An algorithm combining Sensitivity and Flux Analysis was employed for the present skeletal reduction. The size of the mechanisms can be limited to less than 100 species and incorporates the most important details of low-temperature kinetics for a proper prediction of the ignition delay. Furthermore, the high-temperature chemistry is also properly described both in terms of reactivity and species formation, including unsaturated compounds such as acetylene, whose concentration controls soot formation.
Technical Paper

Modeling of Pressure Wave Reflection from Open-Ends in I.C.E. Duct Systems

2010-04-12
2010-01-1051
In the most elementary treatment of plane-wave reflection at the open end of a duct system, it is often assumed that the ends are pressure nodes. This implies that pressure is assumed as a constant at the open end termination and that steady flow boundary condition is supposed as instantaneously established. While this simplifying assumption seems reasonable, it does not consider any radiation of acoustic energy from the duct into the surrounding free space; hence, an error in the estimation of the effects of the flow on the acoustical response of an open-end duct occurs. If radiation is accounted, a complicated three-dimensional wave pattern near the duct end is established, which tends to readjust the exit pressure to its steady-flow level. This adjustment process is continually modified by further incident waves, so that the effective instantaneous boundary conditions which determine the reflected waves depend on the flow history.
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