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The capabilities of the JPL Electronic Nose have been expanded to include characteristics required for a Technology Demonstration schedule on the International Space Station (ISS) in 2008-2009 [1,2]. Concurrently, to accommodate specific needs on ISS, the processes, tools and analyses which influence all aspects of development of the device have also been expanded. The Third Generation ENose developed for this program uses two types of sensor substrates, newly developed inorganic and organic sensor materials, redesigned electronics, onboard near real-time data analysis and power and data interfaces specifically for ISS. This paper will discuss the Third Generation ENose with a focus on detection of mercury in the parts-per-billion range.

An array-based sensing system based on 32 polymer/carbon composite conductometric sensors is under development at JPL. Until the present phase of development, the analyte set has focused on organic compounds (common solvents) and a few selected inorganic compounds, notably ammonia and hydrazine. The present phase of JPL ENose development has added two inorganics to the analyte set: mercury and sulfur dioxide. Through models of sensor-analyte response developed under this program coupled with a literature survey, approaches to including these analytes in the ENose target set have been determined.