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Journal Article

Effects of Fuel Type on Dual SCR Aftertreatment for Lean NOx Reduction

2009-11-02
2009-01-2818
Global demand for alternative fuels to combat rising energy costs has sparked a renewed interest in catalysts that can effectively remediate NOx emissions resulting from combustion of a range of HC based fuels. Because many of these new engine technologies rely on lean operating environments to produce efficient power, the resulting emissions are also present in a lean atmosphere. While HCs are easily controlled in such environments, achieving high NOx conversion to N2 has continued to elude fully satisfactory solution. Until recently, most approaches have relied on catalysts with precious metals to either store NOx and subsequently release it as N2 under rich conditions, or use NH3 SCR catalysts with urea injection to reduce NOx under lean conditions. However, new improvements in Ag based technologies also look very promising for NOx reduction in lean environments.
Journal Article

Dual SCR Aftertreatment for Lean NOx Reduction

2009-04-20
2009-01-0277
Low-cost lean NOx aftertreatment is one of the main challenges facing high-efficiency gasoline and diesel engines operating with lean mixtures. While there are many candidate technologies, they all offer tradeoffs. We have investigated a multi-component Dual SCR aftertreatment system that is capable of obtaining NOx reduction efficiencies of greater than 90% under lean conditions, without the use of precious metals or urea injection into the exhaust. The Dual SCR approach here uses an Ag HC-SCR catalyst followed by an NH3-SCR catalyst. In bench reactor studies from 150 °C to 500 °C, we have found, for modest C/N ratios, that NOx reacts over the first catalyst to predominantly form nitrogen. In addition, it also forms ammonia in sufficient quantities to react on the second NH3-SCR catalyst to improve system performance. The operational window and the formation of NH3 are improved in the presence of small quantities of hydrogen (0.1–1.0%).
Technical Paper

Controlling Induction System Deposits in Flexible Fuel Vehicles Operating on E85

2007-10-29
2007-01-4071
With the wider use of biofuels in the marketplace, a program was conducted to study the deposit forming tendencies and performance of E85 (85% denatured ethanol and 15% gasoline) in a modern Flexible Fuel Vehicle (FFV). The test vehicle for this program was a 2006 General Motors Chevrolet Impala FFV equipped with a 3.5 liter V-6 powertrain. A series of 5,000 mile Chassis Dynamometer (CD) Intake Valve Deposits (IVD) and performance tests were conducted while operating the FFV on conventional (E0) regular unleaded gasoline and E85 to determine the deposit forming tendencies of both fuels. E85 test fuels were found to generate significantly higher levels of IVD than would have been predicted from the base gasoline component alone. The effects on the weight and composition of IVD due to a corrosion inhibitor and sulfates that were indigenous to one of the ethanols were also studied.
Technical Paper

Non-Intrusive Engine Speed Sensor

2007-04-16
2007-01-0960
In the field of vehicle diagnostics accurate instantaneous engine speed information enables the detection and diagnosis of many engine problems, even subtle ones. Currently, there is a limited choice in the ways of obtaining such information. For example, it is known that one can tap into the crank sensor wiring, or use a separate, intrusive method, such as mounting a sensor in the bell housing to sense the rotation of the ring gear. However, the shortcomings of these approaches are locating and gaining access to the crank sensor connector, the location of which varies from vehicle to vehicle. Thus, authors proposed a novel, robust and manufacturing friendly speed sensor. The concept is based on the Villari effect. The sensor, which is attached to the front end of the engine crankshaft, consists of a coil of magnetostrictive wire supplied with AC current. During engine rotation the magnetostrictive wire become stressed due to centrifugal force.
Technical Paper

Impact of Biodiesel Emission Products from a Multi-Cylinder Direct Injection Diesel Engine on Particulate Filter Performance

2009-04-20
2009-01-1184
As diesel emission regulations continue to increase, the use of exhaust aftertreatment systems containing, for example the diesel oxidation catalyst (DOC) and diesel particulate filter (DPF) will become necessary in order to meet these stringent emission requirements. The addition of a DOC and DPF in conjunction with utilizing biodiesel fuels requires extensive research to study the implications that biodiesel blends have on emissions as well as to examine the effect on aftertreatment devices. The proceeding work discusses results from a 2006 VM Motori four-cylinder 2.8L direct injection diesel engine coupled with a diesel oxidation catalyst and catalyzed diesel particulate filter. Tests were done using ultra low sulfur diesel fuel blended with 20% choice white grease biodiesel fuel to evaluate the effects of biodiesel emission products on the performance and effectiveness of the aftertreatment devices and the effect of low temperature combustion modes.
Technical Paper

A Comparative Study of the Production Applications of Hybrid Electric Powertrains

2003-06-23
2003-01-2307
In this paper, a comparative study of the production applications of hybrid electric powertrains is presented. Vehicles studied include the Toyota Prius, Honda Insight, Toyota Estima, Toyota Crown, Honda Civic Hybrid, and Nissan Tino. The upcoming Ford Escape Hybrid and General Motors Parallel Hybrid Truck (PHT) will also be included, although advance information is limited. The goal of this paper is to look at what hybrid drivetrain architectures have actually been selected for production and what are the underlying details of these drivetrains. Since hybridizing a powertrain involves significant changes, the powertrain architectures are presented in diagram form, with analysis as to the similarities and advantages represented in these architectures. The specific hybrid functions used to save fuel are discussed. Peak power-to-weight ratio and degree of hybridization are plotted for the vehicles. System voltage versus electric power level are also plotted and analyzed.
Technical Paper

Combustion Assisted Belt-Cranking of a V-8 Engine at 12-Volts

2004-03-08
2004-01-0569
Implementation of engine turnoff at idle is desirable to gain improvements in vehicle fuel economy. There are a number of alternatives for implementation of the restarting function, including the existing cranking motor, a 12V or 36V belt-starter, a crankshaft integrated-starter-generator (ISG), and other, more complex hybrid powertrain architectures. Of these options, the 12V belt-alternator-starter (BAS) offers strong potential for fast, quiet starting at a lower system cost and complexity than higher-power 36V alternatives. Two challenges are 1) the need to accelerate a large engine to idle speed quickly, and 2) dynamic torque control during the start for smoothness. In the absence of a higher power electrical machine to accomplish these tasks, combustion-assisted starting has been studied as a potential method of aiding a 12V accessory drive belt-alternator-starter in the starting process on larger engines.
Technical Paper

Logistics and Capability Implications of a Bradley Fighting Vehicle with a Fuel Cell Auxiliary Power Unit

2004-03-08
2004-01-1586
Modern military ground vehicles are dependent not only on armor and munitions, but also on their electronic equipment. Advances in battlefield sensing, targeting, and communications devices have resulted in military vehicles with a wide array of electrical and electronic loads requiring power. These vehicles are typically designed to supply this power via a main internal combustion engine outfitted with a generator. Batteries are also incorporated to allow power to be supplied for a limited time when the engine is off. It is desirable to use a subset of the battlefield electronics in the vehicle while the engine is off, in a mode called “silent watch.” Operating time in this mode is limited, however, by battery capacity unless an auxiliary power unit (APU) is used or the main engines are restarted.
Technical Paper

Low Volatility Fuel Delivery Control during Cold Engine Starts

2005-04-11
2005-01-0639
The intensity of a combustion flame ionization current signal (ionsense) can be used to monitor and control combustion in individual cylinders during a cold engine start. The rapid detection of poor or absence of combustion can be used to determine fuel delivery corrections that may prevent engine stalls. With the ionsense cold start control active, no start failures were recorded even when the initially (prior to ionsense correction) commanded fueling had failed to produce a combustible mixture. This new dimension in fuel control allows for leaner cold start calibrations that would still be robust against the possible use of low volatility gasoline. Consequently, when California Phase 2 fuel is used, cold start hydrocarbon emissions could be lowered without the risk of an engine stall if the appropriate fuel is replaced with a less volatile one.
Technical Paper

The Effectiveness of Oxygen in Preventing Embrittlement in Air Bag Inflators Containing Gaseous Hydrogen

2006-04-03
2006-01-1188
This study examines the effectiveness of gaseous oxygen at preventing embrittlement in steel associated with exposure to gaseous hydrogen under static loading conditions. Notched C-ring samples machined from 4340 steel and heat treated to HRC 51-53 were used to test the neutrality of an oxygen-hydrogen gas mixture similar to that which may be used as a generant in an air bag inflator. The 29 percent oxygen to hydrogen gas ratio of the gas mixture was found to be sufficient to protect the steel from hydrogen embrittlement under static loading conditions. This would indicate that any steel with a hardness of HRC 51 or lower would be safe to use in gas-based air bag inflators containing a oxygen to hydrogen gas ratio of 29 percent or higher.
Technical Paper

A Systematic Experimental Investigation of Pd-Based Light-Off Catalysts

2005-10-24
2005-01-3848
Close-coupled or manifold catalysts have been extensively employed to reduce emissions during cold start by achieving quick catalyst light-off. These catalysts must have good thermal durability, high intrinsic light-off activity and high HC/CO/NOx conversions at high temperature and flow conditions. A number of studies have been dedicated to engine control, manifold design and converter optimization to reduce cold start emissions. The current paper focuses on the effect of catalyst design parameters and their performance response to different engine operating conditions. Key design parameters such as catalyst formulation (CeO2 vs. non CeO2), precious metal loading and composition (Pd vs. Pd/Rh), washcoat loading, catalyst thermal mass, substrate properties and key application (in use) parameters such as catalyst aging, exhaust A/F ratio, A/F ratio modulation, exhaust temperature, temperature rise rate and exhaust flow rate were studied on engine dynamometers in a systematic manner.
Technical Paper

DOE Guidelines on Hydrogen Safety

2005-04-11
2005-01-0010
Hydrogen is the most plentiful gas in the universe. However hydrogen never occurs naturally, always combines with other elements such as oxygen and carbon [1]. Hydrogen is the ultimate clean energy carrier once it is separated from other elements [11]. Moreover hydrogen can easily be generated from renewable energy sources. Hydrogen is also nonpolluting, and forms water as a harmless byproduct during the oxidation process. Safe practices in the production, storage, distribution, and use of hydrogen are essential components of a hydrogen economy [2]. A catastrophic failure in any hydrogen project could irreparably damage the entire transition strategy. The safety program element delineates the steps that the hydrogen, fuel cells & infrastructure technologies program shall ensure that all projects are performed in a safe manner.
Technical Paper

E-85 Fuel Corrosivity: Effects on Port Fuel Injector Durability Performance

2007-10-29
2007-01-4072
A study was conducted to investigate the effects of commercial E-85 fuel properties on Port Fuel Injector (PFI) durability performance. E-85 corrosivity, not lubricity, was identified as the primary property affecting injector performance. Relatively high levels of water, chloride and organic acid contamination, detected in commercial E-85 fuels sampled in the U.S. in 2006, were the focus of the study. Analysis results and analytical techniques for determining contaminant levels in and corrosivity of commercial E-85 fuels are discussed. Studies were conducted with E-85 fuels formulated to represent worst-case field fuels. In addition to contamination with water, chloride and organic acids, fuels with various levels of a typical ethanol corrosion inhibitor were tested in the laboratory to measure the effects on E-85 corrosivity. The effects of these E-85 contaminants on injector durability performance were also evaluated.
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