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A recent collaborative research project between Southwest Research Institute® (SwRI®) and the University of Texas at San Antonio (UTSA) has demonstrated that a ruthenium (Ru) catalyst is capable of converting oxides of nitrogen (NOX) emissions to nitrogen (N2) with high activity and selectivity. Testing was performed on coated cordierite ceramic cores using SwRI’s Universal Synthetic Gas Reactor® (USGR®). Various gas mixtures were employed, from model gas mixes to full exhaust simulant gas mixes. Activity was measured as a function of temperature, and gaseous inhibitors and promoters were identified. Different Ru supports were tested to identify ones with lowest temperature activity. A Ru catalyst can be used in the exhaust gas recirculation (EGR) leg of a Dedicated-EGR (D-EGR) engine [1,2], where it uses carbon monoxide (CO) and hydrogen (H2) present in the rich gas environment to reduce NOX to N2 with 100% efficiency and close to 100% selectivity to N2.

The drive to more fuel efficient vehicles is underway, with passenger car targets of 54.5 mpg fleet average by 2025. Improving engine efficiency means reducing losses such as the heat lost in the exhaust gases. However, reducing exhaust temperature makes it harder for emissions control catalysts to function because they require elevated temperatures to be active. Addressing this conundrum was the focus of the work performed. The primary objective of this work was to identify low temperature limiters for a variety of catalyst aftertreatment types. The ultimate goal is to reduce catalyst light-off temperatures, and the knowledge needed is an understanding of what prevents a catalyst from lighting off, why, and how it may be mitigated. Collectively these are referred to here as low temperature limiters to catalyst activity.