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The main purpose of this study is to investigate the effects of exhaust gases on different combustion modes in DI, Direct Injection, compression ignited engines in terms of combustion efficiency and emission formations. The conventional parametric Φ -T (Equivalence Ratio-Temperature) emission map analysis has been extended by constructing the transient maps for different species characterizing the combustion and emission formation processes. The results of the analysis prove the efficiency of different combustion modes when EGR loads and injection scenarios.

A novel concept of combined hydrogen production and power generation system based on the combustion of aluminum in water is explored. The energy conversion system proposed is potentially able to provide four different energy sources, such us pressurized hydrogen, high temperature steam, heat, and work at the crankshaft on demand, as well as to fully comply with the environment sustainability requirements. Once aluminum oxide layer is removed, the pure aluminum can react with water producing alumina and hydrogen while releasing a significant amount of energy. Thus, the hydrogen can be stored for further use and the steam can be employed for energy generation or work production in a supplementary power system. The process is proved to be self-sustained and to provide a remarkable amount of energy available as work or hydrogen.

Both spray-wall and spray-spray interactions in direct injection diesel engines have been found to influence the rate of heat release and the formation of emissions. Simulations of these phenomena for diesel sprays need to be validated, and an issue is investigating what kind of fuels can be used in both experiments and spray calculations. The objective of this work is to compare numerical simulations with experimental data of sprays impinging on a temperature controlled wall with respect to spray characteristics and heat transfer. The numerical simulations were made using the STAR-CD and KIVA-3V codes. The CFD simulations accounted for the actual spray chamber geometry and operating conditions used in the experiments. Particular attention was paid to the fuel used for the simulations.

Computational simulations of the spray combustion and emissions formation processes in a heavy-duty DI diesel engine and in a small-bore DI diesel engine with a complicated injection schedule were performed by using the modified KIVA3V, rel. 2 code. Some initial parameter sets varying engine operating conditions, such as injection pressure, injector nozzle diameter, EGR load, were examined in order to evaluate their effects on the engine performance. Full-scale combustion chamber representations on 360-deg, Cartesian and polar, multiblock meshes with a different number of sprays have been used in the modelling unlike the conventional approach based on polar sector meshes covering the region around one fuel spray. The spray combustion phenomena were simulated using the detailed chemical mechanism for diesel fuel surrogate (69 species and 306 reactions).

Oxygen enriched air (EA) is a well known industrial mixture in which the content of oxygen is higher respect the atmospheric one, in the range 22-35%. Oxygen EA can be obtained by desorption from water, taking advantage of the higher oxygen solubility in water compared to the nitrogen one, since the Henry constants of this two gases are different. The production of EA by this new approach was already studied by experimental runs and theoretical considerations. New results using salt water are reported. EA promoted combustion is considered as one of the most interesting technologies to improve the performance in diesel engines and to simultaneously control and reduce pollution. This paper explores, by means of 3-dimensional computational fluid dynamics simulations, the effects of EA on the performance and exhaust emissions of a high-speed direct-injection diesel engine.