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SCR Deactivation Kinetics for Model-Based Control and Accelerated Aging Applications

2012-06-18
This paper forms the third of a series and presents results obtained during the testing and development phase of a dedicated range extender engine designed for use in a compact class vehicle. The first paper in this series used real world drive logs to identify usage patterns of such vehicles and a driveline model was used to determine the power output requirements of a range extender engine for this application. The second paper presented the results of a design study. Key attributes for the engine were identified, these being minimum package volume, low weight, low cost, and good NVH. A description of the selection process for identifying the appropriate engine technology to satisfy these attributes was given and the resulting design highlights were described. The paper concluded with a presentation of the resulting specification and design highlights of the engine. This paper will present the resulting engine performance characteristics.
Journal Article

Multi-Vehicle Evaluation of Gasoline Additive Packages: A Fourth Generation Protocol for the Assessment of Intake System Deposit Removal

2009-11-02
2009-01-2635
Building on two decades of expertise, a fourth generation fleet test protocol is presented for assessing the response of engine performance to gasoline additive treatment. In this case, the ability of additives to remove pre-existing deposit from the intake systems of port fuel injected vehicles has been examined. The protocol is capable of identifying real benefits under realistic market conditions, isolating fuel performance from other effects thereby allowing a direct comparison between different fuels. It is cost efficient and robust to unplanned incidents. The new protocol has been applied to the development of a candidate fuel additive package for the North American market. A vehicle fleet of 5 quadruplets (5 sets of 4 matched vehicles, each set of a different model) was tested twice, assessing the intake valve clean-up performance of 3 test fuels relative to a control fuel.
Journal Article

Performance and Emissions of Diesel and Alternative Diesel Fuels in a Heavy-duty Industry-Standard Older Engine

2010-10-25
2010-01-2281
Conventional diesel fuel has been in the market for decades and used successfully to run diesel engines of all sizes in many applications. In order to reduce emissions and to foster energy source diversity, new fuels such as alternative and renewable, as well as new fuel formulations have entered the market. These include biodiesel, gas-to-liquid, and alternative formulations by states such as California. Performance variations in fuel economy, emissions, and compatibility for these fuels have been evaluated and debated. In some cases contradictory views have surfaced. “Sustainable”, “Renewable”, and “Clean” designations have been interchanged. Adding to the confusion, results from one fuel in one type of engine such as an older heavy-duty engine, is at times compared to that of another type such as a modern light-duty. This study was an attempt to compare the performance of several fuels in an identical environment, using the same engine, for direct comparison.
Journal Article

1000-Hour Durability Evaluation of a Prototype 2007 Diesel Engine with Aftertreatment Using B20 Biodiesel Fuel

2009-11-02
2009-01-2803
A prototype 2007 ISL Cummins diesel engine equipped with a diesel oxidation catalyst (DOC), diesel particle filter (DPF), variable geometry turbocharger (VGT), and cooled exhaust gas recirculation (EGR) was tested at Southwest Research Institute (SwRI) under a high-load accelerated durability cycle for 1000 hours with B20 soy-based biodiesel blends and ultra-low sulfur diesel (ULSD) fuel to determine the impact of B20 on engine durability, performance, emissions, and fuel consumption. At the completion of the 1000-hour test, a thorough engine teardown evaluation of the overhead, power transfer, cylinder, cooling, lube, air handling, gaskets, aftertreatment, and fuel system parts was performed. The engine operated successfully with no biodiesel-related failures. Results indicate that engine performance was essentially the same when tested at 125 and 1000 hours of accumulated durability operation.
Journal Article

The Effect of Fuel Composition on Performance and Emissions of a Variety of Natural Gas Engines

2010-05-05
2010-01-1476
Work was performed to determine the feasibility of operating heavy-duty natural gas engines over a wide range of fuel compositions by evaluating engine performance and emission levels. Heavy-duty compressed natural gas engines from various engine manufacturers, spanning a range of model years and technologies, were evaluated using a diversity of fuel blends. Performance and regulated emission levels from these engines were evaluated using natural gas fuel blends with varying methane number (MN) and Wobbe Index in a dynamometer test cell. Eight natural gas blends were tested with each engine, and ranged from MN 75 to MN 100. Test engines included a 2007 model year Cummins ISL G, a 2006 model year Cummins C Gas Plus, a 2005 model year John Deere 6081H, a 1998 model year Cummins C Gas, and a 1999 model year Detroit Diesel Series 50G TK. All engines used lean-burn technology, except for the ISL G, which was a stoichiometric engine.
Journal Article

Effects of EGR Dilution and Fuels on Spark Plug Temperatures in Gasoline Engines

2013-04-08
2013-01-1632
The addition of exhaust gas recirculation (EGR) has demonstrated the potential to significantly improve engine efficiency by allowing high CR operation due to a reduction in knock tendency, heat transfer, and pumping losses. In addition, EGR also reduces the engine-out emission of nitrogen oxides, particulates, and carbon monoxide while further improving efficiency at stoichiometric air/fuel ratios. However, improvements in efficiency through enhanced combustion phasing at high compression ratios can result in a significant increase in cylinder pressure. As cylinder pressure and temperature are both important parameters for estimating the durability requirements of the engine - in effect specifying the material and engineering required for the head and block - the impact of EGR on surface temperatures, when combined with the cylinder pressure data, will provide an important understanding of the design requirements for future cylinder heads.
Journal Article

Simulation of Organic Rankine Cycle Electric Power Generation from Light-Duty Spark Ignition and Diesel Engine Exhaust Flows

2013-04-08
2013-01-1644
The performance of an organic Rankine cycle (ORC) used to recover waste heat from the exhaust of a diesel and a spark ignition engine for electric power generation was modeled. The design elements of the ORC incorporated into the thermodynamic model were based on an experimental study performed at Oak Ridge National Laboratory in which a regenerative organic Rankine cycle system was designed, assembled and integrated into the exhaust of a 1.9 liter 4-cylinder automotive turbo-diesel. This engine was operated at a single fixed-load point at which Rankine cycle state point temperatures as well as the electrical power output of an electric generator coupled to a turbine that expanded R245fa refrigerant were measured. These data were used for model calibration.
Journal Article

LPL EGR and D-EGR® Engine Concept Comparison Part 2: High Load Operation

2015-04-14
2015-01-0781
The ongoing pursuit of improved engine efficiency and emissions is driving gasoline low-pressure loop EGR systems into production around the globe. The Dedicated EGR (D-EGR®) engine was developed to minimize some of the challenges of cooled EGR while maintaining its advantages. The D-EGR engine is a high efficiency, low emissions internal combustion engine for automotive and off-highway applications. The core of the engine development focused on a unique concept that combines the efficiency improvements associated with recirculated exhaust gas and the efficiency improvements associated with fuel reformation. To outline the differences of the new engine concept with a conventional LPL EGR setup, a turbocharged 2.0 L PFI engine was modified to operate in both modes. The second part of the cooled EGR engine concept comparison investigates efficiency, knock resistance, combustion stability, and maximum load potential at high load conditions.
Journal Article

Potential and Challenges for a Water-Gas-Shift Catalyst as a Combustion Promoter on a D-EGR® Engine

2015-04-14
2015-01-0784
In light of the increasingly stringent efficiency and emissions requirements, several new engine technologies are currently under investigation. One of these new concepts is the Dedicated EGR (D-EGR®) engine. The concept utilizes fuel reforming and high levels of recirculated exhaust gas (EGR) to achieve very high levels of thermal efficiency. While the positive impact of reformate, in particular hydrogen, on gasoline engine performance has been widely documented, the on-board reforming process and / or storage of H2 remains challenging. The Water-Gas-Shift (WGS) reaction is well known and has been used successfully for many years in the industry to produce hydrogen from the reactants water vapor and carbon monoxide. For this study, prototype WGS catalysts were installed in the exhaust tract of the dedicated cylinder of a turbocharged 2.0 L in-line four cylinder MPI engine. The potential of increased H2 production in a D-EGR engine was evaluated through the use of these catalysts.
Journal Article

Advanced Ignition Systems Evaluations for High-Dilution SI Engines

2014-10-13
2014-01-2625
A series of ignition systems were evaluated for their suitability for high-EGR SI engine applications. Testing was performed in a constant-volume combustion chamber and in a single-cylinder research engine, with EGR rates of up to 40% evaluated. All of the evaluated systems were able to initiate combustion at a simulated 20% EGR level, but not all of the resulting combustion rates were adequate for stable engine operation. High energy spark discharge systems were better, and could ignite a flame at up to 40% simulated EGR, though again the combustion rates were slow relative to that required for stable engine performance. The most effective systems for stable combustion at high EGR rates were systems which created a large effective flame kernel and/or a long kernel lifetime, such as a torch-style prechamber spark plug or a corona discharge igniter.
Technical Paper

Combination of Mixed Metal Oxides with Cu-Zeolite for Enhanced Soot Oxidation on an SCRoF

2021-09-05
2021-24-0071
A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.
Journal Article

Medium-Duty Vehicle Fuel Saving Technology Analysis to Support Phase 2 Regulations

2015-09-29
2015-01-2769
This paper presents the results of engine and vehicle simulation modeling for a wide variety of individual technologies and technology packages applied to two medium-duty vocational vehicles. Simulation modeling was first conducted on one diesel and two gasoline medium-duty engines. Engine technologies were then applied to the baseline engines. The resulting fuel consumption maps were run over a range of vehicle duty cycles and payloads in the vehicle simulation model. Results were reported for both individual engine technologies and combinations or packages of technologies. Two vehicles, a Kenworth T270 box delivery truck and a Ford F-650 tow truck were evaluated. Once the baseline vehicle models were developed, vehicle technologies were added. As with the medium-duty engines, vehicle simulation results were reported for both individual technologies and for combinations. Vehicle technologies were evaluated only with the baseline 2019 diesel medium-duty engine.
Journal Article

Solid Particle Emissions from Vehicle Exhaust during Engine Start-Up

2015-04-14
2015-01-1077
Human exposure to vehicle exhaust during engine start-up can be encountered on a daily basis in parking lots, home garages, and vehicle stop/star traffic environment. This work is the first pilot study to characterize solid particle number and size distribution during engine start-up using various light-duty vehicles with different technology engines. A total of 84 vehicles were tested in this pilot study, consisting of post-2007 diesel engines equipped with high efficiency diesel particulate filters (DPFs) as well as modern gasoline port fuel injected (PFI) and gasoline direct injected (GDI) engines equipped with three-way-catalysts (TWCs). Particle concentration from DPF equipped diesel engines were found to be the lowest, while GDI and 8-cylinder PFI engines had the highest particle emissions.
Journal Article

Extension of Analytical Methods for Detailed Characterization of Advanced Combustion Engine Emissions

2016-10-17
2016-01-2330
Advanced combustion strategies used to improve efficiency, emissions, and performance in internal combustion engines (IC) alter the chemical composition of engine-out emissions. The characterization of exhaust chemistry from advanced IC engines requires an analytical system capable of measuring a wide range of compounds. For many years, the widely accepted Coordinating Research Council (CRC) Auto/Oil procedure[1,2] has been used to quantify hydrocarbon compounds between C1 and C12 from dilute engine exhaust in Tedlar polyvinyl fluoride (PVF) bags. Hydrocarbons greater than C12+ present the greatest challenge for identification in diesel exhaust. Above C12, PVF bags risk losing the higher molecular weight compounds due to adsorption to the walls of the bag or by condensation of the heavier compounds. This paper describes two specialized exhaust gas sampling and analytical systems capable of analyzing the mid-range (C10 - C24) and the high range (C24+) hydrocarbon in exhaust.
Journal Article

The Interaction between Fuel Anti-Knock Index and Reformation Ratio in an Engine Equipped with Dedicated EGR

2016-04-05
2016-01-0712
Experiments were performed on a small displacement (< 2 L), high compression ratio, 4 cylinder, port injected gasoline engine equipped with Dedicated EGR® (D-EGR®) technology using fuels with varying anti-knock properties. Gasolines with anti-knock indices of 84, 89 and 93 anti-knock index (AKI) were tested. The engine was operated at a constant nominal EGR rate of ∼25% while varying the reformation ratio in the dedicated cylinder from a ϕD-EGR = 1.0 - 1.4. Testing was conducted at selected engine speeds and constant torque while operating at knock limited spark advance on the three fuels. The change in combustion phasing as a function of the level of overfuelling in the dedicated cylinder was documented for all three fuels to determine the tradeoff between the reformation ratio required to achieve a certain knock resistance and the fuel octane rating.
Technical Paper

Evaluation of an On-Board, Real-Time Electronic Particulate Matter Sensor Using Heavy-Duty On-Highway Diesel Engine Platform

2020-04-14
2020-01-0385
California Air Resources Board (CARB) has instituted requirements for on-board diagnostics (OBD) that makes a spark-plug sized exhaust particulate matter (PM) sensor a critical component of the OBD system to detect diesel particulate filter (DPF) failure. Currently, non-real-time resistive-type sensors are used by engine OEMs onboard vehicles. Future OBD regulations are likely to lower PM OBD thresholds requiring higher sensitivity sensors with better data yield for OBD decision making. The focus of this work was on the experimental evaluation of a real-time PM sensor manufactured by EmiSense Technologies, LLC that may offer such benefits. A 2011 model year on-highway heavy-duty diesel engine fitted with a diesel oxidation catalyst (DOC) and a catalyzed DPF followed by urea-based selective catalytic reducer (SCR) and ammonia oxidation (AMOX) catalysts was used for this program.
Technical Paper

Development of a Burner-Based Test System to Produce Controllable Particulate Emissions for Evaluation of Gasoline Particulate Filters

2020-04-14
2020-01-0389
Gasoline Direct Injection (GDI) engines have been widely adopted by manufacturers in the light-duty market due to their fuel economy benefits. However, several studies have shown that GDI engines generate higher levels of particulate matter (PM) emissions relative to port fuel injected (PFI) engines and diesel engines equipped with optimally functioning diesel particulate filters (DPF). With stringent particle number (PN) regulations being implemented in both, the European Union and China, gasoline particulate filters (GPF) are expected to be widely utilized to control particulate emissions. Currently, evaluating GPF technologies on a vehicle can be challenging due to a limited number of commercially available vehicles that are calibrated for a GPF in the United States as well as the costs associated with vehicle procurement and evaluations utilizing a chassis dynamometer facility.
Journal Article

Ethanol Flex-fuel Engine Improvements with Exhaust Gas Recirculation and Hydrogen Enrichment

2009-04-20
2009-01-0140
An investigation was performed to identify the benefits of cooled exhaust gas recirculation (EGR) when applied to a potential ethanol flexible fuelled vehicle (eFFV) engine. The fuels investigated in this study represented the range a flex-fuel engine may be exposed to in the United States; from 85% ethanol/gasoline blend (E85) to regular gasoline. The test engine was a 2.0-L in-line 4 cylinder that was turbocharged and port fuel injected (PFI). Ethanol blended fuels, including E85, have a higher octane rating and produce lower exhaust temperatures compared to gasoline. EGR has also been shown to decrease engine knock tendency and decrease exhaust temperatures. A natural progression was to take advantage of the superior combustion characteristics of E85 (i.e. increase compression ratio), and then employ EGR to maintain performance with gasoline. When EGR alone could not provide the necessary knock margin, hydrogen (H2) was added to simulate an onboard fuel reformer.
Journal Article

The Effect of EGR on Low-Speed Pre-Ignition in Boosted SI Engines

2011-04-12
2011-01-0339
The spark ignition (SI) engine has been known to exhibit several different abnormal combustion phenomena, such as knock or pre-ignition, which have been addressed with improved engine design or control schemes. However, in highly boosted SI engines - where the engine displacement is reduced and turbocharging is employed to increase specific power - a new combustion phenomenon, described as Low-Speed Pre-Ignition (LSPI), has been exhibited. LSPI is characterized as a pre-ignition event typically followed by heavy knock, which has the potential to cause degradation of the engine. However, because LSPI events occur only sporadically and in an uncontrolled fashion, it is difficult to identify the causes for this phenomenon and to develop solutions to suppress it. Some countermeasures exist that OEMs can use to avoid LSPI, such as load limiting, but these have drawbacks.
Journal Article

Engine Operating Condition and Gasoline Fuel Composition Effects on Low-Speed Pre-Ignition in High-Performance Spark Ignited Gasoline Engines

2011-04-12
2011-01-0342
Downsizing is an important concept to reduce fuel consumption as well as emissions of spark ignition engines. Engine displacement is reduced in order to shift operating points from lower part load into regions of the operating map with higher efficiency and thus lower specific fuel consumption [ 1 ]. Since maximum power in full load operation decreases due to the reduction of displacement, engines are boosted (turbocharging or supercharging), which leads to a higher specific loading of the engines. Hence, a new combustion phenomenon has been observed at high loads and low engine speed and is referred to as Low-Speed Pre-Ignition or LSPI. In cycles with LSPI, the air/fuel mixture is ignited prior to the spark which results in the initial flame propagation quickly transforming into heavy engine knock. Very high pressure rise rates and peak cylinder pressures could exceed design pressure limits, which in turn could lead to degradation of the engine.
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