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Experiments were performed using a Light-Duty, single-cylinder, research engine in which the emissions, fuel consumption and combustion characteristics of two Fischer-Tropsch (F-T) Diesel fuels derived from natural gas and two conventional Diesel fuels (Swedish low sulfur Diesel and European EN 590 Diesel) were compared. Due to their low aromatic contents combustion with the F-T Diesel fuels resulted in lower soot emissions than combustion with the conventional Diesel fuels. The hydrocarbon emissions were also significantly lower with F-T fuel combustion. Moreover the F-T fuels tended to yield lower CO emissions than the conventional Diesel fuels. The low emissions from the F-T Diesel fuels, and the potential for producing such fuels from biomass, are powerful reason for future interest and research in this field.

Analysis of spray-wall interaction is a major issue in the study of the combustion process in DI diesel engines. Along with spray characteristics, the investigation of impinging sprays and of liquid wall film development is fundamental for predicting the mixture formation. Simulations of these phenomena for diesel sprays need to be validated and improved; nevertheless they can extend and complement experimental measurements. In this paper the wall film thickness for impinging sprays was investigated by evaluating the heat transfer across a temperature controlled wall. In fact, heat transfer is significantly affected by the wall film thickness, and both experiments and simulations were carried out to correlate the wall temperature variations and film height. The numerical simulations were carried out using the STAR-CD and the KIVA-3V, rel. 2, codes.

The emissions from a direct injection diesel engine measured according to the ECE R49 13-mode cycle and as a function of exhaust gas recirculation are compared for diesel fuel without water addition, and for water-in-diesel as emulsion and microemulsion. The effect of water addition on the soot emissions was remarkably strong for both the emulsion and microemulsion fuels. The average weighted soot emission values for the 13-mode cycle were 0.0024 and 0.0023 g/kWh for the two most interesting emulsion and microemulsion fuels tested, respectively; 5-fold lower than the US 2007 emission limit.

Optical studies of combusting diesel sprays were done on three different alternative liquid fuels and compared to Swedish environmental class 1 diesel fuel (MK1). The alternative fuels were Rapeseed Oil Methyl Ester (RME), Palm Oil Methyl Ester (PME) and Fischer-Tropsch (FT) fuel. The studies were carried out in the Chalmers High Pressure High Temperature spray rig under conditions similar to those prevailing in a direct-injected diesel engine prior to injection. High speed shadowgraphs were acquired to measure the penetration of the continuous liquid phase, droplets and ligaments, and vapor penetration. Flame temperatures and relative soot concentrations were measured by emission based, line-of-sight, optical methods. A comparison between previous engine tests and spray rig experiments was conducted in order to provide a deeper explanation of the combustion phenomena in the engine tests.

The CFD model, based on the LANL KIVA-3 computer code, modified to account for the multi-step dimethyl ether, DME/air, oxidation chemistry, was developed and used to study the neat DME combustion dynamics in a constant volume at Diesel-like conditions and in the Volvo AH10A245DI Diesel engine. Constant volume simulations confirm high ignition quality of neat DME in air. The results of engine modeling illustrate that the injection schedule used for Diesel fuel is not optimal for DME. Surprisingly, the positive gain and peak pressure levels comparable with those for Diesel fuel were obtained using an early (∼ -20 ATDC) injection through a nozzle of a larger diameter at reduced injection pressures and velocities (∼150m/s) preventing too rapid spray atomization. At these conditions, combustion heat release has a specific two-stage character with a peak value placed behind the TDC.

Wall wetting can occur irrespective of combustion concept in diesel engines, e.g. during the compression stroke. This action has been related to engine-out emissions in different ways, and an experimental investigation of impinging diesel sprays is thus made for a standard diesel fuel and a two-component model fuel (IDEA). The experiment was performed at conditions corresponding to those found during the compression stroke in a heavy duty diesel engine. The spray characteristics of two fuels were measured using two different optical methods: a Phase Doppler Particle Analyzer (PDPA) and high-speed imaging. A temperature controlled wall equipped with rapid, coaxial thermocouples was used to record the change in surface temperature from the heat transfer of the impinging sprays.

This paper describes an analysis of the Diesel Oil Surrogate (DOS) model used at Chalmers University (Sweden), including 70 species participating in 310 reactions, and subsequent improvements prompted by the model's systematic tendency to under-predict the combustion intensity in simulations of kinetically-driven combustion modes, e.g. Homogeneous Charged Compression Ignition (HCCI). Key bases of the model are the properties of a model Diesel fuel with the molecular formula C14H28. In the vapor phase, a global reaction decomposes the starting fuel, C14H28, into its constituent components; n-heptane (C7H16) and toluene (C7H8). This global reaction was modified to yield a higher n-heptane:toluene ratio, due to the importance of preserving an n-heptane-like cetane number.

It has been previously shown that engine-out soot emissions can be reduced by using Fischer-Tropsch (FT) fuels, due to their lack of aromatics, compared to conventional Diesel fuels. In this investigation the engine-out emissions and fuel consumption parameters of an FT fuel derived from natural gas were compared to those of Swedish low sulfur diesel (MK1) when used in Low Temperature Combustion mode in a single cylinder heavy-duty diesel engine. The effects of varying Needle Opening Pressure (NOP), Charge Air Pressure (CAP) and Exhaust Gas Recirculation (EGR) according to an experimental design on the measured variables were also assessed. CAP and EGR were found to be the most significant factors for the combustion and emission parameters of both fuels. Increases in CAP resulted in lower soot emissions due to enhanced charge mixing, however NOx emissions rose as CAP increased.

The purpose of the investigation presented here was to compare the effects of fuel composition on combustion parameters, emissions and fuel consumption in engine tests and simulations with five fuels: a Diesel-water emulsion, a Diesel-ethanol blend, a Diesel-ethanol blend with EHN (cetane number improver), a Fischer-Tropsch Diesel and an ultra-low sulfur content Diesel. The engine used in the experiments was a light duty, single cylinder, direct injection, common rail Diesel engine equipped with a cylinder head and piston from a Volvo NED5 engine. In tests with each fuel the engine was operated at two load points (3 bar IMEP and 10 bar IMEP), and a pilot-main fuel injection strategy was applied under both load conditions. Data were also obtained from 3-D CFD simulations, using the KIVA code, to compare to the experimental results and to further analyze the effects of water and ethanol on combustion.

The possibilities of operating a direct injection Diesel engine in HCCI combustion mode with early injection of conventional Diesel fuel were investigated. In order to properly phase the combustion process in the cycle and to prevent knock, the geometric compression ratio was reduced from 17.0:1 to 13.4:1 or 11.5:1. Further control of the phasing and combustion rate was achieved with high rates of cooled EGR. The engine used for the experiments was a single cylinder version of a modern passenger car type common rail engine with a displacement of 480 cc. An injector with a small included angle was used to prevent interaction of the spray and the cylinder liner. In order to create a homogeneous mixture, the fuel was injected by multiple short injections during the compression stroke. The low knock resistance of the Diesel fuel limited the operating conditions to low loads. Compared to conventional Diesel combustion, the NOx emissions were dramatically reduced.

Having low aromatic compounds, high cetane rating, higher heat of combustion and almost zero sulphur content, a new paraffinic fuel (NPF), developed by Oroboros AB Sweden, was believed to receive attention as a new alternative fuel. Therefore, further investigation and combustion analyses were conducted in a research single-cylinder diesel engine, where detailed thermodynamic analyses were performed by Burst to File high frequency signal sampling code and by the Dragon software, revealing the real thermochemistry history. The aim of this investigation was an effort to reduce the pollution levels in Santiago de Chile by introducing this new paraffinic fuel (NPF). Experimental results have shown that the NPF fuel has a significant impact not only on the emission levels, but also on other energetic parameters of the engine such as ignition delay, cylinder peak pressure, heat release gradient, indicated efficiency etc.

To reproduce the Diesel fuel structural effect on soot formation, the diesel oil surrogate chemical model has been developed, validated using constant volume and applied to 3-D engine calculations using the KIVA-3V code. To better predict soot production, the presence of toluene, A1CH3, which is a product of benzene alkylation, in the reaction mechanism of n-heptane oxidation has been assumed. Soot formation as a solid phase has been simulated via a finite-rate transition of the gaseous precursor of soot, A2R5, to graphite. The final mechanism consists of 68 species and 278 reactions. Reasonable agreement of predictions with constant volume experimental data, on ignition delay times, flame appearance, accumulated amount of soot produced and soot cloud evolution has been achieved. Then, the fuel surrogate model has been applied to 3-D simulation (on a sectored mesh) of the Volvo NED5 DI Diesel engine.

Reducing emissions and improving efficiency are major goals of modern internal combustion engine research. The use of biomass-derived fuels in Diesel engines is an effective way of reducing well-to-wheels (WTW) greenhouse gas (GHG) emissions. Moreover, partially premixed combustion (PPC) makes it possible to achieve very efficient combustion with low emissions of soot and NOx. The objective of this study was to investigate the effect of using alcohol/Diesel blends or neat alcohols on emissions and thermal efficiency during PPC. Four alcohols were evaluated: n-butanol, isobutanol, n-octanol, and 2-ethylhexanol. The alcohols were blended with fossil Diesel fuel to produce mixtures with low cetane numbers (26-36) suitable for PPC. The blends were then tested in a single cylinder light duty (LD) engine. To optimize combustion, the exhaust gas recirculation (EGR) level, lambda, and injection strategy were tuned.

Laws concerning to emissions from heavy duty (HD) internal combustion engines are becoming increasingly stringent. New engine technologies are therefore needed to satisfy these new legal requirements and reduce fossil fuel dependency. One way to achieve both objectives is to partially replace fossil fuels with alternatives that are more sustainable with respect to emissions of greenhouse gas, particulates and NOx. As a first step towards the development of a direct injected dual fuel engine using diesel fuel and renewable alcohols such as methanol or ethanol, we have studied ethanol (E100) sprays generated with a standard high pressure diesel fuel injection system in a high pressure/temperature spray chamber with optical access. The experiments were performed at a gas density of ∼27kg/m3 at ∼550 °C and ∼60 bar, representing typical operating conditions for a HD engine at low loads.

Both spray-wall and spray-spray interactions in direct injection diesel engines have been found to influence the rate of heat release and the formation of emissions. Simulations of these phenomena for diesel sprays need to be validated, and an issue is investigating what kind of fuels can be used in both experiments and spray calculations. The objective of this work is to compare numerical simulations with experimental data of sprays impinging on a temperature controlled wall with respect to spray characteristics and heat transfer. The numerical simulations were made using the STAR-CD and KIVA-3V codes. The CFD simulations accounted for the actual spray chamber geometry and operating conditions used in the experiments. Particular attention was paid to the fuel used for the simulations.

One of the problems encountered when operating Diesel engines in HCCI mode is a too early start of combustion, due to the low ignition resistance of Diesel fuels. Correct phasing of the combustion process requires a lower in-cylinder temperature during compression. One possibility of regulating the temperature is to adjust the intake valve closing timing and thus the effective compression ratio. A single cylinder research engine, configured as a passenger car type DI Common Rail Diesel engine, was fitted with a fully adjustable hydraulic valve train, which allowed free settings of the valve timing events. Premixed combustion was achieved by injecting the fuel during the compression stroke, prior to ignition, in multiple steps. Different combinations of intake valve closing timing and external EGR were tested as well as the possibility to use internal EGR for combustion control.

The ignition delay of ethanol with different nitrate and polyethylene glycol based ignition improvers was investigated in a single-cylinder DI Diesel engine. The nitrate-based improvers provided a shorter ignition delay than the polyethylene glycol improvers, but the results indicate that the efficiency of the polyethylene glycol improvers increases with the length of the molecular chains. Comparison with reference fuels gives a cetane number of approximately 44 for ethanol with 4% of the best nitrate-based improver versus 40 for ethanol with 7% polyethylene glycol improver. It is shown, that the random ignition delay for all the fuels has a normal distribution, and that the reference fuel of every measurement series has a constant expected ignition delay. Ignition delay measurements in a constant-volume combustion vessel failed to produce the same trends as in the engine for the ethanol fuels.

The free piston internal combustion engine used in conjunction with a linear alternator offers an interesting choice for use in hybrid vehicles. The linear motion of the pistons is directly converted to electricity by the alternator, and the result is a compact and efficient energy converter that has only one moving part. The movement of the pistons is not prescribed by a crank mechanism, but is the result of the equilibrium of forces acting on the pistons, and the engine will act like a mass-spring system. This feature is one of the most prominent advantages of the FPE (Free Piston Engine), as the lack of mechanical linkage gives means of varying the compression ratio in simple manners, without changing the hardware of the engine. By varying the compression ratio, it is also it possible to run on a multitude of different fuels and to use HCCI (Homogeneous Charge Compression Ignition) combustion.

Computational simulations of the spray combustion and emissions formation processes in a heavy-duty DI diesel engine and in a small-bore DI diesel engine with a complicated injection schedule were performed by using the modified KIVA3V, rel. 2 code. Some initial parameter sets varying engine operating conditions, such as injection pressure, injector nozzle diameter, EGR load, were examined in order to evaluate their effects on the engine performance. Full-scale combustion chamber representations on 360-deg, Cartesian and polar, multiblock meshes with a different number of sprays have been used in the modelling unlike the conventional approach based on polar sector meshes covering the region around one fuel spray. The spray combustion phenomena were simulated using the detailed chemical mechanism for diesel fuel surrogate (69 species and 306 reactions).

Soot particle size, particle concentration and volume fraction were measured by laser based methods in optically dense, highly turbulent combusting diesel sprays under engine-like conditions. Experiments were done in the Chalmers High Pressure, High Temperature spray rig under isobaric conditions and combusting commercial diesel fuel. Laser Induced Incandescence (LII), Elastic Scattering and Light Extinction were combined quasi-simultaneously to quantify particle characteristics spatially resolved in the middle plane of a combusting spray at two instants after the start of combustion. The influence that fuel injection pressure, gas temperature and gas pressure exert on particle size, particle concentration and volume fraction were studied. Probability density functions of particle size and two-dimensional images of particle diameter, particle concentration and volume fraction concerning instantaneous single-shot cases and average measurements are presented.