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A study was conducted to investigate the effects of commercial E-85 fuel properties on Port Fuel Injector (PFI) durability performance. E-85 corrosivity, not lubricity, was identified as the primary property affecting injector performance. Relatively high levels of water, chloride and organic acid contamination, detected in commercial E-85 fuels sampled in the U.S. in 2006, were the focus of the study. Analysis results and analytical techniques for determining contaminant levels in and corrosivity of commercial E-85 fuels are discussed. Studies were conducted with E-85 fuels formulated to represent worst-case field fuels. In addition to contamination with water, chloride and organic acids, fuels with various levels of a typical ethanol corrosion inhibitor were tested in the laboratory to measure the effects on E-85 corrosivity. The effects of these E-85 contaminants on injector durability performance were also evaluated.

An HPLC (High Performance Liquid Chromatography) method to measure the concentration of six organic acids in E-85 fuel has been developed. A three point calibration curve is established using standard solutions of the following organic acids: formic acid, acetic acid, propionic acid, butyric acid, glycolic acid and citric acid. An internal standard (maleic acid) is used to monitor HPLC system suitability and peak retention time stability. The method utilizes UV detection at 210 nm to detect and quantify the levels of each acid in E-85 fuel. Test results from nine commercially available E-85 fuel samples are reported. Analytical method validation was achieved by performing and confirming system suitability or injection repeatability (percent relative standard deviation ≤ 3%), calibration curve linearity (R2 ≥ 0.999), analysis repeatability (standard deviation < 1 mg/L) and recovery (percent recovery 91 - 102%).